Nickel-assisted complete cleavage of CO by a silylene/siliconoid hybrid under formation of an Si&z.dbd;C enol ether bridge
Reaction of a silylene-functionalized Si 6 siliconoid with CO in the presence of catalytic quantities of a nickel(0) complex results in the complete cleavage of the CO triple bond, but preserves the Si 6 scaffold with an exohedrally incorporated Si&z.dbd;C enol ether bridge. The uncompromised cl...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2020-09, Vol.56 (74), p.1898-191 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Poitiers, Nadine E Huch, Volker Zimmer, Michael Scheschkewitz, David |
| description | Reaction of a silylene-functionalized Si
6
siliconoid with CO in the presence of catalytic quantities of a nickel(0) complex results in the complete cleavage of the CO triple bond, but preserves the Si
6
scaffold with an exohedrally incorporated Si&z.dbd;C enol ether bridge. The uncompromised cluster core emphasizes the role of the so-called benzpolarene motif as the energetic silicon pendants of benzene in carbon chemistry.
A silylene-siliconoid hybrid incorporates CO to form a Si&z.dbd;C enol ether bridge in the presence of Ni(cod)
2
(
= silicon). |
| doi_str_mv | 10.1039/d0cc04922k |
| format | Article |
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scaffold with an exohedrally incorporated Si&z.dbd;C enol ether bridge. The uncompromised cluster core emphasizes the role of the so-called benzpolarene motif as the energetic silicon pendants of benzene in carbon chemistry.
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2
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2
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siliconoid with CO in the presence of catalytic quantities of a nickel(0) complex results in the complete cleavage of the CO triple bond, but preserves the Si
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scaffold with an exohedrally incorporated Si&z.dbd;C enol ether bridge. The uncompromised cluster core emphasizes the role of the so-called benzpolarene motif as the energetic silicon pendants of benzene in carbon chemistry.
A silylene-siliconoid hybrid incorporates CO to form a Si&z.dbd;C enol ether bridge in the presence of Ni(cod)
2
(
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2020-09, Vol.56 (74), p.1898-191 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_rsc_primary_d0cc04922k |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Nickel-assisted complete cleavage of CO by a silylene/siliconoid hybrid under formation of an Si&z.dbd;C enol ether bridge |
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