Chirality transfer based on dynamic covalent chemistry: from small chiral molecules to supramolecules
Single-tailed and gemini-type supra-gelators were facilely fabricated via the conjugation of the d - or l -enantiomeric dihydrazide TDH with single-tailed achiral aldehyde C 12 BAD through dynamic acylhydrazone bonding. Chirality transfer from small molecules to supramolecules was successfully achie...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2019-08, Vol.55 (66), p.9861-9864 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Sun, Panpan Ren, Shujing Wu, Aoli Sun, Na Shi, Lijuan Zheng, Liqiang |
| description | Single-tailed and gemini-type supra-gelators were facilely fabricated
via
the conjugation of the
d
- or
l
-enantiomeric dihydrazide TDH with single-tailed achiral aldehyde C
12
BAD through dynamic acylhydrazone bonding. Chirality transfer from small molecules to supramolecules was successfully achieved
via
the spontaneous assembly of the formed supra-gelators into supramolecular chiral hydrogels.
Chirality transfer from small molecule to supramolecule was successfully achieved
via
regulation of dynamic covalent chemistry. |
| doi_str_mv | 10.1039/c9cc05598c |
| format | Article |
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via
the conjugation of the
d
- or
l
-enantiomeric dihydrazide TDH with single-tailed achiral aldehyde C
12
BAD through dynamic acylhydrazone bonding. Chirality transfer from small molecules to supramolecules was successfully achieved
via
the spontaneous assembly of the formed supra-gelators into supramolecular chiral hydrogels.
Chirality transfer from small molecule to supramolecule was successfully achieved
via
regulation of dynamic covalent chemistry.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c9cc05598c</identifier><identifier>PMID: 31364622</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Aldehydes ; Chirality ; Conjugation ; Hydrogels ; Organic chemistry ; Rheological properties ; Rheology</subject><ispartof>Chemical communications (Cambridge, England), 2019-08, Vol.55 (66), p.9861-9864</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c363t-d864ba77a298abab16a53ea65b881282f4b1d329ab5b8cece3b4ee323f635c583</citedby><cites>FETCH-LOGICAL-c363t-d864ba77a298abab16a53ea65b881282f4b1d329ab5b8cece3b4ee323f635c583</cites><orcidid>0000-0003-0422-9585 ; 0000-0001-5829-0766 ; 0000-0001-7616-9230</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31364622$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Sun, Panpan</creatorcontrib><creatorcontrib>Ren, Shujing</creatorcontrib><creatorcontrib>Wu, Aoli</creatorcontrib><creatorcontrib>Sun, Na</creatorcontrib><creatorcontrib>Shi, Lijuan</creatorcontrib><creatorcontrib>Zheng, Liqiang</creatorcontrib><title>Chirality transfer based on dynamic covalent chemistry: from small chiral molecules to supramolecules</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>Single-tailed and gemini-type supra-gelators were facilely fabricated
via
the conjugation of the
d
- or
l
-enantiomeric dihydrazide TDH with single-tailed achiral aldehyde C
12
BAD through dynamic acylhydrazone bonding. Chirality transfer from small molecules to supramolecules was successfully achieved
via
the spontaneous assembly of the formed supra-gelators into supramolecular chiral hydrogels.
Chirality transfer from small molecule to supramolecule was successfully achieved
via
regulation of dynamic covalent chemistry.</description><subject>Aldehydes</subject><subject>Chirality</subject><subject>Conjugation</subject><subject>Hydrogels</subject><subject>Organic chemistry</subject><subject>Rheological properties</subject><subject>Rheology</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp90c9L5TAQB_Agir8v3neJ7GURqk3SpKk3Ka4KghcFb2WSTrGSNs-kFd5_b94-fQt7MJeE73wYhgkhJyw_Z7moLmxlbS5lpe0W2WdCFZks9PP26i2rrBSF3CMHMb7m6TCpd8meWCnF-T7B-qUP4PppSacAY-wwUAMRW-pH2i5HGHpLrX8Hh-NE7QsOfZzC8pJ2wQ80DuBcSlct6OAd2tlhpJOncV4E2CRHZKcDF_H48z4kT3-uH-vb7P7h5q6-us-sUGLKWq0KA2UJvNJgwDAFUiAoabRmXPOuMKwVvAKTEosWhSkQBRedEtJKLQ7J73XfRfBvM8apSeNadA5G9HNsOFdlkSuui0R__Udf_RzGNF1SJWdSMpUndbZWNvgYA3bNIvQDhGXD8ma1_Kau6vrv8uuEf362nM2A7YZ-bTuB0zUI0W6q_36vWbRdMj--M-IDg8uVxA</recordid><startdate>20190825</startdate><enddate>20190825</enddate><creator>Sun, Panpan</creator><creator>Ren, Shujing</creator><creator>Wu, Aoli</creator><creator>Sun, Na</creator><creator>Shi, Lijuan</creator><creator>Zheng, Liqiang</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-0422-9585</orcidid><orcidid>https://orcid.org/0000-0001-5829-0766</orcidid><orcidid>https://orcid.org/0000-0001-7616-9230</orcidid></search><sort><creationdate>20190825</creationdate><title>Chirality transfer based on dynamic covalent chemistry: from small chiral molecules to supramolecules</title><author>Sun, Panpan ; Ren, Shujing ; Wu, Aoli ; Sun, Na ; Shi, Lijuan ; Zheng, Liqiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c363t-d864ba77a298abab16a53ea65b881282f4b1d329ab5b8cece3b4ee323f635c583</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aldehydes</topic><topic>Chirality</topic><topic>Conjugation</topic><topic>Hydrogels</topic><topic>Organic chemistry</topic><topic>Rheological properties</topic><topic>Rheology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, Panpan</creatorcontrib><creatorcontrib>Ren, Shujing</creatorcontrib><creatorcontrib>Wu, Aoli</creatorcontrib><creatorcontrib>Sun, Na</creatorcontrib><creatorcontrib>Shi, Lijuan</creatorcontrib><creatorcontrib>Zheng, Liqiang</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sun, Panpan</au><au>Ren, Shujing</au><au>Wu, Aoli</au><au>Sun, Na</au><au>Shi, Lijuan</au><au>Zheng, Liqiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chirality transfer based on dynamic covalent chemistry: from small chiral molecules to supramolecules</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2019-08-25</date><risdate>2019</risdate><volume>55</volume><issue>66</issue><spage>9861</spage><epage>9864</epage><pages>9861-9864</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Single-tailed and gemini-type supra-gelators were facilely fabricated
via
the conjugation of the
d
- or
l
-enantiomeric dihydrazide TDH with single-tailed achiral aldehyde C
12
BAD through dynamic acylhydrazone bonding. Chirality transfer from small molecules to supramolecules was successfully achieved
via
the spontaneous assembly of the formed supra-gelators into supramolecular chiral hydrogels.
Chirality transfer from small molecule to supramolecule was successfully achieved
via
regulation of dynamic covalent chemistry.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>31364622</pmid><doi>10.1039/c9cc05598c</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-0422-9585</orcidid><orcidid>https://orcid.org/0000-0001-5829-0766</orcidid><orcidid>https://orcid.org/0000-0001-7616-9230</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2019-08, Vol.55 (66), p.9861-9864 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_rsc_primary_c9cc05598c |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Aldehydes Chirality Conjugation Hydrogels Organic chemistry Rheological properties Rheology |
| title | Chirality transfer based on dynamic covalent chemistry: from small chiral molecules to supramolecules |
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