Multistep thermal decomposition of granular sodium perborate tetrahydrate: a kinetic approach to complex reactions in solid-gas systemsElectronic supplementary information (ESI) available: S1. Instrumental calibration and baseline correction for thermal analyses; S2. Characterization of sample (Fig. S1); S3. Kinetics of the thermal dehydration process (Fig. S2-S7 and Table S1); S4. Kinetics of the thermal decomposition process (Fig. S8-S12, Table S2 and Fig. S13-S16). See DOI: 10.1039/c8cp01138a
This article demonstrates a kinetic approach to partially overlapping multistep chemical reactions in solid-gas systems as exemplified by the thermal decomposition of granular sodium perborate tetrahydrate. This reaction proceeds via successive thermal dehydration and decomposition occurring at diff...
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