Functionalization of [ReQ(CN)] clusters by methylation of cyanide ligands
Methylation of anionic cluster complexes [Re 6 Q 8 (CN) 6 ] 4− with ((CH 3 ) 3 O)BF 4 or CF 3 SO 3 CH 3 afforded homoleptic isonitrile cluster complexes [Re 6 Q 8 (CH 3 NC) 6 ] 2+ (Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry, 1 H NMR, 13 C NMR, 14 N NM...
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| Veröffentlicht in: | New journal of chemistry 2019-11, Vol.43 (41), p.16338-16348 |
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| container_end_page | 16348 |
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| container_issue | 41 |
| container_start_page | 16338 |
| container_title | New journal of chemistry |
| container_volume | 43 |
| creator | Mikhaylov, Maksim A Mironova, Alina D Brylev, Konstantin A Sukhikh, Taisiya S Eltsov, Ilia V Stass, Dmitri V Gushchin, Artem L Kitamura, Noboru Sokolov, Maxim N |
| description | Methylation of anionic cluster complexes [Re
6
Q
8
(CN)
6
]
4−
with ((CH
3
)
3
O)BF
4
or CF
3
SO
3
CH
3
afforded homoleptic isonitrile cluster complexes [Re
6
Q
8
(CH
3
NC)
6
]
2+
(Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry,
1
H NMR,
13
C NMR,
14
N NMR,
15
N NMR,
77
Se NMR, and
125
Te NMR techniques, electrochemistry, TGA, and photophysical measurements.
Methylation of anionic cluster complexes [Re
6
Q
8
(CN)
6
]
4−
with ((CH
3
)
3
O)BF
4
or CF
3
SO
3
CH
3
afforded homoleptic isonitrile cluster complexes [Re
6
Q
8
(CH
3
NC)
6
]
2+
(Q = S, Se, Te). |
| doi_str_mv | 10.1039/c9nj02971k |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c9nj02971k</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c9nj02971k</sourcerecordid><originalsourceid>FETCH-LOGICAL-r177t-e02e549c046cf8b6e7e9d4dd51ab82af460e906dbf6d2974ea2259e5db5cd4a43</originalsourceid><addsrcrecordid>eNpFj01LAzEURYMoWKsb90KWuojmZZJMs5TBaqEoiq5ESj5edGqaymS6GH-9FUVX9ywuBw4hx8DPgVfmwpu85MLU8L5DRlBpw4zQsLtlkJJxJfU-OShlyTlArWFEZtNN9n27zja1n_Yb6DrS5we8P21uz16oT5vSY1eoG-gK-7ch_Z38YHMbkKb21eZQDsletKng0e-OydP06rG5YfO761lzOWcd1HXPkAtU0ngutY8Tp7FGE2QICqybCBul5mi4Di7qsA2RaIVQBlVwygdpZTUmJz_ervjFR9eubDcs_rurL7rmTMg</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Functionalization of [ReQ(CN)] clusters by methylation of cyanide ligands</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Mikhaylov, Maksim A ; Mironova, Alina D ; Brylev, Konstantin A ; Sukhikh, Taisiya S ; Eltsov, Ilia V ; Stass, Dmitri V ; Gushchin, Artem L ; Kitamura, Noboru ; Sokolov, Maxim N</creator><creatorcontrib>Mikhaylov, Maksim A ; Mironova, Alina D ; Brylev, Konstantin A ; Sukhikh, Taisiya S ; Eltsov, Ilia V ; Stass, Dmitri V ; Gushchin, Artem L ; Kitamura, Noboru ; Sokolov, Maxim N</creatorcontrib><description>Methylation of anionic cluster complexes [Re
6
Q
8
(CN)
6
]
4−
with ((CH
3
)
3
O)BF
4
or CF
3
SO
3
CH
3
afforded homoleptic isonitrile cluster complexes [Re
6
Q
8
(CH
3
NC)
6
]
2+
(Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry,
1
H NMR,
13
C NMR,
14
N NMR,
15
N NMR,
77
Se NMR, and
125
Te NMR techniques, electrochemistry, TGA, and photophysical measurements.
Methylation of anionic cluster complexes [Re
6
Q
8
(CN)
6
]
4−
with ((CH
3
)
3
O)BF
4
or CF
3
SO
3
CH
3
afforded homoleptic isonitrile cluster complexes [Re
6
Q
8
(CH
3
NC)
6
]
2+
(Q = S, Se, Te).</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/c9nj02971k</identifier><language>eng</language><ispartof>New journal of chemistry, 2019-11, Vol.43 (41), p.16338-16348</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Mikhaylov, Maksim A</creatorcontrib><creatorcontrib>Mironova, Alina D</creatorcontrib><creatorcontrib>Brylev, Konstantin A</creatorcontrib><creatorcontrib>Sukhikh, Taisiya S</creatorcontrib><creatorcontrib>Eltsov, Ilia V</creatorcontrib><creatorcontrib>Stass, Dmitri V</creatorcontrib><creatorcontrib>Gushchin, Artem L</creatorcontrib><creatorcontrib>Kitamura, Noboru</creatorcontrib><creatorcontrib>Sokolov, Maxim N</creatorcontrib><title>Functionalization of [ReQ(CN)] clusters by methylation of cyanide ligands</title><title>New journal of chemistry</title><description>Methylation of anionic cluster complexes [Re
6
Q
8
(CN)
6
]
4−
with ((CH
3
)
3
O)BF
4
or CF
3
SO
3
CH
3
afforded homoleptic isonitrile cluster complexes [Re
6
Q
8
(CH
3
NC)
6
]
2+
(Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry,
1
H NMR,
13
C NMR,
14
N NMR,
15
N NMR,
77
Se NMR, and
125
Te NMR techniques, electrochemistry, TGA, and photophysical measurements.
Methylation of anionic cluster complexes [Re
6
Q
8
(CN)
6
]
4−
with ((CH
3
)
3
O)BF
4
or CF
3
SO
3
CH
3
afforded homoleptic isonitrile cluster complexes [Re
6
Q
8
(CH
3
NC)
6
]
2+
(Q = S, Se, Te).</description><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpFj01LAzEURYMoWKsb90KWuojmZZJMs5TBaqEoiq5ESj5edGqaymS6GH-9FUVX9ywuBw4hx8DPgVfmwpu85MLU8L5DRlBpw4zQsLtlkJJxJfU-OShlyTlArWFEZtNN9n27zja1n_Yb6DrS5we8P21uz16oT5vSY1eoG-gK-7ch_Z38YHMbkKb21eZQDsletKng0e-OydP06rG5YfO761lzOWcd1HXPkAtU0ngutY8Tp7FGE2QICqybCBul5mi4Di7qsA2RaIVQBlVwygdpZTUmJz_ervjFR9eubDcs_rurL7rmTMg</recordid><startdate>20191107</startdate><enddate>20191107</enddate><creator>Mikhaylov, Maksim A</creator><creator>Mironova, Alina D</creator><creator>Brylev, Konstantin A</creator><creator>Sukhikh, Taisiya S</creator><creator>Eltsov, Ilia V</creator><creator>Stass, Dmitri V</creator><creator>Gushchin, Artem L</creator><creator>Kitamura, Noboru</creator><creator>Sokolov, Maxim N</creator><scope/></search><sort><creationdate>20191107</creationdate><title>Functionalization of [ReQ(CN)] clusters by methylation of cyanide ligands</title><author>Mikhaylov, Maksim A ; Mironova, Alina D ; Brylev, Konstantin A ; Sukhikh, Taisiya S ; Eltsov, Ilia V ; Stass, Dmitri V ; Gushchin, Artem L ; Kitamura, Noboru ; Sokolov, Maxim N</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-r177t-e02e549c046cf8b6e7e9d4dd51ab82af460e906dbf6d2974ea2259e5db5cd4a43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mikhaylov, Maksim A</creatorcontrib><creatorcontrib>Mironova, Alina D</creatorcontrib><creatorcontrib>Brylev, Konstantin A</creatorcontrib><creatorcontrib>Sukhikh, Taisiya S</creatorcontrib><creatorcontrib>Eltsov, Ilia V</creatorcontrib><creatorcontrib>Stass, Dmitri V</creatorcontrib><creatorcontrib>Gushchin, Artem L</creatorcontrib><creatorcontrib>Kitamura, Noboru</creatorcontrib><creatorcontrib>Sokolov, Maxim N</creatorcontrib><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mikhaylov, Maksim A</au><au>Mironova, Alina D</au><au>Brylev, Konstantin A</au><au>Sukhikh, Taisiya S</au><au>Eltsov, Ilia V</au><au>Stass, Dmitri V</au><au>Gushchin, Artem L</au><au>Kitamura, Noboru</au><au>Sokolov, Maxim N</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Functionalization of [ReQ(CN)] clusters by methylation of cyanide ligands</atitle><jtitle>New journal of chemistry</jtitle><date>2019-11-07</date><risdate>2019</risdate><volume>43</volume><issue>41</issue><spage>16338</spage><epage>16348</epage><pages>16338-16348</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>Methylation of anionic cluster complexes [Re
6
Q
8
(CN)
6
]
4−
with ((CH
3
)
3
O)BF
4
or CF
3
SO
3
CH
3
afforded homoleptic isonitrile cluster complexes [Re
6
Q
8
(CH
3
NC)
6
]
2+
(Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry,
1
H NMR,
13
C NMR,
14
N NMR,
15
N NMR,
77
Se NMR, and
125
Te NMR techniques, electrochemistry, TGA, and photophysical measurements.
Methylation of anionic cluster complexes [Re
6
Q
8
(CN)
6
]
4−
with ((CH
3
)
3
O)BF
4
or CF
3
SO
3
CH
3
afforded homoleptic isonitrile cluster complexes [Re
6
Q
8
(CH
3
NC)
6
]
2+
(Q = S, Se, Te).</abstract><doi>10.1039/c9nj02971k</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1144-0546 |
| ispartof | New journal of chemistry, 2019-11, Vol.43 (41), p.16338-16348 |
| issn | 1144-0546 1369-9261 |
| language | eng |
| recordid | cdi_rsc_primary_c9nj02971k |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Functionalization of [ReQ(CN)] clusters by methylation of cyanide ligands |
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