Hydrothermal synthesis of MoS nanosheet loaded TiO nanoarrays for enhanced visible light photocatalytic applications

A molybdenum disulfide (MoS 2 ) nanosheet-decorated titanium dioxide (TiO 2 ) NRA heterojunction composite was fabricated successfully through a two-step hydrothermal approach. Microstructures and optical properties of specimens were characterized by field-emission scanning electron microscopy, X-ra...

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Veröffentlicht in:RSC advances 2019-01, Vol.9 (6), p.3479-3485
Hauptverfasser: Zhang, Miao, Wang, Shun, Li, Ziliang, Liu, Chunwang, Miao, Rui, He, Gang, Zhao, Min, Xue, Jun, Xia, Zhiyuan, Wang, Yongqi, Sun, Zhaoqi, Lv, Jianguo
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container_end_page 3485
container_issue 6
container_start_page 3479
container_title RSC advances
container_volume 9
creator Zhang, Miao
Wang, Shun
Li, Ziliang
Liu, Chunwang
Miao, Rui
He, Gang
Zhao, Min
Xue, Jun
Xia, Zhiyuan
Wang, Yongqi
Sun, Zhaoqi
Lv, Jianguo
description A molybdenum disulfide (MoS 2 ) nanosheet-decorated titanium dioxide (TiO 2 ) NRA heterojunction composite was fabricated successfully through a two-step hydrothermal approach. Microstructures and optical properties of specimens were characterized by field-emission scanning electron microscopy, X-ray diffractometry, X-ray photoelectron spectroscopy, and ultraviolet-visible spectroscopy. The gaps of the TiO 2 nanorods have been filled with tiny MoS 2 nanosheets, which can increase the surface area of MoS 2 /TiO 2 NRA composite thin films. In addition, the photocatalytic activity of the thin films were measured and discussed in greater detail. The appropriate hydrothermal reaction temperature of MoS 2 is important for the growth of perfect MoS 2 /TiO 2 NRA composites with significantly enhanced photocatalytic performance. The photodegradation rate and k value of MoS 2 -220/TiO 2 are 86% and 0.0105 min −1 , respectively, which are much larger than those of blank TiO 2 . The enhanced photocatalytic performance could be attributed to the higher visible light absorption and the reduced recombination rate of photogenerated electron-hole pairs. A molybdenum disulfide (MoS 2 ) nanosheet-decorated titanium dioxide (TiO 2 ) NRA heterojunction composite was fabricated successfully through a two-step hydrothermal approach.
doi_str_mv 10.1039/c8ra09348b
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Microstructures and optical properties of specimens were characterized by field-emission scanning electron microscopy, X-ray diffractometry, X-ray photoelectron spectroscopy, and ultraviolet-visible spectroscopy. The gaps of the TiO 2 nanorods have been filled with tiny MoS 2 nanosheets, which can increase the surface area of MoS 2 /TiO 2 NRA composite thin films. In addition, the photocatalytic activity of the thin films were measured and discussed in greater detail. The appropriate hydrothermal reaction temperature of MoS 2 is important for the growth of perfect MoS 2 /TiO 2 NRA composites with significantly enhanced photocatalytic performance. The photodegradation rate and k value of MoS 2 -220/TiO 2 are 86% and 0.0105 min −1 , respectively, which are much larger than those of blank TiO 2 . The enhanced photocatalytic performance could be attributed to the higher visible light absorption and the reduced recombination rate of photogenerated electron-hole pairs. 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title Hydrothermal synthesis of MoS nanosheet loaded TiO nanoarrays for enhanced visible light photocatalytic applications
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