Polyaddition of vinyl ethers and phthalaldehydes successive cyclotrimerization reactions: selective model reactions and synthesis of acid-degradable linear poly(cyclic acetal)s

A polyaddition reaction via the cyclotrimerization of one vinyl ether and two conjugated dialdehyde molecules successfully proceeded using EtAlCl 2 as a Lewis acid catalyst, yielding a polymer with cyclic acetal structures in the main chain. The use of a low-reactive or non-polymerizable vinyl ether...

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Veröffentlicht in:Polymer chemistry 2019-03, Vol.1 (11), p.1377-1385
Hauptverfasser: Naito, Tadashi, Kanazawa, Arihiro, Aoshima, Sadahito
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