Inductive modulation of tris(phosphinomethyl)phenylborate donation at group VI metals via borate phenyl substituent modificationElectronic supplementary information (ESI) available. CCDC 1824309-1824325. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8dt00703a
A series of zerovalent group VI metal complexes of tris(diisopropylphosphinomethyl)phenylborate ([PhB(CH 2 P i Pr 2 ) 3 ] − , PhBP iPr 3 ), including [PPN][M(CO) 3 (PhBP iPr 3 )] (M = Cr, Mo, W) and the first bimetallics in which PhBP iPr 3 serves as a bridging ligand via binding M(CO) 3 units at th...
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