Structural, electrical and optical properties of epitaxial Ta-doped titania films by MOCVD

This work presented a detailed study on epitaxial Ta-doped titania (TiO 2 :Ta) films deposited via a metal organic chemical vapor deposition method. The effects of Ta dopant concentration on the film microstructure and functional characteristics including electrical and optical properties were syste...

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Veröffentlicht in:CrystEngComm 2018, Vol.2 (36), p.5395-541
Hauptverfasser: Zhao, Wei, He, Linan, Feng, Xianjin, Luan, Caina, Ma, Jin
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creator Zhao, Wei
He, Linan
Feng, Xianjin
Luan, Caina
Ma, Jin
description This work presented a detailed study on epitaxial Ta-doped titania (TiO 2 :Ta) films deposited via a metal organic chemical vapor deposition method. The effects of Ta dopant concentration on the film microstructure and functional characteristics including electrical and optical properties were systematically explored. The results indicated the deposited TiO 2 :Ta films exhibit high crystallization quality, good transparency (>92%) in the visible range, and tunable electrical properties. The maximum carrier mobility (15.4 cm 2 V −1 s −1 ) and minimum resistivity (8.2 × 10 −2 Ω cm) were achieved at Ta concentrations of 1.0% and 4.0%, respectively. The optical band gaps of the deposited films increased from 3.48 to 3.57 eV with the increase of Ta concentration from 0 to 8.0%. Epitaxial Ta-doped TiO 2 films deposited via MOCVD were found to exhibit much improved electrical properties compared to the intrinsic TiO 2 .
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subjects Carrier mobility
Crystallization
Electrical properties
Metalorganic chemical vapor deposition
Optical properties
Organic chemicals
Organic chemistry
Titanium dioxide
title Structural, electrical and optical properties of epitaxial Ta-doped titania films by MOCVD
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