Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) followed by the formation of molecular poly-oxo cluster {U} containing hemimellitate uranium()

Two coordination compounds bearing tetravalent uranium were synthesized in the presence of tritopic hemimellitic acid in acetonitrile with a controlled amount of water (H 2 O/U 8) and structurally characterized. Compound 1 , [U(1,2,3-Hbtc) 2 ]·0.5CH 3 CN is constructed around an eight-fold coordinat...

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Veröffentlicht in:	RSC advances 2019-08, Vol.9 (4), p.22795-2284
Hauptverfasser:	Dufaye, Maxime, Martin, Nicolas P, Duval, Sylvain, Volkringer, Christophe, Ikeda-Ohno, Atsushi, Loiseau, Thierry
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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