Red-emission over a wide range of wavelengths at various temperatures from tetragonal BaCN2:Eu2+Electronic supplementary information (ESI) available: Crystallographic Data (CSD 434273) in CIF format, powder XRD, lattice parameters. See DOI: 10.1039/c8tc01289j
A new polymorph of BaCN 2 was obtained via a simple nitridation reaction of BaCO 3 under an NH 3 flow at 900 °C. The product was analyzed via single crystal X-ray diffraction and infrared spectroscopy, and it was found to have a tetragonal I 4/ mcm crystal structure (space group no. 140) with a = 0....
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