Morphology-dependent third-order optical nonlinearity of a 2D Co-based metal-organic framework with a porphyrinic skeleton
A two-dimensional (2D) Co-based metal-organic framework (MOF) with porphyrinic skeleton forms crystalline plates, flower-shaped clusters, and ultrathin films under optimized conditions, including the use of polyvinylpyrrolidone (PVP) as a surfactant. Ultrathin films demonstrate the best solution-bas...
Gespeichert in:
| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2019-04, Vol.55 (33), p.4873-4876 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4876 |
|---|---|
| container_issue | 33 |
| container_start_page | 4873 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 55 |
| creator | Niu, Ru-Jie Zhou, Wen-Fa Liu, Yan Yang, Jun-Yi Zhang, Wen-Hua Lang, Jian-Ping Young, David J |
| description | A two-dimensional (2D) Co-based metal-organic framework (MOF) with porphyrinic skeleton forms crystalline plates, flower-shaped clusters, and ultrathin films under optimized conditions, including the use of polyvinylpyrrolidone (PVP) as a surfactant. Ultrathin films demonstrate the best solution-based third-order nonlinear optical properties, featuring a nonlinear transmittance (
T
) value of 0.54, absorption coefficient (
α
2
) of 9.5 × 10
−10
m W
−1
and second hyperpolarizability (
γ
) value of 1.37 × 10
−28
esu, which are slightly better than those of the flower-shaped clusters (
T
= 0.65,
α
2
= 7.0 × 10
−10
m W
−1
;
γ
= 1.27 × 10
−28
esu), but marginally better than those of the crystalline thin plates (
T
= 0.94,
α
2
= 2.4 × 10
−10
m W
−1
;
γ
= 0.24 × 10
−28
esu).
A two-dimensional (2D) Co-based metal-organic framework (MOF) with a porphyrinic skeleton forms crystalline plates, flower-shaped clusters, and ultrathin films under optimized conditions and these forms give distinctively different nonlinear optical properties. |
| doi_str_mv | 10.1039/c9cc01363f |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_c9cc01363f</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2210899017</sourcerecordid><originalsourceid>FETCH-LOGICAL-c337t-88ddff13465b7dc9b044c5d3a9cff05ccc105ca6bad6effc6d734678cf4790813</originalsourceid><addsrcrecordid>eNpd0c9LHDEUB_AgLWrVi_eWQC-lMDaZJDOTo0xrW1B6qeBtyLwkbnQmmSZZZPvXm-2qBXN5gffJj8cXoVNKzihh8gtIAEJZw-weOiyVV4J3N2-2eyGrlnFxgN6ldEfKoqLbRweMSEGJIIfo71WIyypM4XZTabMYr43POK9c1FWI2kQcluxATdgHPzlvVHR5g4PFCtdfcR-qUSWj8WyymsqJW-UdYBvVbB5CvMcPLq8KXbavbKLbNtO9mUwO_hi9tWpK5uSpHqHri2-_-x_V5a_vP_vzywoYa3PVdVpbSxlvxNhqkCPhHIRmSoK1RABAmQRUMyrdGGuh0WXipu3A8laSjrIj9Gl37xLDn7VJeZhdAjNNypuwTkNdE97ImpO60I-v6F1YR19-VxQlnZSEtkV93imIIaVo7LBEN6u4GSgZtokMvez7f4lcFPzh6cr1OBv9Qp8jKOD9DsQEL93_kbJHdYuR8A</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2210899017</pqid></control><display><type>article</type><title>Morphology-dependent third-order optical nonlinearity of a 2D Co-based metal-organic framework with a porphyrinic skeleton</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Niu, Ru-Jie ; Zhou, Wen-Fa ; Liu, Yan ; Yang, Jun-Yi ; Zhang, Wen-Hua ; Lang, Jian-Ping ; Young, David J</creator><creatorcontrib>Niu, Ru-Jie ; Zhou, Wen-Fa ; Liu, Yan ; Yang, Jun-Yi ; Zhang, Wen-Hua ; Lang, Jian-Ping ; Young, David J</creatorcontrib><description>A two-dimensional (2D) Co-based metal-organic framework (MOF) with porphyrinic skeleton forms crystalline plates, flower-shaped clusters, and ultrathin films under optimized conditions, including the use of polyvinylpyrrolidone (PVP) as a surfactant. Ultrathin films demonstrate the best solution-based third-order nonlinear optical properties, featuring a nonlinear transmittance (
T
) value of 0.54, absorption coefficient (
α
2
) of 9.5 × 10
−10
m W
−1
and second hyperpolarizability (
γ
) value of 1.37 × 10
−28
esu, which are slightly better than those of the flower-shaped clusters (
T
= 0.65,
α
2
= 7.0 × 10
−10
m W
−1
;
γ
= 1.27 × 10
−28
esu), but marginally better than those of the crystalline thin plates (
T
= 0.94,
α
2
= 2.4 × 10
−10
m W
−1
;
γ
= 0.24 × 10
−28
esu).
A two-dimensional (2D) Co-based metal-organic framework (MOF) with a porphyrinic skeleton forms crystalline plates, flower-shaped clusters, and ultrathin films under optimized conditions and these forms give distinctively different nonlinear optical properties.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c9cc01363f</identifier><identifier>PMID: 30951050</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Absorptivity ; Clusters ; Crystal structure ; Crystallinity ; Crystallography ; Metal-organic frameworks ; Morphology ; Nonlinearity ; Optical properties ; Polyvinylpyrrolidone ; Thin films ; Thin plates</subject><ispartof>Chemical communications (Cambridge, England), 2019-04, Vol.55 (33), p.4873-4876</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-88ddff13465b7dc9b044c5d3a9cff05ccc105ca6bad6effc6d734678cf4790813</citedby><cites>FETCH-LOGICAL-c337t-88ddff13465b7dc9b044c5d3a9cff05ccc105ca6bad6effc6d734678cf4790813</cites><orcidid>0000-0001-9047-8881 ; 0000-0003-2942-7385</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30951050$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Niu, Ru-Jie</creatorcontrib><creatorcontrib>Zhou, Wen-Fa</creatorcontrib><creatorcontrib>Liu, Yan</creatorcontrib><creatorcontrib>Yang, Jun-Yi</creatorcontrib><creatorcontrib>Zhang, Wen-Hua</creatorcontrib><creatorcontrib>Lang, Jian-Ping</creatorcontrib><creatorcontrib>Young, David J</creatorcontrib><title>Morphology-dependent third-order optical nonlinearity of a 2D Co-based metal-organic framework with a porphyrinic skeleton</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>A two-dimensional (2D) Co-based metal-organic framework (MOF) with porphyrinic skeleton forms crystalline plates, flower-shaped clusters, and ultrathin films under optimized conditions, including the use of polyvinylpyrrolidone (PVP) as a surfactant. Ultrathin films demonstrate the best solution-based third-order nonlinear optical properties, featuring a nonlinear transmittance (
T
) value of 0.54, absorption coefficient (
α
2
) of 9.5 × 10
−10
m W
−1
and second hyperpolarizability (
γ
) value of 1.37 × 10
−28
esu, which are slightly better than those of the flower-shaped clusters (
T
= 0.65,
α
2
= 7.0 × 10
−10
m W
−1
;
γ
= 1.27 × 10
−28
esu), but marginally better than those of the crystalline thin plates (
T
= 0.94,
α
2
= 2.4 × 10
−10
m W
−1
;
γ
= 0.24 × 10
−28
esu).
A two-dimensional (2D) Co-based metal-organic framework (MOF) with a porphyrinic skeleton forms crystalline plates, flower-shaped clusters, and ultrathin films under optimized conditions and these forms give distinctively different nonlinear optical properties.</description><subject>Absorptivity</subject><subject>Clusters</subject><subject>Crystal structure</subject><subject>Crystallinity</subject><subject>Crystallography</subject><subject>Metal-organic frameworks</subject><subject>Morphology</subject><subject>Nonlinearity</subject><subject>Optical properties</subject><subject>Polyvinylpyrrolidone</subject><subject>Thin films</subject><subject>Thin plates</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpd0c9LHDEUB_AgLWrVi_eWQC-lMDaZJDOTo0xrW1B6qeBtyLwkbnQmmSZZZPvXm-2qBXN5gffJj8cXoVNKzihh8gtIAEJZw-weOiyVV4J3N2-2eyGrlnFxgN6ldEfKoqLbRweMSEGJIIfo71WIyypM4XZTabMYr43POK9c1FWI2kQcluxATdgHPzlvVHR5g4PFCtdfcR-qUSWj8WyymsqJW-UdYBvVbB5CvMcPLq8KXbavbKLbNtO9mUwO_hi9tWpK5uSpHqHri2-_-x_V5a_vP_vzywoYa3PVdVpbSxlvxNhqkCPhHIRmSoK1RABAmQRUMyrdGGuh0WXipu3A8laSjrIj9Gl37xLDn7VJeZhdAjNNypuwTkNdE97ImpO60I-v6F1YR19-VxQlnZSEtkV93imIIaVo7LBEN6u4GSgZtokMvez7f4lcFPzh6cr1OBv9Qp8jKOD9DsQEL93_kbJHdYuR8A</recordid><startdate>20190418</startdate><enddate>20190418</enddate><creator>Niu, Ru-Jie</creator><creator>Zhou, Wen-Fa</creator><creator>Liu, Yan</creator><creator>Yang, Jun-Yi</creator><creator>Zhang, Wen-Hua</creator><creator>Lang, Jian-Ping</creator><creator>Young, David J</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-9047-8881</orcidid><orcidid>https://orcid.org/0000-0003-2942-7385</orcidid></search><sort><creationdate>20190418</creationdate><title>Morphology-dependent third-order optical nonlinearity of a 2D Co-based metal-organic framework with a porphyrinic skeleton</title><author>Niu, Ru-Jie ; Zhou, Wen-Fa ; Liu, Yan ; Yang, Jun-Yi ; Zhang, Wen-Hua ; Lang, Jian-Ping ; Young, David J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-88ddff13465b7dc9b044c5d3a9cff05ccc105ca6bad6effc6d734678cf4790813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Absorptivity</topic><topic>Clusters</topic><topic>Crystal structure</topic><topic>Crystallinity</topic><topic>Crystallography</topic><topic>Metal-organic frameworks</topic><topic>Morphology</topic><topic>Nonlinearity</topic><topic>Optical properties</topic><topic>Polyvinylpyrrolidone</topic><topic>Thin films</topic><topic>Thin plates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Niu, Ru-Jie</creatorcontrib><creatorcontrib>Zhou, Wen-Fa</creatorcontrib><creatorcontrib>Liu, Yan</creatorcontrib><creatorcontrib>Yang, Jun-Yi</creatorcontrib><creatorcontrib>Zhang, Wen-Hua</creatorcontrib><creatorcontrib>Lang, Jian-Ping</creatorcontrib><creatorcontrib>Young, David J</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Niu, Ru-Jie</au><au>Zhou, Wen-Fa</au><au>Liu, Yan</au><au>Yang, Jun-Yi</au><au>Zhang, Wen-Hua</au><au>Lang, Jian-Ping</au><au>Young, David J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Morphology-dependent third-order optical nonlinearity of a 2D Co-based metal-organic framework with a porphyrinic skeleton</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2019-04-18</date><risdate>2019</risdate><volume>55</volume><issue>33</issue><spage>4873</spage><epage>4876</epage><pages>4873-4876</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A two-dimensional (2D) Co-based metal-organic framework (MOF) with porphyrinic skeleton forms crystalline plates, flower-shaped clusters, and ultrathin films under optimized conditions, including the use of polyvinylpyrrolidone (PVP) as a surfactant. Ultrathin films demonstrate the best solution-based third-order nonlinear optical properties, featuring a nonlinear transmittance (
T
) value of 0.54, absorption coefficient (
α
2
) of 9.5 × 10
−10
m W
−1
and second hyperpolarizability (
γ
) value of 1.37 × 10
−28
esu, which are slightly better than those of the flower-shaped clusters (
T
= 0.65,
α
2
= 7.0 × 10
−10
m W
−1
;
γ
= 1.27 × 10
−28
esu), but marginally better than those of the crystalline thin plates (
T
= 0.94,
α
2
= 2.4 × 10
−10
m W
−1
;
γ
= 0.24 × 10
−28
esu).
A two-dimensional (2D) Co-based metal-organic framework (MOF) with a porphyrinic skeleton forms crystalline plates, flower-shaped clusters, and ultrathin films under optimized conditions and these forms give distinctively different nonlinear optical properties.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30951050</pmid><doi>10.1039/c9cc01363f</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-9047-8881</orcidid><orcidid>https://orcid.org/0000-0003-2942-7385</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2019-04, Vol.55 (33), p.4873-4876 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_rsc_primary_c9cc01363f |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Absorptivity Clusters Crystal structure Crystallinity Crystallography Metal-organic frameworks Morphology Nonlinearity Optical properties Polyvinylpyrrolidone Thin films Thin plates |
| title | Morphology-dependent third-order optical nonlinearity of a 2D Co-based metal-organic framework with a porphyrinic skeleton |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-10T19%3A36%3A37IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_rsc_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Morphology-dependent%20third-order%20optical%20nonlinearity%20of%20a%202D%20Co-based%20metal-organic%20framework%20with%20a%20porphyrinic%20skeleton&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Niu,%20Ru-Jie&rft.date=2019-04-18&rft.volume=55&rft.issue=33&rft.spage=4873&rft.epage=4876&rft.pages=4873-4876&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/c9cc01363f&rft_dat=%3Cproquest_rsc_p%3E2210899017%3C/proquest_rsc_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2210899017&rft_id=info:pmid/30951050&rfr_iscdi=true |