Highly active copper catalyst obtained through rapid MOF decompositionElectronic supplementary information (ESI) available: Complete synthetic procedures and XPS spectra. See DOI: 10.1039/c8qi01217b

A decomposed copper based metal-organic framework containing amorphous Cu species was found to be a highly reactive carbon supported catalyst ( a-Cu@C ). This catalyst is active for reduction, oxidation, and N -arylation reactions without further tuning or optimization. Higher catalyst turnover numb...

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Hauptverfasser: Nguyen-Sorenson, Anh H. T, Anderson, Clifton M, Balijepalli, Santosh K, McDonald, Kyle A, Matzger, Adam J, Stowers, Kara J
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Anderson, Clifton M
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McDonald, Kyle A
Matzger, Adam J
Stowers, Kara J
description A decomposed copper based metal-organic framework containing amorphous Cu species was found to be a highly reactive carbon supported catalyst ( a-Cu@C ). This catalyst is active for reduction, oxidation, and N -arylation reactions without further tuning or optimization. Higher catalyst turnover numbers for each of these transformations are obtained when comparing a-Cu@C activity to similar Cu-based materials. A decomposed copper based metal-organic framework containing amorphous Cu species was found to be a highly reactive carbon supported catalyst ( a-Cu@C ).
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title Highly active copper catalyst obtained through rapid MOF decompositionElectronic supplementary information (ESI) available: Complete synthetic procedures and XPS spectra. See DOI: 10.1039/c8qi01217b
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