Monomeric nickel hydroxide stabilized by a sterically demanding phosphorus-nitrogen PN3P-pincer ligand: synthesis, reactivity and catalysisElectronic supplementary information (ESI) available: NMR and FTIR spectra. CCDC 1817531, 1817541, 1817542, 1817545, 1817553 and 1834798. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8dt03403f
A terminal nickel hydroxide complex (PN 3 P)Ni(OH) ( 3 ) bearing the 2 nd generation phosphorus-nitrogen PN 3 P-pincer ligand has been synthesized and structurally characterized. As a nucleophile, 3 reacts with CO to afford the hydroxycarbonyl complex 4 , (PN 3 P)Ni(COOH). 3 can also activate CO 2 a...
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| creator | Yao, Changguang Chakraborty, Priyanka Aresu, Emanuele Li, Huaifeng Guan, Chao Zhou, Chunhui Liang, Lan-Chang Huang, Kuo-Wei |
| description | A terminal nickel hydroxide complex (PN
3
P)Ni(OH) (
3
) bearing the 2
nd
generation phosphorus-nitrogen PN
3
P-pincer ligand has been synthesized and structurally characterized. As a nucleophile,
3
reacts with CO to afford the hydroxycarbonyl complex
4
, (PN
3
P)Ni(COOH).
3
can also activate CO
2
and CS
2
to produce nickel bicarbonate (PN
3
P)Ni(OCOOH) (
5
) and bimetallic dithiocarbonate [(PN
3
P)NiS]
2
CO (
6
) respectively, as well as to promote aryl isocyanate and isothiocyanate insertion into the Ni-OH bond to give the corresponding (PN
3
P)NiEC(O)NHAr complexes (E = O,
7
; E = S,
8
). In addition,
3
catalyzes the nitrile hydration to various amides with well-defined intermediates (PN
3
P)Ni-NHC(O)R (R = Me,
9
; R = Ph,
10
).
Various new nickel complexes and amides are synthesized using monomeric nickel hydroxide (PN
3
P)Ni(OH) (
3
) as the precursor or catalyst. |
| doi_str_mv | 10.1039/c8dt03403f |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c8dt03403f</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c8dt03403f</sourcerecordid><originalsourceid>FETCH-rsc_primary_c8dt03403f3</originalsourceid><addsrcrecordid>eNp9kc1PAjEQxVejiYhevJuMN00Ad7eLfFwXNnIACXInZTvsVrvtpi3E9a-3fCgHEw6TvmZeXn_T8by7wG8FPuk9p11mfRL5ZHXu1YKo02n2QhJd_Onw5cq7NubD98PQb4e1MztWUhWoeQqSp58oIK-YVl-cIRhLl1zwb2SwrIC6-9ZHhaiAYUEl4zKDMlfGlV6bpuRWqwwlTCdk2iy5TFGD4Jlz9sFU0uZouGmARppavuHWhUoGKbVUVK4zFJi6BMcBZl2WAguUluoKuFwpXVDLlYTH4fvoCeiGckGXAvswGc92Mcl8NANTbiNoC-J4EEPQDTptEjT2IvoT4a9oH0Sb7CKCLok6vW4LEqXBvbPH05X7CCFUpmmZOzbmeB0SxKMEnE-5sTTgkX3PCgYRBm-jPvzfzY13uaLC4O3hrHv3yXAevza1SRel5oUbenG0k7r3cKq_KNnWczrjB5JGqkA</addsrcrecordid><sourcetype>Enrichment Source</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Monomeric nickel hydroxide stabilized by a sterically demanding phosphorus-nitrogen PN3P-pincer ligand: synthesis, reactivity and catalysisElectronic supplementary information (ESI) available: NMR and FTIR spectra. CCDC 1817531, 1817541, 1817542, 1817545, 1817553 and 1834798. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8dt03403f</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Yao, Changguang ; Chakraborty, Priyanka ; Aresu, Emanuele ; Li, Huaifeng ; Guan, Chao ; Zhou, Chunhui ; Liang, Lan-Chang ; Huang, Kuo-Wei</creator><creatorcontrib>Yao, Changguang ; Chakraborty, Priyanka ; Aresu, Emanuele ; Li, Huaifeng ; Guan, Chao ; Zhou, Chunhui ; Liang, Lan-Chang ; Huang, Kuo-Wei</creatorcontrib><description>A terminal nickel hydroxide complex (PN
3
P)Ni(OH) (
3
) bearing the 2
nd
generation phosphorus-nitrogen PN
3
P-pincer ligand has been synthesized and structurally characterized. As a nucleophile,
3
reacts with CO to afford the hydroxycarbonyl complex
4
, (PN
3
P)Ni(COOH).
3
can also activate CO
2
and CS
2
to produce nickel bicarbonate (PN
3
P)Ni(OCOOH) (
5
) and bimetallic dithiocarbonate [(PN
3
P)NiS]
2
CO (
6
) respectively, as well as to promote aryl isocyanate and isothiocyanate insertion into the Ni-OH bond to give the corresponding (PN
3
P)NiEC(O)NHAr complexes (E = O,
7
; E = S,
8
). In addition,
3
catalyzes the nitrile hydration to various amides with well-defined intermediates (PN
3
P)Ni-NHC(O)R (R = Me,
9
; R = Ph,
10
).
Various new nickel complexes and amides are synthesized using monomeric nickel hydroxide (PN
3
P)Ni(OH) (
3
) as the precursor or catalyst.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c8dt03403f</identifier><language>eng</language><creationdate>2018-11</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Yao, Changguang</creatorcontrib><creatorcontrib>Chakraborty, Priyanka</creatorcontrib><creatorcontrib>Aresu, Emanuele</creatorcontrib><creatorcontrib>Li, Huaifeng</creatorcontrib><creatorcontrib>Guan, Chao</creatorcontrib><creatorcontrib>Zhou, Chunhui</creatorcontrib><creatorcontrib>Liang, Lan-Chang</creatorcontrib><creatorcontrib>Huang, Kuo-Wei</creatorcontrib><title>Monomeric nickel hydroxide stabilized by a sterically demanding phosphorus-nitrogen PN3P-pincer ligand: synthesis, reactivity and catalysisElectronic supplementary information (ESI) available: NMR and FTIR spectra. CCDC 1817531, 1817541, 1817542, 1817545, 1817553 and 1834798. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8dt03403f</title><description>A terminal nickel hydroxide complex (PN
3
P)Ni(OH) (
3
) bearing the 2
nd
generation phosphorus-nitrogen PN
3
P-pincer ligand has been synthesized and structurally characterized. As a nucleophile,
3
reacts with CO to afford the hydroxycarbonyl complex
4
, (PN
3
P)Ni(COOH).
3
can also activate CO
2
and CS
2
to produce nickel bicarbonate (PN
3
P)Ni(OCOOH) (
5
) and bimetallic dithiocarbonate [(PN
3
P)NiS]
2
CO (
6
) respectively, as well as to promote aryl isocyanate and isothiocyanate insertion into the Ni-OH bond to give the corresponding (PN
3
P)NiEC(O)NHAr complexes (E = O,
7
; E = S,
8
). In addition,
3
catalyzes the nitrile hydration to various amides with well-defined intermediates (PN
3
P)Ni-NHC(O)R (R = Me,
9
; R = Ph,
10
).
Various new nickel complexes and amides are synthesized using monomeric nickel hydroxide (PN
3
P)Ni(OH) (
3
) as the precursor or catalyst.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNp9kc1PAjEQxVejiYhevJuMN00Ad7eLfFwXNnIACXInZTvsVrvtpi3E9a-3fCgHEw6TvmZeXn_T8by7wG8FPuk9p11mfRL5ZHXu1YKo02n2QhJd_Onw5cq7NubD98PQb4e1MztWUhWoeQqSp58oIK-YVl-cIRhLl1zwb2SwrIC6-9ZHhaiAYUEl4zKDMlfGlV6bpuRWqwwlTCdk2iy5TFGD4Jlz9sFU0uZouGmARppavuHWhUoGKbVUVK4zFJi6BMcBZl2WAguUluoKuFwpXVDLlYTH4fvoCeiGckGXAvswGc92Mcl8NANTbiNoC-J4EEPQDTptEjT2IvoT4a9oH0Sb7CKCLok6vW4LEqXBvbPH05X7CCFUpmmZOzbmeB0SxKMEnE-5sTTgkX3PCgYRBm-jPvzfzY13uaLC4O3hrHv3yXAevza1SRel5oUbenG0k7r3cKq_KNnWczrjB5JGqkA</recordid><startdate>20181122</startdate><enddate>20181122</enddate><creator>Yao, Changguang</creator><creator>Chakraborty, Priyanka</creator><creator>Aresu, Emanuele</creator><creator>Li, Huaifeng</creator><creator>Guan, Chao</creator><creator>Zhou, Chunhui</creator><creator>Liang, Lan-Chang</creator><creator>Huang, Kuo-Wei</creator><scope/></search><sort><creationdate>20181122</creationdate><title>Monomeric nickel hydroxide stabilized by a sterically demanding phosphorus-nitrogen PN3P-pincer ligand: synthesis, reactivity and catalysisElectronic supplementary information (ESI) available: NMR and FTIR spectra. CCDC 1817531, 1817541, 1817542, 1817545, 1817553 and 1834798. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8dt03403f</title><author>Yao, Changguang ; Chakraborty, Priyanka ; Aresu, Emanuele ; Li, Huaifeng ; Guan, Chao ; Zhou, Chunhui ; Liang, Lan-Chang ; Huang, Kuo-Wei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c8dt03403f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yao, Changguang</creatorcontrib><creatorcontrib>Chakraborty, Priyanka</creatorcontrib><creatorcontrib>Aresu, Emanuele</creatorcontrib><creatorcontrib>Li, Huaifeng</creatorcontrib><creatorcontrib>Guan, Chao</creatorcontrib><creatorcontrib>Zhou, Chunhui</creatorcontrib><creatorcontrib>Liang, Lan-Chang</creatorcontrib><creatorcontrib>Huang, Kuo-Wei</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yao, Changguang</au><au>Chakraborty, Priyanka</au><au>Aresu, Emanuele</au><au>Li, Huaifeng</au><au>Guan, Chao</au><au>Zhou, Chunhui</au><au>Liang, Lan-Chang</au><au>Huang, Kuo-Wei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Monomeric nickel hydroxide stabilized by a sterically demanding phosphorus-nitrogen PN3P-pincer ligand: synthesis, reactivity and catalysisElectronic supplementary information (ESI) available: NMR and FTIR spectra. CCDC 1817531, 1817541, 1817542, 1817545, 1817553 and 1834798. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8dt03403f</atitle><date>2018-11-22</date><risdate>2018</risdate><volume>47</volume><issue>45</issue><spage>1657</spage><epage>1665</epage><pages>1657-1665</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A terminal nickel hydroxide complex (PN
3
P)Ni(OH) (
3
) bearing the 2
nd
generation phosphorus-nitrogen PN
3
P-pincer ligand has been synthesized and structurally characterized. As a nucleophile,
3
reacts with CO to afford the hydroxycarbonyl complex
4
, (PN
3
P)Ni(COOH).
3
can also activate CO
2
and CS
2
to produce nickel bicarbonate (PN
3
P)Ni(OCOOH) (
5
) and bimetallic dithiocarbonate [(PN
3
P)NiS]
2
CO (
6
) respectively, as well as to promote aryl isocyanate and isothiocyanate insertion into the Ni-OH bond to give the corresponding (PN
3
P)NiEC(O)NHAr complexes (E = O,
7
; E = S,
8
). In addition,
3
catalyzes the nitrile hydration to various amides with well-defined intermediates (PN
3
P)Ni-NHC(O)R (R = Me,
9
; R = Ph,
10
).
Various new nickel complexes and amides are synthesized using monomeric nickel hydroxide (PN
3
P)Ni(OH) (
3
) as the precursor or catalyst.</abstract><doi>10.1039/c8dt03403f</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Monomeric nickel hydroxide stabilized by a sterically demanding phosphorus-nitrogen PN3P-pincer ligand: synthesis, reactivity and catalysisElectronic supplementary information (ESI) available: NMR and FTIR spectra. CCDC 1817531, 1817541, 1817542, 1817545, 1817553 and 1834798. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8dt03403f |
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