Single-component solid state white-light emission and photoluminescence color tuning of a Cd() complex and its application as a luminescence thermometer
A single-component solid white-light emitter, the Cd( ii ) complex Cd 2 (Sal) 4 (PyNH 2 ) 2 ( 1 ) (where Sal = 2-formylphenolato, PyNH 2 = 4-aminopyridine), was synthesized in a simple procedure. Crystals of 1 display almost pure white-light emission upon excitation in a wide range from 300 to 400 n...
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| Veröffentlicht in: | Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2019, Vol.7 (43), p.13454-1346 |
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| container_title | Journal of materials chemistry. C, Materials for optical and electronic devices |
| container_volume | 7 |
| creator | Miao, Jinling Nie, Yong Li, Yexin Qin, Chengyuan Ren, Yifan Xu, Chunyue Yan, Meijing Liu, Kexin Liu, Guangning |
| description | A single-component solid white-light emitter, the Cd(
ii
) complex Cd
2
(Sal)
4
(PyNH
2
)
2
(
1
) (where Sal = 2-formylphenolato, PyNH
2
= 4-aminopyridine), was synthesized in a simple procedure. Crystals of
1
display almost pure white-light emission upon excitation in a wide range from 300 to 400 nm. The white-light emission of
1
is composed of complementary blue and yellow components in an appropriate ratio, which belong to the ligand to metal (PyNH
2
to Cd(
ii
)) charge transfer (LMCT) and the π-π* transition of Sal, respectively. Grinding crystals of
1
led to the transformation into the amorphous state along with the white-cyan-green emission color change and a color change from orange to yellow. The color of amorphous
1
could return to orange when heated. The emission color of amorphous
1
undergoes a gradual change from green to yellow when heated to 180 °C without a change in the molecular structure, and the corresponding color temperature exhibits a linear relationship with the heating temperature in a wide range (323-453 K), which makes amorphous
1
a reliable luminescence thermometer based on the photoemission energy.
A single-component white-light emitting Cd(
ii
) complex exhibits tunable photoluminescence and acts as a novel luminescence thermometer based on the correlation between temperature and color temperature. |
| doi_str_mv | 10.1039/c9tc04033a |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_c9tc04033a</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2312517010</sourcerecordid><originalsourceid>FETCH-LOGICAL-c318t-7afab32c8f08b1f431dfb1d4ac5dc4fecbb288f0400cf5fcae1dd73995843213</originalsourceid><addsrcrecordid>eNpVkU1LxDAQhoMouKx78S4EvKhQTZp22x6X4hcseHDvJU0m2yxpUpMs6j_x59rdFcW5zAzzzjPwDkLnlNxSwqo7UUVBMsIYP0KTlOQkKXKWHf_W6fwUzULYkDFKOi_n1QR9vWq7NpAI1w_Ogo04OKMlDpFHwO-djpAYve4ihl6HoJ3F3Eo8dC46s-21hSDACsDCGedx3NqRh53CHNfy6hrvuAY-9ks6BsyHwWjB4x40tvgfJHbge9dDBH-GThQ3AWY_eYpWD_er-ilZvjw-14tlIhgtY1JwxVuWilKRsqUqY1SqlsqMi1yKTIFo27QchxkhQuVKcKBSFqyq8jJjKWVTdHnADt69bSHEZuO23o4Xm5TRNKcFGb2dopuDSngXggfVDF733H82lDQ775u6WtV77xej-OIg9kH86v5-w74BAw2EYg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2312517010</pqid></control><display><type>article</type><title>Single-component solid state white-light emission and photoluminescence color tuning of a Cd() complex and its application as a luminescence thermometer</title><source>Royal Society Of Chemistry Journals</source><creator>Miao, Jinling ; Nie, Yong ; Li, Yexin ; Qin, Chengyuan ; Ren, Yifan ; Xu, Chunyue ; Yan, Meijing ; Liu, Kexin ; Liu, Guangning</creator><creatorcontrib>Miao, Jinling ; Nie, Yong ; Li, Yexin ; Qin, Chengyuan ; Ren, Yifan ; Xu, Chunyue ; Yan, Meijing ; Liu, Kexin ; Liu, Guangning</creatorcontrib><description>A single-component solid white-light emitter, the Cd(
ii
) complex Cd
2
(Sal)
4
(PyNH
2
)
2
(
1
) (where Sal = 2-formylphenolato, PyNH
2
= 4-aminopyridine), was synthesized in a simple procedure. Crystals of
1
display almost pure white-light emission upon excitation in a wide range from 300 to 400 nm. The white-light emission of
1
is composed of complementary blue and yellow components in an appropriate ratio, which belong to the ligand to metal (PyNH
2
to Cd(
ii
)) charge transfer (LMCT) and the π-π* transition of Sal, respectively. Grinding crystals of
1
led to the transformation into the amorphous state along with the white-cyan-green emission color change and a color change from orange to yellow. The color of amorphous
1
could return to orange when heated. The emission color of amorphous
1
undergoes a gradual change from green to yellow when heated to 180 °C without a change in the molecular structure, and the corresponding color temperature exhibits a linear relationship with the heating temperature in a wide range (323-453 K), which makes amorphous
1
a reliable luminescence thermometer based on the photoemission energy.
A single-component white-light emitting Cd(
ii
) complex exhibits tunable photoluminescence and acts as a novel luminescence thermometer based on the correlation between temperature and color temperature.</description><identifier>ISSN: 2050-7526</identifier><identifier>EISSN: 2050-7534</identifier><identifier>DOI: 10.1039/c9tc04033a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Cadmium compounds ; Charge transfer ; Color temperature ; Crystallography ; Diodes ; Emitters ; Light emission ; Luminescence ; Molecular structure ; Photoelectric emission ; Photoluminescence ; White light</subject><ispartof>Journal of materials chemistry. C, Materials for optical and electronic devices, 2019, Vol.7 (43), p.13454-1346</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c318t-7afab32c8f08b1f431dfb1d4ac5dc4fecbb288f0400cf5fcae1dd73995843213</citedby><cites>FETCH-LOGICAL-c318t-7afab32c8f08b1f431dfb1d4ac5dc4fecbb288f0400cf5fcae1dd73995843213</cites><orcidid>0000-0003-1339-0186 ; 0000-0003-2702-1744 ; 0000-0003-3311-5632</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,4025,27927,27928,27929</link.rule.ids></links><search><creatorcontrib>Miao, Jinling</creatorcontrib><creatorcontrib>Nie, Yong</creatorcontrib><creatorcontrib>Li, Yexin</creatorcontrib><creatorcontrib>Qin, Chengyuan</creatorcontrib><creatorcontrib>Ren, Yifan</creatorcontrib><creatorcontrib>Xu, Chunyue</creatorcontrib><creatorcontrib>Yan, Meijing</creatorcontrib><creatorcontrib>Liu, Kexin</creatorcontrib><creatorcontrib>Liu, Guangning</creatorcontrib><title>Single-component solid state white-light emission and photoluminescence color tuning of a Cd() complex and its application as a luminescence thermometer</title><title>Journal of materials chemistry. C, Materials for optical and electronic devices</title><description>A single-component solid white-light emitter, the Cd(
ii
) complex Cd
2
(Sal)
4
(PyNH
2
)
2
(
1
) (where Sal = 2-formylphenolato, PyNH
2
= 4-aminopyridine), was synthesized in a simple procedure. Crystals of
1
display almost pure white-light emission upon excitation in a wide range from 300 to 400 nm. The white-light emission of
1
is composed of complementary blue and yellow components in an appropriate ratio, which belong to the ligand to metal (PyNH
2
to Cd(
ii
)) charge transfer (LMCT) and the π-π* transition of Sal, respectively. Grinding crystals of
1
led to the transformation into the amorphous state along with the white-cyan-green emission color change and a color change from orange to yellow. The color of amorphous
1
could return to orange when heated. The emission color of amorphous
1
undergoes a gradual change from green to yellow when heated to 180 °C without a change in the molecular structure, and the corresponding color temperature exhibits a linear relationship with the heating temperature in a wide range (323-453 K), which makes amorphous
1
a reliable luminescence thermometer based on the photoemission energy.
A single-component white-light emitting Cd(
ii
) complex exhibits tunable photoluminescence and acts as a novel luminescence thermometer based on the correlation between temperature and color temperature.</description><subject>Cadmium compounds</subject><subject>Charge transfer</subject><subject>Color temperature</subject><subject>Crystallography</subject><subject>Diodes</subject><subject>Emitters</subject><subject>Light emission</subject><subject>Luminescence</subject><subject>Molecular structure</subject><subject>Photoelectric emission</subject><subject>Photoluminescence</subject><subject>White light</subject><issn>2050-7526</issn><issn>2050-7534</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpVkU1LxDAQhoMouKx78S4EvKhQTZp22x6X4hcseHDvJU0m2yxpUpMs6j_x59rdFcW5zAzzzjPwDkLnlNxSwqo7UUVBMsIYP0KTlOQkKXKWHf_W6fwUzULYkDFKOi_n1QR9vWq7NpAI1w_Ogo04OKMlDpFHwO-djpAYve4ihl6HoJ3F3Eo8dC46s-21hSDACsDCGedx3NqRh53CHNfy6hrvuAY-9ks6BsyHwWjB4x40tvgfJHbge9dDBH-GThQ3AWY_eYpWD_er-ilZvjw-14tlIhgtY1JwxVuWilKRsqUqY1SqlsqMi1yKTIFo27QchxkhQuVKcKBSFqyq8jJjKWVTdHnADt69bSHEZuO23o4Xm5TRNKcFGb2dopuDSngXggfVDF733H82lDQ775u6WtV77xej-OIg9kH86v5-w74BAw2EYg</recordid><startdate>2019</startdate><enddate>2019</enddate><creator>Miao, Jinling</creator><creator>Nie, Yong</creator><creator>Li, Yexin</creator><creator>Qin, Chengyuan</creator><creator>Ren, Yifan</creator><creator>Xu, Chunyue</creator><creator>Yan, Meijing</creator><creator>Liu, Kexin</creator><creator>Liu, Guangning</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-1339-0186</orcidid><orcidid>https://orcid.org/0000-0003-2702-1744</orcidid><orcidid>https://orcid.org/0000-0003-3311-5632</orcidid></search><sort><creationdate>2019</creationdate><title>Single-component solid state white-light emission and photoluminescence color tuning of a Cd() complex and its application as a luminescence thermometer</title><author>Miao, Jinling ; Nie, Yong ; Li, Yexin ; Qin, Chengyuan ; Ren, Yifan ; Xu, Chunyue ; Yan, Meijing ; Liu, Kexin ; Liu, Guangning</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c318t-7afab32c8f08b1f431dfb1d4ac5dc4fecbb288f0400cf5fcae1dd73995843213</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Cadmium compounds</topic><topic>Charge transfer</topic><topic>Color temperature</topic><topic>Crystallography</topic><topic>Diodes</topic><topic>Emitters</topic><topic>Light emission</topic><topic>Luminescence</topic><topic>Molecular structure</topic><topic>Photoelectric emission</topic><topic>Photoluminescence</topic><topic>White light</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Miao, Jinling</creatorcontrib><creatorcontrib>Nie, Yong</creatorcontrib><creatorcontrib>Li, Yexin</creatorcontrib><creatorcontrib>Qin, Chengyuan</creatorcontrib><creatorcontrib>Ren, Yifan</creatorcontrib><creatorcontrib>Xu, Chunyue</creatorcontrib><creatorcontrib>Yan, Meijing</creatorcontrib><creatorcontrib>Liu, Kexin</creatorcontrib><creatorcontrib>Liu, Guangning</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Miao, Jinling</au><au>Nie, Yong</au><au>Li, Yexin</au><au>Qin, Chengyuan</au><au>Ren, Yifan</au><au>Xu, Chunyue</au><au>Yan, Meijing</au><au>Liu, Kexin</au><au>Liu, Guangning</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Single-component solid state white-light emission and photoluminescence color tuning of a Cd() complex and its application as a luminescence thermometer</atitle><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle><date>2019</date><risdate>2019</risdate><volume>7</volume><issue>43</issue><spage>13454</spage><epage>1346</epage><pages>13454-1346</pages><issn>2050-7526</issn><eissn>2050-7534</eissn><abstract>A single-component solid white-light emitter, the Cd(
ii
) complex Cd
2
(Sal)
4
(PyNH
2
)
2
(
1
) (where Sal = 2-formylphenolato, PyNH
2
= 4-aminopyridine), was synthesized in a simple procedure. Crystals of
1
display almost pure white-light emission upon excitation in a wide range from 300 to 400 nm. The white-light emission of
1
is composed of complementary blue and yellow components in an appropriate ratio, which belong to the ligand to metal (PyNH
2
to Cd(
ii
)) charge transfer (LMCT) and the π-π* transition of Sal, respectively. Grinding crystals of
1
led to the transformation into the amorphous state along with the white-cyan-green emission color change and a color change from orange to yellow. The color of amorphous
1
could return to orange when heated. The emission color of amorphous
1
undergoes a gradual change from green to yellow when heated to 180 °C without a change in the molecular structure, and the corresponding color temperature exhibits a linear relationship with the heating temperature in a wide range (323-453 K), which makes amorphous
1
a reliable luminescence thermometer based on the photoemission energy.
A single-component white-light emitting Cd(
ii
) complex exhibits tunable photoluminescence and acts as a novel luminescence thermometer based on the correlation between temperature and color temperature.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c9tc04033a</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-1339-0186</orcidid><orcidid>https://orcid.org/0000-0003-2702-1744</orcidid><orcidid>https://orcid.org/0000-0003-3311-5632</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2050-7526 |
| ispartof | Journal of materials chemistry. C, Materials for optical and electronic devices, 2019, Vol.7 (43), p.13454-1346 |
| issn | 2050-7526 2050-7534 |
| language | eng |
| recordid | cdi_rsc_primary_c9tc04033a |
| source | Royal Society Of Chemistry Journals |
| subjects | Cadmium compounds Charge transfer Color temperature Crystallography Diodes Emitters Light emission Luminescence Molecular structure Photoelectric emission Photoluminescence White light |
| title | Single-component solid state white-light emission and photoluminescence color tuning of a Cd() complex and its application as a luminescence thermometer |
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