Selective homo- and cross-desilacoupling of aryl and benzyl primary silanes catalyzed by a barium complex

Under mild conditions (25 °C, 5 mol% cat.), highly selective homo- and cross-desilacoupling of aryl and benzyl primary silanes to secondary silanes was achieved by the use of the heteroleptic barium aminobenzyl complex [(Tp Ad,iPr )Ba(CH 2 C 6 H 4 NMe 2 - o )] (Tp Ad,iPr = hydrotris(3-adamantyl-5-is...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2020-06, Vol.49 (24), p.834-8346
Hauptverfasser:	Liu, Zhizhou, Shi, Xianghui, Cheng, Jianhua
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Barium NMR Nuclear magnetic resonance Silanes
Online-Zugang:	Volltext
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