Hydrogen-bonded nickel() complexes
A series of nickel( ii ) tris(2-pyridylmethyl)amine (TPA) complexes featuring appended hydrogen bonds (H-bonds) to halides (F, Cl, Br) was synthesized and charcterized. Reduction to the nickel( i ) state provided access to an unusual nickel( i ) fluoride complex stabilized by H-bonds, enabling struc...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2021-01, Vol.57 (6), p.753-756 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A series of nickel(
ii
) tris(2-pyridylmethyl)amine (TPA) complexes featuring appended hydrogen bonds (H-bonds) to halides (F, Cl, Br) was synthesized and charcterized. Reduction to the nickel(
i
) state provided access to an unusual nickel(
i
) fluoride complex stabilized by H-bonds, enabling structural and spectroscopic characterization.
Secondary-sphere hydrogen bonds enable structural characterization and evaluation of an unusual nickel(
i
) fluoride complex. |
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| ISSN: | 1359-7345 1364-548X 1364-548X |
| DOI: | 10.1039/d0cc07216h |