Comparison of TiO2 and g-C3N4 2D/2D nanocomposites from three synthesis protocols for visible-light induced hydrogen evolutionElectronic supplementary information (ESI) available: The results of TGA and N2 sorption measurements, SEM and low-magnification TEM images, and stability test results. See DOI: 10.1039/c8cy00965a

Knowledge of the interfacial structure of nanocomposite materials is a prerequisite for rational design of nanostructured photocatalysts. Herein, TiO 2 and g-C 3 N 4 2D/2D nanocomposites were fabricated from three distinct synthetic protocols ( i.e. , co-calcination, solvothermal treatment and charg...

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Hauptverfasser: Zhong, Ruyi, Zhang, Zisheng, Luo, Shuqi, Zhang, Z. Conrad, Huang, Limin, Gu, Meng
Format: Artikel
Sprache:eng
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Zusammenfassung:Knowledge of the interfacial structure of nanocomposite materials is a prerequisite for rational design of nanostructured photocatalysts. Herein, TiO 2 and g-C 3 N 4 2D/2D nanocomposites were fabricated from three distinct synthetic protocols ( i.e. , co-calcination, solvothermal treatment and charge-induced aggregation), showing different degrees of enhancement (1.4-6.1 fold) in the visible-light induced photocatalytic hydrogen evolution reaction compared to the simple physical mixture. We propose that the interfacial Ti-O-N covalent bonding promotes the charge carrier transfer and separation more effectively than the electrostatic interaction, thus accelerating the photocatalytic H 2 production. Meanwhile, the exposed surface area of TiO 2 in the composite needs to be enlarged for deposition of the co-catalyst. This research sheds light on the rational design of hybrid nanocomposites based on earth-abundant elements for photocatalysis. Knowledge of the interfacial structure of nanocomposite materials is a prerequisite for rational design of nanostructured photocatalysts.
ISSN:2044-4753
2044-4761
DOI:10.1039/c8cy00965a