Synthesis, structure and magnetic properties of honeycomb-layered LiCoSbO with new data on its sodium precursor, NaCoSbO
Li 3 Co 2 SbO 6 is prepared by molten salt ion exchange and its structure refined by the Rietveld method confirming the honeycomb-type Co/Sb ordering of its Na precursor. Monoclinic rather than trigonal symmetry of Na 3 Co 2 SbO 6 is directly demonstrated for the first time by peak splitting in the...
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Veröffentlicht in: | New journal of chemistry 2019-08, Vol.43 (34), p.13545-13553 |
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container_issue | 34 |
container_start_page | 13545 |
container_title | New journal of chemistry |
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creator | Stratan, Mikhail I Shukaev, Igor L Vasilchikova, Tatyana M Vasiliev, Alexander N Korshunov, Artem N Kurbakov, Alexander I Nalbandyan, Vladimir B Zvereva, Elena A |
description | Li
3
Co
2
SbO
6
is prepared by molten salt ion exchange and its structure refined by the Rietveld method confirming the honeycomb-type Co/Sb ordering of its Na precursor. Monoclinic rather than trigonal symmetry of Na
3
Co
2
SbO
6
is directly demonstrated for the first time by peak splitting in the high-resolution synchrotron XRD pattern. The long-range antiferromagnetic order is established at
T
N
6.7 K and 9.9 K in Na
3
Co
2
SbO
6
and Li
3
Co
2
SbO
6
, respectively, confirmed by both the magnetic susceptibility and specific heat. Spin-wave analysis of specific heat data indicates the presence of 3D AFM magnons in Na
3
Co
2
SbO
6
and 2D AFM magnons in Li
3
Co
2
SbO
6
. The field dependence of the magnetization almost reaches saturation in moderate magnetic fields up to 9 T and demonstrates characteristic features of magnetic field induced spin-reorientation transitions for both A
3
Co
2
SbO
6
(A = Na, Li). Overall thermodynamic studies show that the magnetic properties of both compounds are very sensitive to an external magnetic field, thus predicting a non-trivial ground state with a rich magnetic phase diagram. The ground state spin configuration of Li
3
Co
2
SbO
6
has been determined by low-temperature neutron powder diffraction. It represents a ferromagnetic arrangement of moments in the honeycomb layers with antiferromagnetic coupling between adjacent layers.
Crystallographic and magnetic properties of new layered honeycomb-lattice Li
3
Co
2
SbO
6
antimonate were studied and compared with its sodium precursor Na
3
Co
2
SbO
6
. |
doi_str_mv | 10.1039/c9nj03627j |
format | Article |
fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c9nj03627j</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c9nj03627j</sourcerecordid><originalsourceid>FETCH-rsc_primary_c9nj03627j3</originalsourceid><addsrcrecordid>eNqFj8FqwkAURQepUKtuuhfeB5g6k8SRrKXFRbEL3cs4eTETzEx4b4LN31ek0GVX98K5HLhCvCr5pmRWrGzhG5npdNOMxERlukiKVKune1d5nsh1rp_FC3MjpVIbrSbi-zD4WCM7XgJH6m3sCcH4Elpz8RidhY5ChxQdMoQK6uBxsKE9J1czIGEJn24bDucvuLlYg8cblCYaCB5cZOBQur69O9D2xIGWsDeP-UyMK3NlnP_mVCw-3o_bXUJsTx251tBw-ruT_cd_AIfpT9w</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis, structure and magnetic properties of honeycomb-layered LiCoSbO with new data on its sodium precursor, NaCoSbO</title><source>Royal Society Of Chemistry Journals</source><source>Alma/SFX Local Collection</source><creator>Stratan, Mikhail I ; Shukaev, Igor L ; Vasilchikova, Tatyana M ; Vasiliev, Alexander N ; Korshunov, Artem N ; Kurbakov, Alexander I ; Nalbandyan, Vladimir B ; Zvereva, Elena A</creator><creatorcontrib>Stratan, Mikhail I ; Shukaev, Igor L ; Vasilchikova, Tatyana M ; Vasiliev, Alexander N ; Korshunov, Artem N ; Kurbakov, Alexander I ; Nalbandyan, Vladimir B ; Zvereva, Elena A</creatorcontrib><description>Li
3
Co
2
SbO
6
is prepared by molten salt ion exchange and its structure refined by the Rietveld method confirming the honeycomb-type Co/Sb ordering of its Na precursor. Monoclinic rather than trigonal symmetry of Na
3
Co
2
SbO
6
is directly demonstrated for the first time by peak splitting in the high-resolution synchrotron XRD pattern. The long-range antiferromagnetic order is established at
T
N
6.7 K and 9.9 K in Na
3
Co
2
SbO
6
and Li
3
Co
2
SbO
6
, respectively, confirmed by both the magnetic susceptibility and specific heat. Spin-wave analysis of specific heat data indicates the presence of 3D AFM magnons in Na
3
Co
2
SbO
6
and 2D AFM magnons in Li
3
Co
2
SbO
6
. The field dependence of the magnetization almost reaches saturation in moderate magnetic fields up to 9 T and demonstrates characteristic features of magnetic field induced spin-reorientation transitions for both A
3
Co
2
SbO
6
(A = Na, Li). Overall thermodynamic studies show that the magnetic properties of both compounds are very sensitive to an external magnetic field, thus predicting a non-trivial ground state with a rich magnetic phase diagram. The ground state spin configuration of Li
3
Co
2
SbO
6
has been determined by low-temperature neutron powder diffraction. It represents a ferromagnetic arrangement of moments in the honeycomb layers with antiferromagnetic coupling between adjacent layers.
Crystallographic and magnetic properties of new layered honeycomb-lattice Li
3
Co
2
SbO
6
antimonate were studied and compared with its sodium precursor Na
3
Co
2
SbO
6
.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/c9nj03627j</identifier><ispartof>New journal of chemistry, 2019-08, Vol.43 (34), p.13545-13553</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Stratan, Mikhail I</creatorcontrib><creatorcontrib>Shukaev, Igor L</creatorcontrib><creatorcontrib>Vasilchikova, Tatyana M</creatorcontrib><creatorcontrib>Vasiliev, Alexander N</creatorcontrib><creatorcontrib>Korshunov, Artem N</creatorcontrib><creatorcontrib>Kurbakov, Alexander I</creatorcontrib><creatorcontrib>Nalbandyan, Vladimir B</creatorcontrib><creatorcontrib>Zvereva, Elena A</creatorcontrib><title>Synthesis, structure and magnetic properties of honeycomb-layered LiCoSbO with new data on its sodium precursor, NaCoSbO</title><title>New journal of chemistry</title><description>Li
3
Co
2
SbO
6
is prepared by molten salt ion exchange and its structure refined by the Rietveld method confirming the honeycomb-type Co/Sb ordering of its Na precursor. Monoclinic rather than trigonal symmetry of Na
3
Co
2
SbO
6
is directly demonstrated for the first time by peak splitting in the high-resolution synchrotron XRD pattern. The long-range antiferromagnetic order is established at
T
N
6.7 K and 9.9 K in Na
3
Co
2
SbO
6
and Li
3
Co
2
SbO
6
, respectively, confirmed by both the magnetic susceptibility and specific heat. Spin-wave analysis of specific heat data indicates the presence of 3D AFM magnons in Na
3
Co
2
SbO
6
and 2D AFM magnons in Li
3
Co
2
SbO
6
. The field dependence of the magnetization almost reaches saturation in moderate magnetic fields up to 9 T and demonstrates characteristic features of magnetic field induced spin-reorientation transitions for both A
3
Co
2
SbO
6
(A = Na, Li). Overall thermodynamic studies show that the magnetic properties of both compounds are very sensitive to an external magnetic field, thus predicting a non-trivial ground state with a rich magnetic phase diagram. The ground state spin configuration of Li
3
Co
2
SbO
6
has been determined by low-temperature neutron powder diffraction. It represents a ferromagnetic arrangement of moments in the honeycomb layers with antiferromagnetic coupling between adjacent layers.
Crystallographic and magnetic properties of new layered honeycomb-lattice Li
3
Co
2
SbO
6
antimonate were studied and compared with its sodium precursor Na
3
Co
2
SbO
6
.</description><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFj8FqwkAURQepUKtuuhfeB5g6k8SRrKXFRbEL3cs4eTETzEx4b4LN31ek0GVX98K5HLhCvCr5pmRWrGzhG5npdNOMxERlukiKVKune1d5nsh1rp_FC3MjpVIbrSbi-zD4WCM7XgJH6m3sCcH4Elpz8RidhY5ChxQdMoQK6uBxsKE9J1czIGEJn24bDucvuLlYg8cblCYaCB5cZOBQur69O9D2xIGWsDeP-UyMK3NlnP_mVCw-3o_bXUJsTx251tBw-ruT_cd_AIfpT9w</recordid><startdate>20190827</startdate><enddate>20190827</enddate><creator>Stratan, Mikhail I</creator><creator>Shukaev, Igor L</creator><creator>Vasilchikova, Tatyana M</creator><creator>Vasiliev, Alexander N</creator><creator>Korshunov, Artem N</creator><creator>Kurbakov, Alexander I</creator><creator>Nalbandyan, Vladimir B</creator><creator>Zvereva, Elena A</creator><scope/></search><sort><creationdate>20190827</creationdate><title>Synthesis, structure and magnetic properties of honeycomb-layered LiCoSbO with new data on its sodium precursor, NaCoSbO</title><author>Stratan, Mikhail I ; Shukaev, Igor L ; Vasilchikova, Tatyana M ; Vasiliev, Alexander N ; Korshunov, Artem N ; Kurbakov, Alexander I ; Nalbandyan, Vladimir B ; Zvereva, Elena A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c9nj03627j3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stratan, Mikhail I</creatorcontrib><creatorcontrib>Shukaev, Igor L</creatorcontrib><creatorcontrib>Vasilchikova, Tatyana M</creatorcontrib><creatorcontrib>Vasiliev, Alexander N</creatorcontrib><creatorcontrib>Korshunov, Artem N</creatorcontrib><creatorcontrib>Kurbakov, Alexander I</creatorcontrib><creatorcontrib>Nalbandyan, Vladimir B</creatorcontrib><creatorcontrib>Zvereva, Elena A</creatorcontrib><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stratan, Mikhail I</au><au>Shukaev, Igor L</au><au>Vasilchikova, Tatyana M</au><au>Vasiliev, Alexander N</au><au>Korshunov, Artem N</au><au>Kurbakov, Alexander I</au><au>Nalbandyan, Vladimir B</au><au>Zvereva, Elena A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, structure and magnetic properties of honeycomb-layered LiCoSbO with new data on its sodium precursor, NaCoSbO</atitle><jtitle>New journal of chemistry</jtitle><date>2019-08-27</date><risdate>2019</risdate><volume>43</volume><issue>34</issue><spage>13545</spage><epage>13553</epage><pages>13545-13553</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>Li
3
Co
2
SbO
6
is prepared by molten salt ion exchange and its structure refined by the Rietveld method confirming the honeycomb-type Co/Sb ordering of its Na precursor. Monoclinic rather than trigonal symmetry of Na
3
Co
2
SbO
6
is directly demonstrated for the first time by peak splitting in the high-resolution synchrotron XRD pattern. The long-range antiferromagnetic order is established at
T
N
6.7 K and 9.9 K in Na
3
Co
2
SbO
6
and Li
3
Co
2
SbO
6
, respectively, confirmed by both the magnetic susceptibility and specific heat. Spin-wave analysis of specific heat data indicates the presence of 3D AFM magnons in Na
3
Co
2
SbO
6
and 2D AFM magnons in Li
3
Co
2
SbO
6
. The field dependence of the magnetization almost reaches saturation in moderate magnetic fields up to 9 T and demonstrates characteristic features of magnetic field induced spin-reorientation transitions for both A
3
Co
2
SbO
6
(A = Na, Li). Overall thermodynamic studies show that the magnetic properties of both compounds are very sensitive to an external magnetic field, thus predicting a non-trivial ground state with a rich magnetic phase diagram. The ground state spin configuration of Li
3
Co
2
SbO
6
has been determined by low-temperature neutron powder diffraction. It represents a ferromagnetic arrangement of moments in the honeycomb layers with antiferromagnetic coupling between adjacent layers.
Crystallographic and magnetic properties of new layered honeycomb-lattice Li
3
Co
2
SbO
6
antimonate were studied and compared with its sodium precursor Na
3
Co
2
SbO
6
.</abstract><doi>10.1039/c9nj03627j</doi><tpages>9</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
title | Synthesis, structure and magnetic properties of honeycomb-layered LiCoSbO with new data on its sodium precursor, NaCoSbO |
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