Partial magnetic ordering in one-dimensional arrays of endofullerene single-molecule magnet peapodsElectronic supplementary information (ESI) available. See DOI: 10.1039/C8NR05386C
The magnetic ordering and bistability of one-dimensional chains of endofullerene Dy 2 ScN@C 80 single-molecule magnets (SMMs) packed inside single-walled carbon nanotubes (SWCNTs) have been studied using high-resolution transmission electron microscopy (HRTEM), X-ray magnetic circular dichroism (XMC...
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| creator | Avdoshenko, Stanislav M Fritz, Fabian Schlesier, Christin Kostanyan, Aram Dreiser, Jan Luysberg, Martina Popov, Alexey A Meyer, Carola Westerström, Rasmus |
| description | The magnetic ordering and bistability of one-dimensional chains of endofullerene Dy
2
ScN@C
80
single-molecule magnets (SMMs) packed inside single-walled carbon nanotubes (SWCNTs) have been studied using high-resolution transmission electron microscopy (HRTEM), X-ray magnetic circular dichroism (XMCD), and
ab initio
calculations. X-ray absorption measurements reveal that the orientation of the encapsulated endofullerenes differs from the isotropic distribution in the bulk sample, indicating a partial ordering of the endofullerenes inside the SWCNTs. The effect of the one-dimensional packing was further investigated by
ab initio
calculations, demonstrating that for specific tube diameters, the encapsulation is leading to energetically preferential orientations of the endohedral clusters. Additionally, element-specific magnetization curves reveal a decreased magnetic bistability of the encapsulated Dy
2
ScN@C
80
SMMs compared to the bulk analog.
Magnetic ordering and bistability of one-dimensional chains of endofullerene Dy
2
ScN@C
80
single-molecule magnets packed inside single-walled carbon nanotubes. |
| doi_str_mv | 10.1039/c8nr05386c |
| format | Article |
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2
ScN@C
80
single-molecule magnets (SMMs) packed inside single-walled carbon nanotubes (SWCNTs) have been studied using high-resolution transmission electron microscopy (HRTEM), X-ray magnetic circular dichroism (XMCD), and
ab initio
calculations. X-ray absorption measurements reveal that the orientation of the encapsulated endofullerenes differs from the isotropic distribution in the bulk sample, indicating a partial ordering of the endofullerenes inside the SWCNTs. The effect of the one-dimensional packing was further investigated by
ab initio
calculations, demonstrating that for specific tube diameters, the encapsulation is leading to energetically preferential orientations of the endohedral clusters. Additionally, element-specific magnetization curves reveal a decreased magnetic bistability of the encapsulated Dy
2
ScN@C
80
SMMs compared to the bulk analog.
Magnetic ordering and bistability of one-dimensional chains of endofullerene Dy
2
ScN@C
80
single-molecule magnets packed inside single-walled carbon nanotubes.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/c8nr05386c</identifier><language>eng</language><creationdate>2018-10</creationdate><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Avdoshenko, Stanislav M</creatorcontrib><creatorcontrib>Fritz, Fabian</creatorcontrib><creatorcontrib>Schlesier, Christin</creatorcontrib><creatorcontrib>Kostanyan, Aram</creatorcontrib><creatorcontrib>Dreiser, Jan</creatorcontrib><creatorcontrib>Luysberg, Martina</creatorcontrib><creatorcontrib>Popov, Alexey A</creatorcontrib><creatorcontrib>Meyer, Carola</creatorcontrib><creatorcontrib>Westerström, Rasmus</creatorcontrib><title>Partial magnetic ordering in one-dimensional arrays of endofullerene single-molecule magnet peapodsElectronic supplementary information (ESI) available. See DOI: 10.1039/C8NR05386C</title><description>The magnetic ordering and bistability of one-dimensional chains of endofullerene Dy
2
ScN@C
80
single-molecule magnets (SMMs) packed inside single-walled carbon nanotubes (SWCNTs) have been studied using high-resolution transmission electron microscopy (HRTEM), X-ray magnetic circular dichroism (XMCD), and
ab initio
calculations. X-ray absorption measurements reveal that the orientation of the encapsulated endofullerenes differs from the isotropic distribution in the bulk sample, indicating a partial ordering of the endofullerenes inside the SWCNTs. The effect of the one-dimensional packing was further investigated by
ab initio
calculations, demonstrating that for specific tube diameters, the encapsulation is leading to energetically preferential orientations of the endohedral clusters. Additionally, element-specific magnetization curves reveal a decreased magnetic bistability of the encapsulated Dy
2
ScN@C
80
SMMs compared to the bulk analog.
Magnetic ordering and bistability of one-dimensional chains of endofullerene Dy
2
ScN@C
80
single-molecule magnets packed inside single-walled carbon nanotubes.</description><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkDFPwzAQhS0EEqWwsCMdGwwpbl1CypoG0QUQZY8O51IZObZ1TpD6v_iBWKjABtOd3j19T--EOJ3KyVSqxZUuHMtrVeR6T4xmci4zpW5m-z97Pj8URzG-SZkvVK5G4uMJuTdoocONo95o8NwQG7cB48A7yhrTkYvGu2RCZtxG8C2Qa3w7WEtMjiAmv6Ws85b0YGkHg0AYfBOrpPbsXYLHIQRLCdgjb1NC67nDPsHholqvLgHf0Vh8tTSBNREsH1e38N2tLB6ev7qVx-KgRRvpZDfH4uyueinvM466Dmy6BK9_X6HG4vyvex2aVv3H-ASwaW8t</recordid><startdate>20181004</startdate><enddate>20181004</enddate><creator>Avdoshenko, Stanislav M</creator><creator>Fritz, Fabian</creator><creator>Schlesier, Christin</creator><creator>Kostanyan, Aram</creator><creator>Dreiser, Jan</creator><creator>Luysberg, Martina</creator><creator>Popov, Alexey A</creator><creator>Meyer, Carola</creator><creator>Westerström, Rasmus</creator><scope/></search><sort><creationdate>20181004</creationdate><title>Partial magnetic ordering in one-dimensional arrays of endofullerene single-molecule magnet peapodsElectronic supplementary information (ESI) available. See DOI: 10.1039/C8NR05386C</title><author>Avdoshenko, Stanislav M ; Fritz, Fabian ; Schlesier, Christin ; Kostanyan, Aram ; Dreiser, Jan ; Luysberg, Martina ; Popov, Alexey A ; Meyer, Carola ; Westerström, Rasmus</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c8nr05386c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Avdoshenko, Stanislav M</creatorcontrib><creatorcontrib>Fritz, Fabian</creatorcontrib><creatorcontrib>Schlesier, Christin</creatorcontrib><creatorcontrib>Kostanyan, Aram</creatorcontrib><creatorcontrib>Dreiser, Jan</creatorcontrib><creatorcontrib>Luysberg, Martina</creatorcontrib><creatorcontrib>Popov, Alexey A</creatorcontrib><creatorcontrib>Meyer, Carola</creatorcontrib><creatorcontrib>Westerström, Rasmus</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Avdoshenko, Stanislav M</au><au>Fritz, Fabian</au><au>Schlesier, Christin</au><au>Kostanyan, Aram</au><au>Dreiser, Jan</au><au>Luysberg, Martina</au><au>Popov, Alexey A</au><au>Meyer, Carola</au><au>Westerström, Rasmus</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Partial magnetic ordering in one-dimensional arrays of endofullerene single-molecule magnet peapodsElectronic supplementary information (ESI) available. See DOI: 10.1039/C8NR05386C</atitle><date>2018-10-04</date><risdate>2018</risdate><volume>1</volume><issue>38</issue><spage>18153</spage><epage>1816</epage><pages>18153-1816</pages><issn>2040-3364</issn><eissn>2040-3372</eissn><abstract>The magnetic ordering and bistability of one-dimensional chains of endofullerene Dy
2
ScN@C
80
single-molecule magnets (SMMs) packed inside single-walled carbon nanotubes (SWCNTs) have been studied using high-resolution transmission electron microscopy (HRTEM), X-ray magnetic circular dichroism (XMCD), and
ab initio
calculations. X-ray absorption measurements reveal that the orientation of the encapsulated endofullerenes differs from the isotropic distribution in the bulk sample, indicating a partial ordering of the endofullerenes inside the SWCNTs. The effect of the one-dimensional packing was further investigated by
ab initio
calculations, demonstrating that for specific tube diameters, the encapsulation is leading to energetically preferential orientations of the endohedral clusters. Additionally, element-specific magnetization curves reveal a decreased magnetic bistability of the encapsulated Dy
2
ScN@C
80
SMMs compared to the bulk analog.
Magnetic ordering and bistability of one-dimensional chains of endofullerene Dy
2
ScN@C
80
single-molecule magnets packed inside single-walled carbon nanotubes.</abstract><doi>10.1039/c8nr05386c</doi><tpages>8</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals |
| title | Partial magnetic ordering in one-dimensional arrays of endofullerene single-molecule magnet peapodsElectronic supplementary information (ESI) available. See DOI: 10.1039/C8NR05386C |
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