Achiral amino acid glycine acts as an origin of homochirality in asymmetric autocatalysis

Chiral crystals of the only achiral proteinogenic α-amino acid, glycine induced the asymmetric autocatalysis with amplification of enantiomeric excess (ee). The P 3 1 crystals of γ-glycine, which display positive Cotton effect (CD) at around 215 nm, mediate the asymmetric autocatalysis to yield ( R...

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Veröffentlicht in:	Organic & biomolecular chemistry 2019-04, Vol.17 (17), p.42-423
Hauptverfasser:	Matsumoto, Arimasa, Ozaki, Hanae, Tsuchiya, Sumeru, Asahi, Toru, Lahav, Meir, Kawasaki, Tsuneomi, Soai, Kenso
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids Amino acids Amplification Asymmetry Autocatalysis Cotton Crystals Glycine Handedness
Online-Zugang:	Volltext
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