A multifunctional selective "turn-on" fluorescent chemosensor for detection of Group IIIA ions Al, Ga and In
A versatile chemosensor 1 ( E )-2-(((8-hydroxy-2,3,6,7-tetrahydro-1 H ,5 H -pyrido[3,2,1- ij ]quinolin-9-yl)methylene)amino)-1 H -benzo[ de ]isoquinoline-1,3(2 H )-dione, based on naphthalimide and julolidine moieties, was developed for highly distinguishable and selective recognition of Group IIIA...
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| Veröffentlicht in: | Photochemical & photobiological sciences 2018-09, Vol.17 (9), p.1247-1255 |
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| container_title | Photochemical & photobiological sciences |
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| creator | Jang, Hyo Jung Kang, Ji Hye Yun, Dongju Kim, Cheal |
| description | A versatile chemosensor
1
(
E
)-2-(((8-hydroxy-2,3,6,7-tetrahydro-1
H
,5
H
-pyrido[3,2,1-
ij
]quinolin-9-yl)methylene)amino)-1
H
-benzo[
de
]isoquinoline-1,3(2
H
)-dione, based on naphthalimide and julolidine moieties, was developed for highly distinguishable and selective recognition of Group IIIA metal ions (Al
3+
, Ga
3+
and In
3+
). Sensor
1
exhibited significant 'off-on' fluorescence responses at 488 nm in the presence of Al
3+
and at 570 nm in the presence of Ga
3+
and In
3+
. The same emission of Ga
3+
and In
3+
could be distinguished through different color changes (from colorless to yellow for Ga
3+
and no color change for In
3+
). Binding constants of
1
for Ga
3+
and In
3+
are the highest reported to date for an organic chemosensor. A 2 : 1 binding mode between
1
with Al
3+
, Ga
3+
and In
3+
is proposed based on electrospray ionization mass spectrometry, Job plot analysis, and theoretical calculations.
A versatile chemosensor was developed for highly distinguishable and selective recognition of group IIIA metal ions (Al
3+
, Ga
3+
and In
3+
). |
| doi_str_mv | 10.1039/c8pp00171e |
| format | Article |
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1
(
E
)-2-(((8-hydroxy-2,3,6,7-tetrahydro-1
H
,5
H
-pyrido[3,2,1-
ij
]quinolin-9-yl)methylene)amino)-1
H
-benzo[
de
]isoquinoline-1,3(2
H
)-dione, based on naphthalimide and julolidine moieties, was developed for highly distinguishable and selective recognition of Group IIIA metal ions (Al
3+
, Ga
3+
and In
3+
). Sensor
1
exhibited significant 'off-on' fluorescence responses at 488 nm in the presence of Al
3+
and at 570 nm in the presence of Ga
3+
and In
3+
. The same emission of Ga
3+
and In
3+
could be distinguished through different color changes (from colorless to yellow for Ga
3+
and no color change for In
3+
). Binding constants of
1
for Ga
3+
and In
3+
are the highest reported to date for an organic chemosensor. A 2 : 1 binding mode between
1
with Al
3+
, Ga
3+
and In
3+
is proposed based on electrospray ionization mass spectrometry, Job plot analysis, and theoretical calculations.
A versatile chemosensor was developed for highly distinguishable and selective recognition of group IIIA metal ions (Al
3+
, Ga
3+
and In
3+
).</description><identifier>ISSN: 1474-905X</identifier><identifier>EISSN: 1474-9092</identifier><identifier>DOI: 10.1039/c8pp00171e</identifier><language>eng</language><ispartof>Photochemical & photobiological sciences, 2018-09, Vol.17 (9), p.1247-1255</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Jang, Hyo Jung</creatorcontrib><creatorcontrib>Kang, Ji Hye</creatorcontrib><creatorcontrib>Yun, Dongju</creatorcontrib><creatorcontrib>Kim, Cheal</creatorcontrib><title>A multifunctional selective "turn-on" fluorescent chemosensor for detection of Group IIIA ions Al, Ga and In</title><title>Photochemical & photobiological sciences</title><description>A versatile chemosensor
1
(
E
)-2-(((8-hydroxy-2,3,6,7-tetrahydro-1
H
,5
H
-pyrido[3,2,1-
ij
]quinolin-9-yl)methylene)amino)-1
H
-benzo[
de
]isoquinoline-1,3(2
H
)-dione, based on naphthalimide and julolidine moieties, was developed for highly distinguishable and selective recognition of Group IIIA metal ions (Al
3+
, Ga
3+
and In
3+
). Sensor
1
exhibited significant 'off-on' fluorescence responses at 488 nm in the presence of Al
3+
and at 570 nm in the presence of Ga
3+
and In
3+
. The same emission of Ga
3+
and In
3+
could be distinguished through different color changes (from colorless to yellow for Ga
3+
and no color change for In
3+
). Binding constants of
1
for Ga
3+
and In
3+
are the highest reported to date for an organic chemosensor. A 2 : 1 binding mode between
1
with Al
3+
, Ga
3+
and In
3+
is proposed based on electrospray ionization mass spectrometry, Job plot analysis, and theoretical calculations.
A versatile chemosensor was developed for highly distinguishable and selective recognition of group IIIA metal ions (Al
3+
, Ga
3+
and In
3+
).</description><issn>1474-905X</issn><issn>1474-9092</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpFUMFKxDAUDKLgunrxLjz2bDVpkrY5lsVdCwte9uBtSdMXrKRJSVrBv7eo6GGYYZiZwxByy-gDo1w9mmocKWUlwzOyYqIUmaIqP__T8vWSXKX0vmSkKMoVcTUMs5t6O3sz9cFrBwkdLvoDYTPN0WfBb8C6OURMBv0E5g2HkNCnEMEu6HDC7y4EC_sY5hGapqlhcRLU7h72GrTvoPHX5MJql_Dml9fkuHs6bp-zw8u-2daHLKp8yiQXZWErVinWtdTkomCSay4qFAYlaiYNommLUnDZqjZXlLVWc4tFqwWVBV-Tu5_ZmMxpjP2g4-fp_xn-BedbV70</recordid><startdate>20180912</startdate><enddate>20180912</enddate><creator>Jang, Hyo Jung</creator><creator>Kang, Ji Hye</creator><creator>Yun, Dongju</creator><creator>Kim, Cheal</creator><scope/></search><sort><creationdate>20180912</creationdate><title>A multifunctional selective "turn-on" fluorescent chemosensor for detection of Group IIIA ions Al, Ga and In</title><author>Jang, Hyo Jung ; Kang, Ji Hye ; Yun, Dongju ; Kim, Cheal</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-r92t-53476f81891db0c246153a348e4ce5ea15ceecb67435b9b2901bfa3fe6ba40563</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jang, Hyo Jung</creatorcontrib><creatorcontrib>Kang, Ji Hye</creatorcontrib><creatorcontrib>Yun, Dongju</creatorcontrib><creatorcontrib>Kim, Cheal</creatorcontrib><jtitle>Photochemical & photobiological sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jang, Hyo Jung</au><au>Kang, Ji Hye</au><au>Yun, Dongju</au><au>Kim, Cheal</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A multifunctional selective "turn-on" fluorescent chemosensor for detection of Group IIIA ions Al, Ga and In</atitle><jtitle>Photochemical & photobiological sciences</jtitle><date>2018-09-12</date><risdate>2018</risdate><volume>17</volume><issue>9</issue><spage>1247</spage><epage>1255</epage><pages>1247-1255</pages><issn>1474-905X</issn><eissn>1474-9092</eissn><abstract>A versatile chemosensor
1
(
E
)-2-(((8-hydroxy-2,3,6,7-tetrahydro-1
H
,5
H
-pyrido[3,2,1-
ij
]quinolin-9-yl)methylene)amino)-1
H
-benzo[
de
]isoquinoline-1,3(2
H
)-dione, based on naphthalimide and julolidine moieties, was developed for highly distinguishable and selective recognition of Group IIIA metal ions (Al
3+
, Ga
3+
and In
3+
). Sensor
1
exhibited significant 'off-on' fluorescence responses at 488 nm in the presence of Al
3+
and at 570 nm in the presence of Ga
3+
and In
3+
. The same emission of Ga
3+
and In
3+
could be distinguished through different color changes (from colorless to yellow for Ga
3+
and no color change for In
3+
). Binding constants of
1
for Ga
3+
and In
3+
are the highest reported to date for an organic chemosensor. A 2 : 1 binding mode between
1
with Al
3+
, Ga
3+
and In
3+
is proposed based on electrospray ionization mass spectrometry, Job plot analysis, and theoretical calculations.
A versatile chemosensor was developed for highly distinguishable and selective recognition of group IIIA metal ions (Al
3+
, Ga
3+
and In
3+
).</abstract><doi>10.1039/c8pp00171e</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1474-905X |
| ispartof | Photochemical & photobiological sciences, 2018-09, Vol.17 (9), p.1247-1255 |
| issn | 1474-905X 1474-9092 |
| language | eng |
| recordid | cdi_rsc_primary_c8pp00171e |
| source | Springer Nature - Complete Springer Journals |
| title | A multifunctional selective "turn-on" fluorescent chemosensor for detection of Group IIIA ions Al, Ga and In |
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