Deoxygenative trifluoromethylthiolation of carboxylic acids

Here we describe a deoxygenative trifluoromethylthiolation method that yields trifluoromethyl thioesters from readily available carboxylic acids. The method is built upon an umpolung strategy where triphenylphosphine is used to first activate an electrophilic trifluoromethylthiolating reagent and th...

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Veröffentlicht in:	Chemical science (Cambridge) 2019-11, Vol.1 (41), p.9555-9559
Hauptverfasser:	Mao, Runze, Bera, Srikrishna, Cheseaux, Alexis, Hu, Xile
Format:	Artikel
Sprache:	eng
Schlagworte:	Carboxylic acids Chemistry Deoxygenation Natural products Reagents Thioesters
Online-Zugang:	Volltext
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