Nickel catalyzed site selective C-H functionalization of α-aryl-thioamides

A catalytic site selective intramolecular C-S bond forming reaction is demonstrated for the first time. The C-H bond functionalization of α-aryl-thioacetanilides was efficiently catalyzed by 2 mol% NiBr 2 , resulting in valuable 2-aminobenzo[ b ]thiophenes in moderate to good yields. Furthermore, th...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Organic & biomolecular chemistry 2018, Vol.16 (35), p.645-649
Hauptverfasser:	Bandyopadhyay, Debashruti, Thirupathi, Annaram, Dhage, Nagsen Munjaji, Mohanta, Nirmala, Peruncheralathan, S
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Catalysis Hydrogen bonds Nickel Thiophenes
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!