Combining unsaturated metal sites and narrow pores within a Co()-based MOF towards CO separation and transformation

A Co( ii )-based MOF, {[Co 3 (L) 2 (bpb)(DMA)(H 2 O)]·Solvents} n ( RH-1 ), with a unique interpenetrated framework has been solvothermally prepared. Because of its unsaturated metal sites and narrow pores inside the framework, RH-1 demonstrated excellent selective CO 2 adsorption over N 2 and CH 4...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2020-02, Vol.49 (7), p.258-262
Hauptverfasser:	Zhang, Xiuling, Zhang, Ran-Hui, Hu, Hui, Geng, Longlong, Zhang, Yong-Zheng, Gao, Jun, Zhang, Da-Shuai, Jin, Yao-Qiang, Sheng, Jianmin
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