Tracing and elucidating visible-light mediated oxidation and C-H functionalization of amines using mass spectrometry
The co-existing mechanism of visible light mediated direct oxidation and C-H functionalization of amines was investigated by capturing all the intermediates using online mass spectrometry. The two-step dehydrogenation of amine involving a proton coupled electron transfer (PCET) process was revealed...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2020-02, Vol.56 (14), p.2163-2166 |
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| container_issue | 14 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Ai, Wanpeng Gao, Yunpeng Xue, Jinjuan Liu, Xiaoyun Liu, Huwei Wang, Jianbo Bai, Yu |
| description | The co-existing mechanism of visible light mediated direct oxidation and C-H functionalization of amines was investigated by capturing all the intermediates using online mass spectrometry. The two-step dehydrogenation of amine involving a proton coupled electron transfer (PCET) process was revealed for the first time.
The mechanism of visible-light mediated direct oxidation and C-H functionalization of amines was investigated by capturing all intermediates using mass spectrometry. |
| doi_str_mv | 10.1039/c9cc09629a |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2020-02, Vol.56 (14), p.2163-2166 |
| issn | 1359-7345 1364-548X |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Amines Dehydrogenation Electron transfer Ions Mass spectrometry Oxidation Scientific imaging Spectroscopy |
| title | Tracing and elucidating visible-light mediated oxidation and C-H functionalization of amines using mass spectrometry |
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