Remarkable reversal of C-NMR assignment in d, d compared to d, d acetylacetonate complexes: analysis and explanation based on solid-state MAS NMR and computations

13 C solid-state MAS NMR spectra of a series of paramagnetic metal acetylacetonate complexes; [VO(acac) 2 ] (d 1 , S = ½), [V(acac) 3 ] (d 2 , S = 1), [Ni(acac) 2 (H 2 O) 2 ] (d 8 , S = 1), and [Cu(acac) 2 ] (d 9 , S = ½), were assigned using modern NMR shielding calculations. This provided a reliab...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2020-04, Vol.22 (15), p.848-859
Hauptverfasser:	Andersen, Anders B. A, Pyykkönen, Ari, Jensen, Hans Jørgen Aa, McKee, Vickie, Vaara, Juha, Nielsen, Ulla Gro
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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