Synthesis, structural characterization and transformation of an eight-electron superatomic alloy, [Au@Ag19{S2P(OPr)2}12]Electronic supplementary information (ESI) available: Experimental data of 1 and 2, 31P NMR spectra of 1 and 2, XPS (1), EDS spectra of 1 and 2 and TD-DFT spectra. See DOI: 10.1039/c8nr00172c
Controlling the metal nanoclusters with atomic precision is highly difficult and further studies on their transformation reactions are even more challenging. Herein we report the controlled formation of a silver alloy nanocluster [AuAg 19 {S 2 P(O n Pr) 2 } 12 ] ( 1 ) from an Ag 20 template via a ga...
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