Transition metal carbon quadruple bond: viability through single electron transmutation

Quadruple bonding to main group elements is extremely rare although they have four valence orbitals accessible for bonding. Here we report the unprecedented quadruple bonding between a carbon atom and a transition metal fragment Fe(CO) 3 based on high level theoretical calculations. Various bonding...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2020-11, Vol.22 (42), p.24178-2418
Hauptverfasser:	Kalita, Amlan J, Rohman, Shahnaz S, Kashyap, Chayanika, Ullah, Sabnam S, Guha, Ankur K
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding Carbon Cartesian coordinates Iron Periodic table Single electrons Transition metals Transmutation
Online-Zugang:	Volltext
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