An unusual NiSiP cluster formed by complexation and thermolysis
[LSi(η 2 -P 4 )] (L = CH[C(Me)N(Dipp)][C(CH 2 )N(Dipp)], Dipp = 2,6-diisopropylphenyl) forms well-defined 1 : 1 and 2 : 1 complexes with N-heterocyclic carbene nickel fragments. The cluster compound [(IDipp)Ni 2 P 8 (SiL) 2 ] (IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) is selectivel...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2020-11, Vol.56 (9), p.1471-1474 |
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| container_issue | 9 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Ziegler, Christoph G. P Taube, Clemens Kelly, John A Hierlmeier, Gabriele Uttendorfer, Maria Weigand, Jan J Wolf, Robert |
| description | [LSi(η
2
-P
4
)] (L = CH[C(Me)N(Dipp)][C(CH
2
)N(Dipp)], Dipp = 2,6-diisopropylphenyl) forms well-defined 1 : 1 and 2 : 1 complexes with N-heterocyclic carbene nickel fragments. The cluster compound [(IDipp)Ni
2
P
8
(SiL)
2
] (IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) is selectively formed by thermolysis of the complex [(IDipp)Ni(μ-η
2:2
-P
4
)SiL].
A ternary Ni
2
Si
2
P
8
cluster compound is formed selectively by thermolysis of a well-defined nickel complex. This reaction illustrates a potentially useful strategy for the preparation of heteroatom-doped transition metal-phosphide clusters. |
| doi_str_mv | 10.1039/d0cc05365a |
| format | Article |
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2
-P
4
)] (L = CH[C(Me)N(Dipp)][C(CH
2
)N(Dipp)], Dipp = 2,6-diisopropylphenyl) forms well-defined 1 : 1 and 2 : 1 complexes with N-heterocyclic carbene nickel fragments. The cluster compound [(IDipp)Ni
2
P
8
(SiL)
2
] (IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) is selectively formed by thermolysis of the complex [(IDipp)Ni(μ-η
2:2
-P
4
)SiL].
A ternary Ni
2
Si
2
P
8
cluster compound is formed selectively by thermolysis of a well-defined nickel complex. This reaction illustrates a potentially useful strategy for the preparation of heteroatom-doped transition metal-phosphide clusters.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d0cc05365a</identifier><ispartof>Chemical communications (Cambridge, England), 2020-11, Vol.56 (9), p.1471-1474</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Ziegler, Christoph G. P</creatorcontrib><creatorcontrib>Taube, Clemens</creatorcontrib><creatorcontrib>Kelly, John A</creatorcontrib><creatorcontrib>Hierlmeier, Gabriele</creatorcontrib><creatorcontrib>Uttendorfer, Maria</creatorcontrib><creatorcontrib>Weigand, Jan J</creatorcontrib><creatorcontrib>Wolf, Robert</creatorcontrib><title>An unusual NiSiP cluster formed by complexation and thermolysis</title><title>Chemical communications (Cambridge, England)</title><description>[LSi(η
2
-P
4
)] (L = CH[C(Me)N(Dipp)][C(CH
2
)N(Dipp)], Dipp = 2,6-diisopropylphenyl) forms well-defined 1 : 1 and 2 : 1 complexes with N-heterocyclic carbene nickel fragments. The cluster compound [(IDipp)Ni
2
P
8
(SiL)
2
] (IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) is selectively formed by thermolysis of the complex [(IDipp)Ni(μ-η
2:2
-P
4
)SiL].
A ternary Ni
2
Si
2
P
8
cluster compound is formed selectively by thermolysis of a well-defined nickel complex. This reaction illustrates a potentially useful strategy for the preparation of heteroatom-doped transition metal-phosphide clusters.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpjYBAyNNAzNDC21E8xSE42MDU2M01kYuA0NDYz0TU1sYhgAbFNLXXNjU1MORi4iouzDIDA0NSCk8HeMU-hNK-0uDQxR8EvMzgzQCE5p7S4JLVIIS2_KDc1RSGpUiE5P7cgJ7UisSQzP08hMS9FoSQjtSg3P6eyOLOYh4E1LTGnOJUXSnMzyLq5hjh76BYVJ8cXFGXmJhZVxiNcZUxIHgCayTrR</recordid><startdate>20201112</startdate><enddate>20201112</enddate><creator>Ziegler, Christoph G. P</creator><creator>Taube, Clemens</creator><creator>Kelly, John A</creator><creator>Hierlmeier, Gabriele</creator><creator>Uttendorfer, Maria</creator><creator>Weigand, Jan J</creator><creator>Wolf, Robert</creator><scope/></search><sort><creationdate>20201112</creationdate><title>An unusual NiSiP cluster formed by complexation and thermolysis</title><author>Ziegler, Christoph G. P ; Taube, Clemens ; Kelly, John A ; Hierlmeier, Gabriele ; Uttendorfer, Maria ; Weigand, Jan J ; Wolf, Robert</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d0cc05365a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2020</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Ziegler, Christoph G. P</creatorcontrib><creatorcontrib>Taube, Clemens</creatorcontrib><creatorcontrib>Kelly, John A</creatorcontrib><creatorcontrib>Hierlmeier, Gabriele</creatorcontrib><creatorcontrib>Uttendorfer, Maria</creatorcontrib><creatorcontrib>Weigand, Jan J</creatorcontrib><creatorcontrib>Wolf, Robert</creatorcontrib><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ziegler, Christoph G. P</au><au>Taube, Clemens</au><au>Kelly, John A</au><au>Hierlmeier, Gabriele</au><au>Uttendorfer, Maria</au><au>Weigand, Jan J</au><au>Wolf, Robert</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An unusual NiSiP cluster formed by complexation and thermolysis</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2020-11-12</date><risdate>2020</risdate><volume>56</volume><issue>9</issue><spage>1471</spage><epage>1474</epage><pages>1471-1474</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>[LSi(η
2
-P
4
)] (L = CH[C(Me)N(Dipp)][C(CH
2
)N(Dipp)], Dipp = 2,6-diisopropylphenyl) forms well-defined 1 : 1 and 2 : 1 complexes with N-heterocyclic carbene nickel fragments. The cluster compound [(IDipp)Ni
2
P
8
(SiL)
2
] (IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) is selectively formed by thermolysis of the complex [(IDipp)Ni(μ-η
2:2
-P
4
)SiL].
A ternary Ni
2
Si
2
P
8
cluster compound is formed selectively by thermolysis of a well-defined nickel complex. This reaction illustrates a potentially useful strategy for the preparation of heteroatom-doped transition metal-phosphide clusters.</abstract><doi>10.1039/d0cc05365a</doi><tpages>4</tpages></addata></record> |
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| ispartof | Chemical communications (Cambridge, England), 2020-11, Vol.56 (9), p.1471-1474 |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | An unusual NiSiP cluster formed by complexation and thermolysis |
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