Lanthanide-titanium-oxalate clusters and their degradation products, photocurrent response and photocatalytic behavioursElectronic supplementary information (ESI) available. CCDC 1828904 and 1828905 contain the supplementary crystallographic data for 1 and 2, respectively. Structures of 2 and 3, IR and UV-vis spectra of 1′-3′, crystal data and structural refinement parameters. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8nj02247j
Incorporation of lanthanide ions (Ln) into TiO 2 nanomaterials has recently been proved to be an efficient strategy to explore photoelectric active materials. Herein, three lanthanide-titanium oxo-clusters (LnTOCs), formulated as [Ln 2 Ti 6 O 2 (C 2 O 4 ) 4 (NO 3 ) 2 (O i Pr) 20 ]·2HO i Pr (Ln = La...
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