Transition metal-free hydrodefluorination of acid fluorides and organofluorines by PhGeH promoted by catalytic [PhC][B(CF)]

It has been shown that the germane Ph 3 GeH converts aryl and aliphatic acid fluorides directly to their corresponding aldehydes without over-reduction via the conversion of Ph 3 GeH to the germylium cation [Ph 3 Ge] + by a catalytic amount of the tritylium salt [Ph 3 C][B(C 6 F 5 ) 4 ]. Here, no tr...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2019-09, Vol.55 (73), p.1852-1855
Hauptverfasser:	Hayatifar, Ardalan, Borrego, Alejandro, Bosek, David, Czarnecki, Matthew, Derocher, Gabriel, Kuplicki, Adam, Lytle, Erik, Padilla, Jonas, Paroly, Charles, Tubay, Gillian, Vyletel, Jackson, Weinert, Charles S
Format:	Artikel
Sprache:	eng
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