Lewis acid activated CO2 reduction over a Ni modified Ni-Ge hydroxide driven by visible-infrared lightElectronic supplementary information (ESI) available. See DOI: 10.1039/c8dt04408b
Improvement of light harvesting and reaction kinetics is of great importance for achieving efficient solar-driven CO 2 reduction. Here, a Ni modified low-crystalline Ni-Ge containing hydroxide with Lewis acid sites was synthesized in highly reductive NaBH 4 solution and exhibited 9.3 μmol g cat. −1...
Gespeichert in:
| Hauptverfasser: | , , , , , , , , |
|---|---|
| Format: | Artikel |
| Sprache: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1679 |
|---|---|
| container_issue | 5 |
| container_start_page | 1672 |
| container_title | |
| container_volume | 48 |
| creator | Xin, Zhenyu Lu, Lei Wang, Bing Wang, Xiaohui Zhu, Kai Xu, Zhe Yu, Zhentao Yan, Shicheng Zou, Zhigang |
| description | Improvement of light harvesting and reaction kinetics is of great importance for achieving efficient solar-driven CO
2
reduction. Here, a Ni modified low-crystalline Ni-Ge containing hydroxide with Lewis acid sites was synthesized in highly reductive NaBH
4
solution and exhibited 9.3 μmol g
cat.
−1
h
−1
CO and 3.5 μmol g
cat.
−1
h
−1
CH
4
generation rates under visible light irradiation, and even achieved a 3.8 μmol g
cat.
−1
h
−1
CO evolution under infrared light irradiation. The wide-spectrum light harvesting resulted from the light absorption from the localized surface plasmonic resonance of Ni nanoparticles. In addition, the Lewis acid can activate C&z.dbd;O bonds to decrease the kinetic barriers of CO
2
reduction. The design concept that rationally combines the advantages of expanding the spectral response and activating CO
2
may offer a new strategy for efficient solar energy utilization.
Improvement of light harvesting and reaction kinetics is of great importance for achieving efficient solar-driven CO
2
reduction. |
| doi_str_mv | 10.1039/c8dt04408b |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c8dt04408b</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c8dt04408b</sourcerecordid><originalsourceid>FETCH-rsc_primary_c8dt04408b3</originalsourceid><addsrcrecordid>eNqFjz1PwzAQhi0EEuVjYUe6EYYUxwm0ZS0BKqF2KHvl2Bd6yIkj2zXkl_H3sBCCgYHl7vTeo-d0jJ3lfJzzYnalpjrwsuTTeo-N8nIyyWaiKPd_ZnFzyI68f-VcCH4tRuzjCd_Ig1SkUwkUZUAN85UAh3qXAtuBjehAwpKgtZoaSsCSsgeE7aCdfSeNoB1F7KAeIJKn2mBGXeNkcoChl22oDKrgbEcK_K7vDbbYBekGSJh1rfy6c1GtF5cgoyQjk2IMa0S4Wy1u4e97J-ygkcbj6Xc_Zuf31fP8MXNebXpHbZJvfvHiv_0nmQljNA</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Lewis acid activated CO2 reduction over a Ni modified Ni-Ge hydroxide driven by visible-infrared lightElectronic supplementary information (ESI) available. See DOI: 10.1039/c8dt04408b</title><source>Royal Society Of Chemistry Journals</source><source>Alma/SFX Local Collection</source><creator>Xin, Zhenyu ; Lu, Lei ; Wang, Bing ; Wang, Xiaohui ; Zhu, Kai ; Xu, Zhe ; Yu, Zhentao ; Yan, Shicheng ; Zou, Zhigang</creator><creatorcontrib>Xin, Zhenyu ; Lu, Lei ; Wang, Bing ; Wang, Xiaohui ; Zhu, Kai ; Xu, Zhe ; Yu, Zhentao ; Yan, Shicheng ; Zou, Zhigang</creatorcontrib><description>Improvement of light harvesting and reaction kinetics is of great importance for achieving efficient solar-driven CO
2
reduction. Here, a Ni modified low-crystalline Ni-Ge containing hydroxide with Lewis acid sites was synthesized in highly reductive NaBH
4
solution and exhibited 9.3 μmol g
cat.
−1
h
−1
CO and 3.5 μmol g
cat.
−1
h
−1
CH
4
generation rates under visible light irradiation, and even achieved a 3.8 μmol g
cat.
−1
h
−1
CO evolution under infrared light irradiation. The wide-spectrum light harvesting resulted from the light absorption from the localized surface plasmonic resonance of Ni nanoparticles. In addition, the Lewis acid can activate C&z.dbd;O bonds to decrease the kinetic barriers of CO
2
reduction. The design concept that rationally combines the advantages of expanding the spectral response and activating CO
2
may offer a new strategy for efficient solar energy utilization.
Improvement of light harvesting and reaction kinetics is of great importance for achieving efficient solar-driven CO
2
reduction.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c8dt04408b</identifier><creationdate>2019-01</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27926,27927</link.rule.ids></links><search><creatorcontrib>Xin, Zhenyu</creatorcontrib><creatorcontrib>Lu, Lei</creatorcontrib><creatorcontrib>Wang, Bing</creatorcontrib><creatorcontrib>Wang, Xiaohui</creatorcontrib><creatorcontrib>Zhu, Kai</creatorcontrib><creatorcontrib>Xu, Zhe</creatorcontrib><creatorcontrib>Yu, Zhentao</creatorcontrib><creatorcontrib>Yan, Shicheng</creatorcontrib><creatorcontrib>Zou, Zhigang</creatorcontrib><title>Lewis acid activated CO2 reduction over a Ni modified Ni-Ge hydroxide driven by visible-infrared lightElectronic supplementary information (ESI) available. See DOI: 10.1039/c8dt04408b</title><description>Improvement of light harvesting and reaction kinetics is of great importance for achieving efficient solar-driven CO
2
reduction. Here, a Ni modified low-crystalline Ni-Ge containing hydroxide with Lewis acid sites was synthesized in highly reductive NaBH
4
solution and exhibited 9.3 μmol g
cat.
−1
h
−1
CO and 3.5 μmol g
cat.
−1
h
−1
CH
4
generation rates under visible light irradiation, and even achieved a 3.8 μmol g
cat.
−1
h
−1
CO evolution under infrared light irradiation. The wide-spectrum light harvesting resulted from the light absorption from the localized surface plasmonic resonance of Ni nanoparticles. In addition, the Lewis acid can activate C&z.dbd;O bonds to decrease the kinetic barriers of CO
2
reduction. The design concept that rationally combines the advantages of expanding the spectral response and activating CO
2
may offer a new strategy for efficient solar energy utilization.
Improvement of light harvesting and reaction kinetics is of great importance for achieving efficient solar-driven CO
2
reduction.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjz1PwzAQhi0EEuVjYUe6EYYUxwm0ZS0BKqF2KHvl2Bd6yIkj2zXkl_H3sBCCgYHl7vTeo-d0jJ3lfJzzYnalpjrwsuTTeo-N8nIyyWaiKPd_ZnFzyI68f-VcCH4tRuzjCd_Ig1SkUwkUZUAN85UAh3qXAtuBjehAwpKgtZoaSsCSsgeE7aCdfSeNoB1F7KAeIJKn2mBGXeNkcoChl22oDKrgbEcK_K7vDbbYBekGSJh1rfy6c1GtF5cgoyQjk2IMa0S4Wy1u4e97J-ygkcbj6Xc_Zuf31fP8MXNebXpHbZJvfvHiv_0nmQljNA</recordid><startdate>20190130</startdate><enddate>20190130</enddate><creator>Xin, Zhenyu</creator><creator>Lu, Lei</creator><creator>Wang, Bing</creator><creator>Wang, Xiaohui</creator><creator>Zhu, Kai</creator><creator>Xu, Zhe</creator><creator>Yu, Zhentao</creator><creator>Yan, Shicheng</creator><creator>Zou, Zhigang</creator><scope/></search><sort><creationdate>20190130</creationdate><title>Lewis acid activated CO2 reduction over a Ni modified Ni-Ge hydroxide driven by visible-infrared lightElectronic supplementary information (ESI) available. See DOI: 10.1039/c8dt04408b</title><author>Xin, Zhenyu ; Lu, Lei ; Wang, Bing ; Wang, Xiaohui ; Zhu, Kai ; Xu, Zhe ; Yu, Zhentao ; Yan, Shicheng ; Zou, Zhigang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c8dt04408b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xin, Zhenyu</creatorcontrib><creatorcontrib>Lu, Lei</creatorcontrib><creatorcontrib>Wang, Bing</creatorcontrib><creatorcontrib>Wang, Xiaohui</creatorcontrib><creatorcontrib>Zhu, Kai</creatorcontrib><creatorcontrib>Xu, Zhe</creatorcontrib><creatorcontrib>Yu, Zhentao</creatorcontrib><creatorcontrib>Yan, Shicheng</creatorcontrib><creatorcontrib>Zou, Zhigang</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xin, Zhenyu</au><au>Lu, Lei</au><au>Wang, Bing</au><au>Wang, Xiaohui</au><au>Zhu, Kai</au><au>Xu, Zhe</au><au>Yu, Zhentao</au><au>Yan, Shicheng</au><au>Zou, Zhigang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lewis acid activated CO2 reduction over a Ni modified Ni-Ge hydroxide driven by visible-infrared lightElectronic supplementary information (ESI) available. See DOI: 10.1039/c8dt04408b</atitle><date>2019-01-30</date><risdate>2019</risdate><volume>48</volume><issue>5</issue><spage>1672</spage><epage>1679</epage><pages>1672-1679</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Improvement of light harvesting and reaction kinetics is of great importance for achieving efficient solar-driven CO
2
reduction. Here, a Ni modified low-crystalline Ni-Ge containing hydroxide with Lewis acid sites was synthesized in highly reductive NaBH
4
solution and exhibited 9.3 μmol g
cat.
−1
h
−1
CO and 3.5 μmol g
cat.
−1
h
−1
CH
4
generation rates under visible light irradiation, and even achieved a 3.8 μmol g
cat.
−1
h
−1
CO evolution under infrared light irradiation. The wide-spectrum light harvesting resulted from the light absorption from the localized surface plasmonic resonance of Ni nanoparticles. In addition, the Lewis acid can activate C&z.dbd;O bonds to decrease the kinetic barriers of CO
2
reduction. The design concept that rationally combines the advantages of expanding the spectral response and activating CO
2
may offer a new strategy for efficient solar energy utilization.
Improvement of light harvesting and reaction kinetics is of great importance for achieving efficient solar-driven CO
2
reduction.</abstract><doi>10.1039/c8dt04408b</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | |
| issn | 1477-9226 1477-9234 |
| language | |
| recordid | cdi_rsc_primary_c8dt04408b |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | Lewis acid activated CO2 reduction over a Ni modified Ni-Ge hydroxide driven by visible-infrared lightElectronic supplementary information (ESI) available. See DOI: 10.1039/c8dt04408b |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-18T02%3A28%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Lewis%20acid%20activated%20CO2%20reduction%20over%20a%20Ni%20modified%20Ni-Ge%20hydroxide%20driven%20by%20visible-infrared%20lightElectronic%20supplementary%20information%20(ESI)%20available.%20See%20DOI:%2010.1039/c8dt04408b&rft.au=Xin,%20Zhenyu&rft.date=2019-01-30&rft.volume=48&rft.issue=5&rft.spage=1672&rft.epage=1679&rft.pages=1672-1679&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/c8dt04408b&rft_dat=%3Crsc%3Ec8dt04408b%3C/rsc%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |