Zwitterionic poly(sulfobetaine methacrylate)s in water: from upper critical solution temperature (UCST) to lower critical solution temperature (LCST) with increasing length of one alkyl substituent on the nitrogen atom

Zwitterionic poly(sulfobetaine methacrylate)s in water: from upper critical solution temperature (UCST) to lower critical solution temperature (LCST) with increasing length of one alkyl substituent on the nitrogen atom

By gradually increasing the length of one linear alkyl substituent from one to seven carbon atoms on the nitrogen atom while keeping another substituent as a methyl group, poly(sulfobetaine methacrylate)s are found to exhibit a wide range of solution behavior in water, ranging from UCST, to totally...

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Veröffentlicht in:Polymer chemistry 2018-11, Vol.9 (43), p.5257-5261
Hauptverfasser: Wang, Ning, Seymour, Bryan T, Lewoczko, Evan M, Kent, Ethan W, Chen, Ming-Li, Wang, Jian-Hua, Zhao, Bin
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Nitrogen
Polymer chemistry
Zwitterions
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container_end_page 5261
container_issue 43
container_start_page 5257
container_title Polymer chemistry
container_volume 9
creator Wang, Ning
Seymour, Bryan T
Lewoczko, Evan M
Kent, Ethan W
Chen, Ming-Li
Wang, Jian-Hua
Zhao, Bin
description By gradually increasing the length of one linear alkyl substituent from one to seven carbon atoms on the nitrogen atom while keeping another substituent as a methyl group, poly(sulfobetaine methacrylate)s are found to exhibit a wide range of solution behavior in water, ranging from UCST, to totally soluble in water, to LCST, and then insoluble in water. Increasing the alkyl length on nitrogen of the polymer changes behaviour from UCST, to soluble, LCST, and insoluble.
doi_str_mv 10.1039/c8py01211c
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source Royal Society Of Chemistry Journals 2008-
subjects Nitrogen
Polymer chemistry
Zwitterions
title Zwitterionic poly(sulfobetaine methacrylate)s in water: from upper critical solution temperature (UCST) to lower critical solution temperature (LCST) with increasing length of one alkyl substituent on the nitrogen atom
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