Two Ni/Co-substituted sandwich-type germanomolybdates based on an unprecedented trivacant polyanion [α-GeMoO]
Two Ni/Co-substituted sandwich-type germanomolybdates, {[M 3 (NH 2 -trz) 6 (H 2 O) 6 ][M 4 (H 2 O) 2 (HGeMo 10 O 36 ) 2 ]}· n H 2 O (M = Ni 2+ ( 1 ) and Co 2+ ( 2 ), n = 10 ( 1 ) or 11 ( 2 ), NH 2 -trz = 4-amino-1,2,4-triazole), have been obtained under hydrothermal conditions. 1 and 2 represent the...
Gespeichert in:
| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2020-01, Vol.49 (4), p.977-982 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 982 |
|---|---|
| container_issue | 4 |
| container_start_page | 977 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 49 |
| creator | Xu, Hui Liu, Xing-Man Su, Tan Chen, Wei-Chao Su, Zhong-Min |
| description | Two Ni/Co-substituted sandwich-type germanomolybdates, {[M
3
(NH
2
-trz)
6
(H
2
O)
6
][M
4
(H
2
O)
2
(HGeMo
10
O
36
)
2
]}·
n
H
2
O (M = Ni
2+
(
1
) and Co
2+
(
2
),
n
= 10 (
1
) or 11 (
2
), NH
2
-trz = 4-amino-1,2,4-triazole), have been obtained under hydrothermal conditions.
1
and
2
represent the first trivacant Keggin germanomolybdates involving unprecedented [α-GeMo
10
O
36
]
8−
fragments and {M
3
O
4
} quasi-cubane building units. Both of them exhibit electrocatalytic behaviours for H
2
O
2
reduction and photocatalytic properties for CO
2
conversion.
Two sandwich-type germanomolybdates with unprecedented trivacant [α-GeMo
10
O
36
]
8−
fragments and {M
3
O
4
} quasi-cubane units were obtained. They exhibited electrocatalytic behaviours for H
2
O
2
reduction and photocatalytic properties for CO
2
conversion. |
| doi_str_mv | 10.1039/c9dt04433g |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c9dt04433g</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c9dt04433g</sourcerecordid><originalsourceid>FETCH-LOGICAL-r203t-b0ab52cfe21e0695c933800d8caaeb0ce571e86606090ce432801eca5a7830243</originalsourceid><addsrcrecordid>eNp90M9KAzEQBvAgCtbqxbsQHyB2Ntm_RynaCtVe6klkmU1m60qbXZLUso_li_hMrih68zTzwW--wzB2HsFVBKqY6MIEiGOl1gdsFMVZJgqp4sPfXabH7MT7VwApIZEjZlf7lj80k2kr_K7yoQm7QIZ7tGbf6BcR-o74mtwWbbttN31lMJDnFfpBtZaj5TvbOdJkyH5dBte8oUYbeDdwtM2Anj7exYzu2-XzKTuqcePp7GeO2ePtzWo6F4vl7G56vRBOggqiAqwSqWuSEUFaJLpQKgcwuUakCjQlWUR5mkIKxZBiJXOISGOCWa5AxmrMLr97nddl55otur78e07ZmXowF_8Z9QkHZmZF</addsrcrecordid><sourcetype>Enrichment Source</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Two Ni/Co-substituted sandwich-type germanomolybdates based on an unprecedented trivacant polyanion [α-GeMoO]</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Xu, Hui ; Liu, Xing-Man ; Su, Tan ; Chen, Wei-Chao ; Su, Zhong-Min</creator><creatorcontrib>Xu, Hui ; Liu, Xing-Man ; Su, Tan ; Chen, Wei-Chao ; Su, Zhong-Min</creatorcontrib><description>Two Ni/Co-substituted sandwich-type germanomolybdates, {[M
3
(NH
2
-trz)
6
(H
2
O)
6
][M
4
(H
2
O)
2
(HGeMo
10
O
36
)
2
]}·
n
H
2
O (M = Ni
2+
(
1
) and Co
2+
(
2
),
n
= 10 (
1
) or 11 (
2
), NH
2
-trz = 4-amino-1,2,4-triazole), have been obtained under hydrothermal conditions.
1
and
2
represent the first trivacant Keggin germanomolybdates involving unprecedented [α-GeMo
10
O
36
]
8−
fragments and {M
3
O
4
} quasi-cubane building units. Both of them exhibit electrocatalytic behaviours for H
2
O
2
reduction and photocatalytic properties for CO
2
conversion.
Two sandwich-type germanomolybdates with unprecedented trivacant [α-GeMo
10
O
36
]
8−
fragments and {M
3
O
4
} quasi-cubane units were obtained. They exhibited electrocatalytic behaviours for H
2
O
2
reduction and photocatalytic properties for CO
2
conversion.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c9dt04433g</identifier><language>eng</language><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2020-01, Vol.49 (4), p.977-982</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Xu, Hui</creatorcontrib><creatorcontrib>Liu, Xing-Man</creatorcontrib><creatorcontrib>Su, Tan</creatorcontrib><creatorcontrib>Chen, Wei-Chao</creatorcontrib><creatorcontrib>Su, Zhong-Min</creatorcontrib><title>Two Ni/Co-substituted sandwich-type germanomolybdates based on an unprecedented trivacant polyanion [α-GeMoO]</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>Two Ni/Co-substituted sandwich-type germanomolybdates, {[M
3
(NH
2
-trz)
6
(H
2
O)
6
][M
4
(H
2
O)
2
(HGeMo
10
O
36
)
2
]}·
n
H
2
O (M = Ni
2+
(
1
) and Co
2+
(
2
),
n
= 10 (
1
) or 11 (
2
), NH
2
-trz = 4-amino-1,2,4-triazole), have been obtained under hydrothermal conditions.
1
and
2
represent the first trivacant Keggin germanomolybdates involving unprecedented [α-GeMo
10
O
36
]
8−
fragments and {M
3
O
4
} quasi-cubane building units. Both of them exhibit electrocatalytic behaviours for H
2
O
2
reduction and photocatalytic properties for CO
2
conversion.
Two sandwich-type germanomolybdates with unprecedented trivacant [α-GeMo
10
O
36
]
8−
fragments and {M
3
O
4
} quasi-cubane units were obtained. They exhibited electrocatalytic behaviours for H
2
O
2
reduction and photocatalytic properties for CO
2
conversion.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNp90M9KAzEQBvAgCtbqxbsQHyB2Ntm_RynaCtVe6klkmU1m60qbXZLUso_li_hMrih68zTzwW--wzB2HsFVBKqY6MIEiGOl1gdsFMVZJgqp4sPfXabH7MT7VwApIZEjZlf7lj80k2kr_K7yoQm7QIZ7tGbf6BcR-o74mtwWbbttN31lMJDnFfpBtZaj5TvbOdJkyH5dBte8oUYbeDdwtM2Anj7exYzu2-XzKTuqcePp7GeO2ePtzWo6F4vl7G56vRBOggqiAqwSqWuSEUFaJLpQKgcwuUakCjQlWUR5mkIKxZBiJXOISGOCWa5AxmrMLr97nddl55otur78e07ZmXowF_8Z9QkHZmZF</recordid><startdate>20200128</startdate><enddate>20200128</enddate><creator>Xu, Hui</creator><creator>Liu, Xing-Man</creator><creator>Su, Tan</creator><creator>Chen, Wei-Chao</creator><creator>Su, Zhong-Min</creator><scope/></search><sort><creationdate>20200128</creationdate><title>Two Ni/Co-substituted sandwich-type germanomolybdates based on an unprecedented trivacant polyanion [α-GeMoO]</title><author>Xu, Hui ; Liu, Xing-Man ; Su, Tan ; Chen, Wei-Chao ; Su, Zhong-Min</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-r203t-b0ab52cfe21e0695c933800d8caaeb0ce571e86606090ce432801eca5a7830243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Hui</creatorcontrib><creatorcontrib>Liu, Xing-Man</creatorcontrib><creatorcontrib>Su, Tan</creatorcontrib><creatorcontrib>Chen, Wei-Chao</creatorcontrib><creatorcontrib>Su, Zhong-Min</creatorcontrib><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Hui</au><au>Liu, Xing-Man</au><au>Su, Tan</au><au>Chen, Wei-Chao</au><au>Su, Zhong-Min</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Two Ni/Co-substituted sandwich-type germanomolybdates based on an unprecedented trivacant polyanion [α-GeMoO]</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2020-01-28</date><risdate>2020</risdate><volume>49</volume><issue>4</issue><spage>977</spage><epage>982</epage><pages>977-982</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Two Ni/Co-substituted sandwich-type germanomolybdates, {[M
3
(NH
2
-trz)
6
(H
2
O)
6
][M
4
(H
2
O)
2
(HGeMo
10
O
36
)
2
]}·
n
H
2
O (M = Ni
2+
(
1
) and Co
2+
(
2
),
n
= 10 (
1
) or 11 (
2
), NH
2
-trz = 4-amino-1,2,4-triazole), have been obtained under hydrothermal conditions.
1
and
2
represent the first trivacant Keggin germanomolybdates involving unprecedented [α-GeMo
10
O
36
]
8−
fragments and {M
3
O
4
} quasi-cubane building units. Both of them exhibit electrocatalytic behaviours for H
2
O
2
reduction and photocatalytic properties for CO
2
conversion.
Two sandwich-type germanomolybdates with unprecedented trivacant [α-GeMo
10
O
36
]
8−
fragments and {M
3
O
4
} quasi-cubane units were obtained. They exhibited electrocatalytic behaviours for H
2
O
2
reduction and photocatalytic properties for CO
2
conversion.</abstract><doi>10.1039/c9dt04433g</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2020-01, Vol.49 (4), p.977-982 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_rsc_primary_c9dt04433g |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Two Ni/Co-substituted sandwich-type germanomolybdates based on an unprecedented trivacant polyanion [α-GeMoO] |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T12%3A37%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Two%20Ni/Co-substituted%20sandwich-type%20germanomolybdates%20based%20on%20an%20unprecedented%20trivacant%20polyanion%20%5B%CE%B1-GeMoO%5D&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Xu,%20Hui&rft.date=2020-01-28&rft.volume=49&rft.issue=4&rft.spage=977&rft.epage=982&rft.pages=977-982&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/c9dt04433g&rft_dat=%3Crsc%3Ec9dt04433g%3C/rsc%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |