NHC-Au() complexes bearing trispyrazolyl borate (Tp) ligands: efficient platforms for bimetallic species

Treatment of NHC-AuCl (NHC = IPr and IMes) complexes with equimolar amounts of KTp R2 (R = Me, H) salts in tetrahydrofuran produces in high yields the heteroleptic complexes 3-6 with the general formula NHC-Au-Tp R2 . As the Tp R ligand in complexes 3-6 features a k 1 -N type coordination toward the...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2020-05, Vol.49 (19), p.6199-624
Hauptverfasser:	Ángel-Jijón, Carlos, Rendón-Nava, David, Vazques-Pérez, Jose M, Álvarez-Hernández, Alejandro, Mendoza-Espinosa, Daniel, Salazar-Pereda, Verónica
Format:	Artikel
Sprache:	eng
Schlagworte:	Bimetals Chemical analysis Coordination compounds Crystal structure Crystallography Gold Ligands NMR spectroscopy Platforms Spectrum analysis Tetrahydrofuran
Online-Zugang:	Volltext
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