Atomically precise Au144(SR)60 nanoclusters (R = Et, Pr) are capped by 12 distinct ligand types of 5-fold equivalence and display gigantic diastereotopic effectsElectronic supplementary information (ESI) available: Fig. S1-S12, Tables S1-S4, details on the synthesis of the clusters, ICP-MS, ESI-MS, NMR, electrochemistry, EPR, and DFT calculations. See DOI: 10.1039/c8sc04092c

For two decades, Au 144 (SR) 60 has been one of the most studied and used thiolate (SR) protected gold nanoclusters. In many ways, however, it proved to be a challenging and elusive case, also because of the difficulties in solving its structure by single-crystal X-ray crystallography. We used very...

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Hauptverfasser:	Dainese, Tiziano, Agrachev, Mikhail, Antonello, Sabrina, Badocco, Denis, Black, David M, Fortunelli, Alessandro, Gascón, José A, Stener, Mauro, Venzo, Alfonso, Whetten, Robert L, Maran, Flavio
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Sprache:	eng
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