Tetranuclear and dinuclear phenoxido bridged copper complexes based on unsymmetrical thiosemicarbazone ligandsElectronic supplementary information (ESI) available: 1H NMR for HLMeH and HLMe2 (S1), packing details for 1t and 2d (S2-S5), χMvs. T for 1t and 2d (S6), magnetic orbitals for the broken-symmetry state of complex 1t and 2d (S7). UV-Vis spectra (S8), ESI-MS and isotopic patterns (S9-S11) for 1t and 2d, CV for 1t (S12), spin density plot for 2d and mono-oxidized form (S13), COSY spectra (S

We report on the synthesis of new dinucleating phenol-based "end-off" compartmental ligands HL MeH and HL Me2 bearing two different binding sites, one bis(2-methylpyridyl)aminomethyl (BPA) and one thiosemicarbazone (TSC) site, and their corresponding copper( ii ) complexes 1t and 2d . With...

Ausführliche Beschreibung

Bibliographische Detailangaben

Hauptverfasser:	Isaac, J. A, Mansour, A.-T, David, R, Kochem, A, Philouze, C, Demeshko, S, Meyer, F, Réglier, M, Simaan, A. J, Caldarelli, S, Yemloul, M, Jamet, H, Thibon-Pourret, A, Belle, C
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!