A tetraphenylethylene-based covalent organic polymer for highly selective and sensitive detection of Fe and as a white light emitting diode

A newly prepared tetraphenylethylene-based (TPE-based) covalent organic polymer (COP) named COP-1 exhibits high selectivity for sensing Fe 3+ and the limit of detection (LOD) for Fe 3+ is 0.42 μM, which is lower than the reported metal-free porous polymers. Furthermore, a WLED is fabricated and the...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2019-10, Vol.55 (82), p.12328-12331
Hauptverfasser: Zhang, Han, Zhou, Jie, Shan, Guo-Gang, Li, Guang-Fu, Sun, Chun-Yi, Cui, Dong-Xu, Wang, Xin-Long, Su, Zhong-Min
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container_end_page 12331
container_issue 82
container_start_page 12328
container_title Chemical communications (Cambridge, England)
container_volume 55
creator Zhang, Han
Zhou, Jie
Shan, Guo-Gang
Li, Guang-Fu
Sun, Chun-Yi
Cui, Dong-Xu
Wang, Xin-Long
Su, Zhong-Min
description A newly prepared tetraphenylethylene-based (TPE-based) covalent organic polymer (COP) named COP-1 exhibits high selectivity for sensing Fe 3+ and the limit of detection (LOD) for Fe 3+ is 0.42 μM, which is lower than the reported metal-free porous polymers. Furthermore, a WLED is fabricated and the CIE coordinates are (0.32, 0.33), very close to pure white light. The COP-1 shows potential applications in biosensors of Fe 3+ and preparation of WLEDs. A new COP is synthesized, exhibiting excellent performance as an Fe 3+ sensor with a LOD of 23.5 ppb, and solid-state illumination.
doi_str_mv 10.1039/c9cc06337d
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title A tetraphenylethylene-based covalent organic polymer for highly selective and sensitive detection of Fe and as a white light emitting diode
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