B3@Si12+: strong stabilizing effects of a triatomic cyclic boron unit on tubular silicon clustersElectronic supplementary information (ESI) available. See DOI: 10.1039/c8cp00380g
Remarkably strong effects of the aromatic B 3 cycle in stabilizing tubular silicon clusters were observed for the first time. The doped cluster B 3 @Si 12 + presents a novel structural motif for silicon clusters in which a B 3 cycle is encapsulated into a (6 × 2) Si 12 prism giving rise to a high sy...
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| creator | Pham, Hung Tan Dang, Thi Tuyet Mai Van Duong, Long Tam, Nguyen Minh Nguyen, Minh Tho |
| description | Remarkably strong effects of the aromatic B
3
cycle in stabilizing tubular silicon clusters were observed for the first time. The doped cluster B
3
@Si
12
+
presents a novel structural motif for silicon clusters in which a B
3
cycle is encapsulated into a (6 × 2) Si
12
prism giving rise to a high symmetry stable tubular structure (
D
3h
). A large amount of electron density is transferred to the boron cycle, and the B
3
δ
−
unit not only retains a delocalized bonding pattern within the Si
12
prism but also enables a two-fold aromaticity for the resulting silicon double ring. This double ring can be used as a building block to make longer nanotubes.
Remarkably strong effects of the aromatic B
3
cycle in stabilizing tubular silicon clusters were observed for the first time. |
| doi_str_mv | 10.1039/c8cp00380g |
| format | Article |
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3
cycle in stabilizing tubular silicon clusters were observed for the first time. The doped cluster B
3
@Si
12
+
presents a novel structural motif for silicon clusters in which a B
3
cycle is encapsulated into a (6 × 2) Si
12
prism giving rise to a high symmetry stable tubular structure (
D
3h
). A large amount of electron density is transferred to the boron cycle, and the B
3
δ
−
unit not only retains a delocalized bonding pattern within the Si
12
prism but also enables a two-fold aromaticity for the resulting silicon double ring. This double ring can be used as a building block to make longer nanotubes.
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3
cycle in stabilizing tubular silicon clusters were observed for the first time.</description><identifier>ISSN: 1463-9076</identifier><identifier>EISSN: 1463-9084</identifier><identifier>DOI: 10.1039/c8cp00380g</identifier><language>eng</language><creationdate>2018-03</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Pham, Hung Tan</creatorcontrib><creatorcontrib>Dang, Thi Tuyet Mai</creatorcontrib><creatorcontrib>Van Duong, Long</creatorcontrib><creatorcontrib>Tam, Nguyen Minh</creatorcontrib><creatorcontrib>Nguyen, Minh Tho</creatorcontrib><title>B3@Si12+: strong stabilizing effects of a triatomic cyclic boron unit on tubular silicon clustersElectronic supplementary information (ESI) available. See DOI: 10.1039/c8cp00380g</title><description>Remarkably strong effects of the aromatic B
3
cycle in stabilizing tubular silicon clusters were observed for the first time. The doped cluster B
3
@Si
12
+
presents a novel structural motif for silicon clusters in which a B
3
cycle is encapsulated into a (6 × 2) Si
12
prism giving rise to a high symmetry stable tubular structure (
D
3h
). A large amount of electron density is transferred to the boron cycle, and the B
3
δ
−
unit not only retains a delocalized bonding pattern within the Si
12
prism but also enables a two-fold aromaticity for the resulting silicon double ring. This double ring can be used as a building block to make longer nanotubes.
Remarkably strong effects of the aromatic B
3
cycle in stabilizing tubular silicon clusters were observed for the first time.</description><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFj01LAzEQhoMoWKsX78J4U6Q1MbVuexJ1xZ48rPclG5Mykt2EfAj1Z_kLnYPoQbCn5x3eDxjGjgWfCi4Xl7rSgXNZ8fUOG4nZXE4WvJrt_uib-T47SOmNcy6uhRyxzzt526C4ulhCytEPa4Lq0OEHkjbWGp0TeAsKckSVfY8a9EY7QuepAGXADMRcuuJUhERlTbd2JWUTU-1ogoJUSCUEZ3ozZBU3gIP1sVcZKXxWN6tzUO8KneqcmUJjDDw8r5bw97NDtmeVS-bom2N28li_3D9NYtJtiNjTePsbl9v90__8Nrxa-QUvDW0f</recordid><startdate>20180314</startdate><enddate>20180314</enddate><creator>Pham, Hung Tan</creator><creator>Dang, Thi Tuyet Mai</creator><creator>Van Duong, Long</creator><creator>Tam, Nguyen Minh</creator><creator>Nguyen, Minh Tho</creator><scope/></search><sort><creationdate>20180314</creationdate><title>B3@Si12+: strong stabilizing effects of a triatomic cyclic boron unit on tubular silicon clustersElectronic supplementary information (ESI) available. See DOI: 10.1039/c8cp00380g</title><author>Pham, Hung Tan ; Dang, Thi Tuyet Mai ; Van Duong, Long ; Tam, Nguyen Minh ; Nguyen, Minh Tho</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c8cp00380g3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pham, Hung Tan</creatorcontrib><creatorcontrib>Dang, Thi Tuyet Mai</creatorcontrib><creatorcontrib>Van Duong, Long</creatorcontrib><creatorcontrib>Tam, Nguyen Minh</creatorcontrib><creatorcontrib>Nguyen, Minh Tho</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pham, Hung Tan</au><au>Dang, Thi Tuyet Mai</au><au>Van Duong, Long</au><au>Tam, Nguyen Minh</au><au>Nguyen, Minh Tho</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>B3@Si12+: strong stabilizing effects of a triatomic cyclic boron unit on tubular silicon clustersElectronic supplementary information (ESI) available. See DOI: 10.1039/c8cp00380g</atitle><date>2018-03-14</date><risdate>2018</risdate><volume>2</volume><issue>11</issue><spage>7588</spage><epage>7592</epage><pages>7588-7592</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>Remarkably strong effects of the aromatic B
3
cycle in stabilizing tubular silicon clusters were observed for the first time. The doped cluster B
3
@Si
12
+
presents a novel structural motif for silicon clusters in which a B
3
cycle is encapsulated into a (6 × 2) Si
12
prism giving rise to a high symmetry stable tubular structure (
D
3h
). A large amount of electron density is transferred to the boron cycle, and the B
3
δ
−
unit not only retains a delocalized bonding pattern within the Si
12
prism but also enables a two-fold aromaticity for the resulting silicon double ring. This double ring can be used as a building block to make longer nanotubes.
Remarkably strong effects of the aromatic B
3
cycle in stabilizing tubular silicon clusters were observed for the first time.</abstract><doi>10.1039/c8cp00380g</doi><tpages>5</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | B3@Si12+: strong stabilizing effects of a triatomic cyclic boron unit on tubular silicon clustersElectronic supplementary information (ESI) available. See DOI: 10.1039/c8cp00380g |
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