Homogeneously-catalysed hydrogen release/storage using the 2-methylindole/2-methylindoline LOHC system in molten salt-organic biphasic reaction systems
Ir-Complex catalysed hydrogen release/storage using a 2-methylindole/2-methylindoline Liquid Organic Hydrogen Carrier (LOHC) system is shown to be effective in a temperature range of 120 to 140 °C. In the form of a liquid-liquid biphasic reaction system with molten [PPh 4 ][NTf 2 ] as catalyst immob...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2019-02, Vol.55 (14), p.246-249 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Søgaard, Alexander Scheuermeyer, Marlene Bösmann, Andreas Wasserscheid, Peter Riisager, Anders |
| description | Ir-Complex catalysed hydrogen release/storage using a 2-methylindole/2-methylindoline Liquid Organic Hydrogen Carrier (LOHC) system is shown to be effective in a temperature range of 120 to 140 °C. In the form of a liquid-liquid biphasic reaction system with molten [PPh
4
][NTf
2
] as catalyst immobilisation phase, the applied cationic Ir-complex can be easily separated and recycled enabling a small amount of ionic catalyst solution to store/release a large amount of hydrogen.
Hydrogenation/dehydrogenation is effectively catalyzed by a molten salt immobilized Ir-complex in a temperature range of 120 to 140 °C in a 2-methylindole/2-methylindoline Liquid Hydrogen Carrier (LOHC) system. |
| doi_str_mv | 10.1039/c8cc09883b |
| format | Article |
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4
][NTf
2
] as catalyst immobilisation phase, the applied cationic Ir-complex can be easily separated and recycled enabling a small amount of ionic catalyst solution to store/release a large amount of hydrogen.
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4
][NTf
2
] as catalyst immobilisation phase, the applied cationic Ir-complex can be easily separated and recycled enabling a small amount of ionic catalyst solution to store/release a large amount of hydrogen.
Hydrogenation/dehydrogenation is effectively catalyzed by a molten salt immobilized Ir-complex in a temperature range of 120 to 140 °C in a 2-methylindole/2-methylindoline Liquid Hydrogen Carrier (LOHC) system.</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Hydrogen</subject><subject>Hydrogen storage</subject><subject>Molten salts</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kU2P0zAQhiMEYj_gwh1ktBeEFBp_1c4RItiuVGkvi8Qtcpxp65UTF49zyC_h7-Juy6LlgH3wWO-jd0bzFsUbWn2iFa8XVltb1Vrz7llxTvlSlFLoH88PtaxLxYU8Ky4Q76t8qNQvizNeLbXSUp0Xv1ZhCFsYIUzo59KaZPyM0JPd3MeDQCJ4MAgLTCGaLZAJ3bglaQeElQOk3ezd2AcPiydfNwJZ364agjMmGIgbyRB8yn5ofCpD3JrRWdK5_c5gLiIYm1wYTzy-Kl5sjEd4fXovi-_fvt41q3J9e33TfF6XVlQilayTlGtqOGcgFGOy5lqrjaLMqtp2SoBayrriluZbM5G79B1Iq5joOQfJL4sPR999DD8nwNQODi14bx5W0jKqasFyi2VGr_5B78MUxzzdgdKSK8F5pj4eKRsDYoRNu49uMHFuadUe4mob3TQPcX3J8LuT5dQN0D-if_LJwNsjENE-qn_zzvr7_-ntvt_w37tHp34</recordid><startdate>20190212</startdate><enddate>20190212</enddate><creator>Søgaard, Alexander</creator><creator>Scheuermeyer, Marlene</creator><creator>Bösmann, Andreas</creator><creator>Wasserscheid, Peter</creator><creator>Riisager, Anders</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-7086-1143</orcidid><orcidid>https://orcid.org/0000-0001-6564-3945</orcidid><orcidid>https://orcid.org/0000-0003-0413-9539</orcidid><orcidid>https://orcid.org/0000-0002-9523-4330</orcidid></search><sort><creationdate>20190212</creationdate><title>Homogeneously-catalysed hydrogen release/storage using the 2-methylindole/2-methylindoline LOHC system in molten salt-organic biphasic reaction systems</title><author>Søgaard, Alexander ; Scheuermeyer, Marlene ; Bösmann, Andreas ; Wasserscheid, Peter ; Riisager, Anders</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c404t-2b51381a332e4722593887f712c79cb74e765903c1c1c924eacdbe5c724d33e53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Catalysis</topic><topic>Catalysts</topic><topic>Hydrogen</topic><topic>Hydrogen storage</topic><topic>Molten salts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Søgaard, Alexander</creatorcontrib><creatorcontrib>Scheuermeyer, Marlene</creatorcontrib><creatorcontrib>Bösmann, Andreas</creatorcontrib><creatorcontrib>Wasserscheid, Peter</creatorcontrib><creatorcontrib>Riisager, Anders</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Søgaard, Alexander</au><au>Scheuermeyer, Marlene</au><au>Bösmann, Andreas</au><au>Wasserscheid, Peter</au><au>Riisager, Anders</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Homogeneously-catalysed hydrogen release/storage using the 2-methylindole/2-methylindoline LOHC system in molten salt-organic biphasic reaction systems</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2019-02-12</date><risdate>2019</risdate><volume>55</volume><issue>14</issue><spage>246</spage><epage>249</epage><pages>246-249</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Ir-Complex catalysed hydrogen release/storage using a 2-methylindole/2-methylindoline Liquid Organic Hydrogen Carrier (LOHC) system is shown to be effective in a temperature range of 120 to 140 °C. In the form of a liquid-liquid biphasic reaction system with molten [PPh
4
][NTf
2
] as catalyst immobilisation phase, the applied cationic Ir-complex can be easily separated and recycled enabling a small amount of ionic catalyst solution to store/release a large amount of hydrogen.
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| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2019-02, Vol.55 (14), p.246-249 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_rsc_primary_c8cc09883b |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Catalysis Catalysts Hydrogen Hydrogen storage Molten salts |
| title | Homogeneously-catalysed hydrogen release/storage using the 2-methylindole/2-methylindoline LOHC system in molten salt-organic biphasic reaction systems |
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