A luminescent dicyanidonitridotechnetium(v) core with tridentate ligand coordination sitesElectronic supplementary information (ESI) available: Experimental details. Atomic coordinates of the optimized geometries by the DFT method. Observed and calculated bond distances and angles. Observed and calculated IR and UV-vis spectral data. CCDC 1851198 and 1851199. For the ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8dt02935k
A novel, luminescent technetium complex, [TcN(CN) 2 bpa] (bpa = bis-(2-pyridylmethyl)amine), with tridentate ligand coordination sites was synthesized and characterized. Photoemission with a maximum wavelength at 666 nm was observed in the solid-state at 296 K. A novel luminescent technetium complex...
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| creator | Yoshimura, Takashi Nagata, Kojiro Shiroyama, Tatsuki Kino, Yasushi Takayama, Tsutomu Sekine, Tsutomu Shinohara, Atsushi |
| description | A novel, luminescent technetium complex, [TcN(CN)
2
bpa] (bpa = bis-(2-pyridylmethyl)amine), with tridentate ligand coordination sites was synthesized and characterized. Photoemission with a maximum wavelength at 666 nm was observed in the solid-state at 296 K.
A novel luminescent technetium complex with tridentate ligand coordination sites was synthesized and characterized. |
| doi_str_mv | 10.1039/c8dt02935k |
| format | Article |
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bpa] (bpa = bis-(2-pyridylmethyl)amine), with tridentate ligand coordination sites was synthesized and characterized. Photoemission with a maximum wavelength at 666 nm was observed in the solid-state at 296 K.
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bpa] (bpa = bis-(2-pyridylmethyl)amine), with tridentate ligand coordination sites was synthesized and characterized. Photoemission with a maximum wavelength at 666 nm was observed in the solid-state at 296 K.
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2
bpa] (bpa = bis-(2-pyridylmethyl)amine), with tridentate ligand coordination sites was synthesized and characterized. Photoemission with a maximum wavelength at 666 nm was observed in the solid-state at 296 K.
A novel luminescent technetium complex with tridentate ligand coordination sites was synthesized and characterized.</abstract><doi>10.1039/c8dt02935k</doi><tpages>4</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | A luminescent dicyanidonitridotechnetium(v) core with tridentate ligand coordination sitesElectronic supplementary information (ESI) available: Experimental details. Atomic coordinates of the optimized geometries by the DFT method. Observed and calculated bond distances and angles. Observed and calculated IR and UV-vis spectral data. CCDC 1851198 and 1851199. For the ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8dt02935k |
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