Two luminescent lanthanide-organic frameworks containing bithiophene groups for the selective detection of nitrobenzene and Fe
Two lanthanide-organic frameworks formulated as [Eu 2 (DMTDC) 3 (DEF) 4 ]·DEF·6H 2 O ( 1 ) and [Tb 2 (DMTDC) 3 (DEF) 4 ]·DEF·6H 2 O ( 2 ) (H 2 DMTDC = 3,4-dimethylthieno[2,3- b ]thiophene-2,5-dicarboxylic acid and DEF = N , N -diethylformamide) have been synthesized under solvothermal conditions by...
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| Veröffentlicht in: | CrystEngComm 2018-06, Vol.2 (25), p.369-3619 |
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| creator | Dou, Ai-Na Yang, Li-Bo Fang, Xiao-Dan Yin, Qi Li, Mao-Dong Li, Ju Wang, Mei-Yan Zhu, Ai-Xin Xu, Quan-Qing |
| description | Two lanthanide-organic frameworks formulated as [Eu
2
(DMTDC)
3
(DEF)
4
]·DEF·6H
2
O (
1
) and [Tb
2
(DMTDC)
3
(DEF)
4
]·DEF·6H
2
O (
2
) (H
2
DMTDC = 3,4-dimethylthieno[2,3-
b
]thiophene-2,5-dicarboxylic acid and DEF =
N
,
N
-diethylformamide) have been synthesized under solvothermal conditions by using a bithiophene dicarboxylate organic ligand, H
2
DMTDC. Compounds
1
and
2
are isomorphous and feature 3D frameworks with uninodal six-connected pcu α-Po topology structures. The systematic luminescence experiments reveal that
1
and
2
can be used as fast-response fluorescence sensors for the sensitive detection of nitrobenzene and Fe
3+
ions with favorable recyclability through fluorescence quenching.
Two isostructural lanthanide-organic frameworks containing bithiophene groups can be used as fast-response fluorescent probes for the sensitive detection of nitrobenzene and Fe
3+
ions through fluorescence quenching. |
| doi_str_mv | 10.1039/c8ce00530c |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c8ce00530c</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c8ce00530c</sourcerecordid><originalsourceid>FETCH-LOGICAL-r92t-d3f4c4a0e7d17960d019ff906c569b23f6a545c48851268ea5c28cfb54de213c3</originalsourceid><addsrcrecordid>eNpFkM1KAzEURoMgWKsb90JeYDSZ_HRmKcVqoeCm-5K5uelEZ5IhSS268Nm1KLg6Z3O-xUfIDWd3nIn2HhpAxpRgcEZmXGpdNUyIC3KZ8ytjXHLOZuRre4x0OIw-YAYMhQ4mlN4Eb7GKaf8jQF0yIx5jessUYijGBx_2tPOl93HqMSDdp3iYMnUx0dIjzTggFP-O1GI5WQw0Ohp8SbHD8HlKTLB0hVfk3Jkh4_Uf52S7etwun6vNy9N6-bCpUluXygonQRqGC8sXrWaW8da5lmlQuu1q4bRRUoFsGsVr3aBRUDfgOiUt1lyAmJPb39mUYTclP5r0sfv_R3wDjtVexg</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Two luminescent lanthanide-organic frameworks containing bithiophene groups for the selective detection of nitrobenzene and Fe</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Dou, Ai-Na ; Yang, Li-Bo ; Fang, Xiao-Dan ; Yin, Qi ; Li, Mao-Dong ; Li, Ju ; Wang, Mei-Yan ; Zhu, Ai-Xin ; Xu, Quan-Qing</creator><creatorcontrib>Dou, Ai-Na ; Yang, Li-Bo ; Fang, Xiao-Dan ; Yin, Qi ; Li, Mao-Dong ; Li, Ju ; Wang, Mei-Yan ; Zhu, Ai-Xin ; Xu, Quan-Qing</creatorcontrib><description>Two lanthanide-organic frameworks formulated as [Eu
2
(DMTDC)
3
(DEF)
4
]·DEF·6H
2
O (
1
) and [Tb
2
(DMTDC)
3
(DEF)
4
]·DEF·6H
2
O (
2
) (H
2
DMTDC = 3,4-dimethylthieno[2,3-
b
]thiophene-2,5-dicarboxylic acid and DEF =
N
,
N
-diethylformamide) have been synthesized under solvothermal conditions by using a bithiophene dicarboxylate organic ligand, H
2
DMTDC. Compounds
1
and
2
are isomorphous and feature 3D frameworks with uninodal six-connected pcu α-Po topology structures. The systematic luminescence experiments reveal that
1
and
2
can be used as fast-response fluorescence sensors for the sensitive detection of nitrobenzene and Fe
3+
ions with favorable recyclability through fluorescence quenching.
Two isostructural lanthanide-organic frameworks containing bithiophene groups can be used as fast-response fluorescent probes for the sensitive detection of nitrobenzene and Fe
3+
ions through fluorescence quenching.</description><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/c8ce00530c</identifier><language>eng</language><ispartof>CrystEngComm, 2018-06, Vol.2 (25), p.369-3619</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Dou, Ai-Na</creatorcontrib><creatorcontrib>Yang, Li-Bo</creatorcontrib><creatorcontrib>Fang, Xiao-Dan</creatorcontrib><creatorcontrib>Yin, Qi</creatorcontrib><creatorcontrib>Li, Mao-Dong</creatorcontrib><creatorcontrib>Li, Ju</creatorcontrib><creatorcontrib>Wang, Mei-Yan</creatorcontrib><creatorcontrib>Zhu, Ai-Xin</creatorcontrib><creatorcontrib>Xu, Quan-Qing</creatorcontrib><title>Two luminescent lanthanide-organic frameworks containing bithiophene groups for the selective detection of nitrobenzene and Fe</title><title>CrystEngComm</title><description>Two lanthanide-organic frameworks formulated as [Eu
2
(DMTDC)
3
(DEF)
4
]·DEF·6H
2
O (
1
) and [Tb
2
(DMTDC)
3
(DEF)
4
]·DEF·6H
2
O (
2
) (H
2
DMTDC = 3,4-dimethylthieno[2,3-
b
]thiophene-2,5-dicarboxylic acid and DEF =
N
,
N
-diethylformamide) have been synthesized under solvothermal conditions by using a bithiophene dicarboxylate organic ligand, H
2
DMTDC. Compounds
1
and
2
are isomorphous and feature 3D frameworks with uninodal six-connected pcu α-Po topology structures. The systematic luminescence experiments reveal that
1
and
2
can be used as fast-response fluorescence sensors for the sensitive detection of nitrobenzene and Fe
3+
ions with favorable recyclability through fluorescence quenching.
Two isostructural lanthanide-organic frameworks containing bithiophene groups can be used as fast-response fluorescent probes for the sensitive detection of nitrobenzene and Fe
3+
ions through fluorescence quenching.</description><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpFkM1KAzEURoMgWKsb90JeYDSZ_HRmKcVqoeCm-5K5uelEZ5IhSS268Nm1KLg6Z3O-xUfIDWd3nIn2HhpAxpRgcEZmXGpdNUyIC3KZ8ytjXHLOZuRre4x0OIw-YAYMhQ4mlN4Eb7GKaf8jQF0yIx5jessUYijGBx_2tPOl93HqMSDdp3iYMnUx0dIjzTggFP-O1GI5WQw0Ohp8SbHD8HlKTLB0hVfk3Jkh4_Uf52S7etwun6vNy9N6-bCpUluXygonQRqGC8sXrWaW8da5lmlQuu1q4bRRUoFsGsVr3aBRUDfgOiUt1lyAmJPb39mUYTclP5r0sfv_R3wDjtVexg</recordid><startdate>20180626</startdate><enddate>20180626</enddate><creator>Dou, Ai-Na</creator><creator>Yang, Li-Bo</creator><creator>Fang, Xiao-Dan</creator><creator>Yin, Qi</creator><creator>Li, Mao-Dong</creator><creator>Li, Ju</creator><creator>Wang, Mei-Yan</creator><creator>Zhu, Ai-Xin</creator><creator>Xu, Quan-Qing</creator><scope/></search><sort><creationdate>20180626</creationdate><title>Two luminescent lanthanide-organic frameworks containing bithiophene groups for the selective detection of nitrobenzene and Fe</title><author>Dou, Ai-Na ; Yang, Li-Bo ; Fang, Xiao-Dan ; Yin, Qi ; Li, Mao-Dong ; Li, Ju ; Wang, Mei-Yan ; Zhu, Ai-Xin ; Xu, Quan-Qing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-r92t-d3f4c4a0e7d17960d019ff906c569b23f6a545c48851268ea5c28cfb54de213c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dou, Ai-Na</creatorcontrib><creatorcontrib>Yang, Li-Bo</creatorcontrib><creatorcontrib>Fang, Xiao-Dan</creatorcontrib><creatorcontrib>Yin, Qi</creatorcontrib><creatorcontrib>Li, Mao-Dong</creatorcontrib><creatorcontrib>Li, Ju</creatorcontrib><creatorcontrib>Wang, Mei-Yan</creatorcontrib><creatorcontrib>Zhu, Ai-Xin</creatorcontrib><creatorcontrib>Xu, Quan-Qing</creatorcontrib><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dou, Ai-Na</au><au>Yang, Li-Bo</au><au>Fang, Xiao-Dan</au><au>Yin, Qi</au><au>Li, Mao-Dong</au><au>Li, Ju</au><au>Wang, Mei-Yan</au><au>Zhu, Ai-Xin</au><au>Xu, Quan-Qing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Two luminescent lanthanide-organic frameworks containing bithiophene groups for the selective detection of nitrobenzene and Fe</atitle><jtitle>CrystEngComm</jtitle><date>2018-06-26</date><risdate>2018</risdate><volume>2</volume><issue>25</issue><spage>369</spage><epage>3619</epage><pages>369-3619</pages><eissn>1466-8033</eissn><abstract>Two lanthanide-organic frameworks formulated as [Eu
2
(DMTDC)
3
(DEF)
4
]·DEF·6H
2
O (
1
) and [Tb
2
(DMTDC)
3
(DEF)
4
]·DEF·6H
2
O (
2
) (H
2
DMTDC = 3,4-dimethylthieno[2,3-
b
]thiophene-2,5-dicarboxylic acid and DEF =
N
,
N
-diethylformamide) have been synthesized under solvothermal conditions by using a bithiophene dicarboxylate organic ligand, H
2
DMTDC. Compounds
1
and
2
are isomorphous and feature 3D frameworks with uninodal six-connected pcu α-Po topology structures. The systematic luminescence experiments reveal that
1
and
2
can be used as fast-response fluorescence sensors for the sensitive detection of nitrobenzene and Fe
3+
ions with favorable recyclability through fluorescence quenching.
Two isostructural lanthanide-organic frameworks containing bithiophene groups can be used as fast-response fluorescent probes for the sensitive detection of nitrobenzene and Fe
3+
ions through fluorescence quenching.</abstract><doi>10.1039/c8ce00530c</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 1466-8033 |
| ispartof | CrystEngComm, 2018-06, Vol.2 (25), p.369-3619 |
| issn | 1466-8033 |
| language | eng |
| recordid | cdi_rsc_primary_c8ce00530c |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Two luminescent lanthanide-organic frameworks containing bithiophene groups for the selective detection of nitrobenzene and Fe |
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