Hydrogen-bonded nickel() complexes
A series of nickel( ii ) tris(2-pyridylmethyl)amine (TPA) complexes featuring appended hydrogen bonds (H-bonds) to halides (F, Cl, Br) was synthesized and charcterized. Reduction to the nickel( i ) state provided access to an unusual nickel( i ) fluoride complex stabilized by H-bonds, enabling struc...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2021-01, Vol.57 (6), p.753-756 |
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| container_issue | 6 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Wilson, Jessica R Zeller, Matthias Szymczak, Nathaniel K |
| description | A series of nickel(
ii
) tris(2-pyridylmethyl)amine (TPA) complexes featuring appended hydrogen bonds (H-bonds) to halides (F, Cl, Br) was synthesized and charcterized. Reduction to the nickel(
i
) state provided access to an unusual nickel(
i
) fluoride complex stabilized by H-bonds, enabling structural and spectroscopic characterization.
Secondary-sphere hydrogen bonds enable structural characterization and evaluation of an unusual nickel(
i
) fluoride complex. |
| doi_str_mv | 10.1039/d0cc07216h |
| format | Article |
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ii
) tris(2-pyridylmethyl)amine (TPA) complexes featuring appended hydrogen bonds (H-bonds) to halides (F, Cl, Br) was synthesized and charcterized. Reduction to the nickel(
i
) state provided access to an unusual nickel(
i
) fluoride complex stabilized by H-bonds, enabling structural and spectroscopic characterization.
Secondary-sphere hydrogen bonds enable structural characterization and evaluation of an unusual nickel(
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ii
) tris(2-pyridylmethyl)amine (TPA) complexes featuring appended hydrogen bonds (H-bonds) to halides (F, Cl, Br) was synthesized and charcterized. Reduction to the nickel(
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i
) fluoride complex stabilized by H-bonds, enabling structural and spectroscopic characterization.
Secondary-sphere hydrogen bonds enable structural characterization and evaluation of an unusual nickel(
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ii
) tris(2-pyridylmethyl)amine (TPA) complexes featuring appended hydrogen bonds (H-bonds) to halides (F, Cl, Br) was synthesized and charcterized. Reduction to the nickel(
i
) state provided access to an unusual nickel(
i
) fluoride complex stabilized by H-bonds, enabling structural and spectroscopic characterization.
Secondary-sphere hydrogen bonds enable structural characterization and evaluation of an unusual nickel(
i
) fluoride complex.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>33346759</pmid><doi>10.1039/d0cc07216h</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-1296-1445</orcidid><orcidid>https://orcid.org/0000-0002-7116-4737</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2021-01, Vol.57 (6), p.753-756 |
| issn | 1359-7345 1364-548X 1364-548X |
| language | eng |
| recordid | cdi_rsc_primary_d0cc07216h |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Crystallography Halides Hydrogen bonding Hydrogen bonds Nickel Structural analysis |
| title | Hydrogen-bonded nickel() complexes |
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