Interfacial reactions of Cu() adsorption and hydrolysis driven by nano-scale confinement

Spatial confinement is prevalent in sedimentary rocks and can lead to changes in the chemical behavior at mineral-water interfaces. This includes both deviations in the physico-chemical properties of confined water, when compared to the bulk liquid phase, and subsequent alterations in adsorption che...

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Veröffentlicht in:	Environmental science. Nano 2020-01, Vol.7 (1), p.68-8
Hauptverfasser:	Knight, Andrew W, Ilani-Kashkouli, Poorandokht, Harvey, Jacob A, Greathouse, Jeffery A, Ho, Tuan A, Kabengi, Nadine, Ilgen, Anastasia G
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectroscopy Adsorption Analytical methods Calorimetry Chemical behavior Chemical properties Chemical speciation Chemicophysical properties Computer simulation Configurations Confinement Coordination Copper Dehydration Density Dimers Endothermic reactions Exothermic reactions Heat measurement Hydration Interface reactions Interfaces Liquid phases Molecular modelling Monomers Natural environment Organic chemistry Physicochemical properties Pore size Pores Porosity Profiles Sedimentary rocks Silica Silicon dioxide Simulation Speciation X ray absorption X-ray absorption spectroscopy
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