Palladium(0)-catalyzed C(sp3)-Si bond formation via formal carbene insertion into a Si-H bondElectronic supplementary information (ESI) available: Experimental details, and characterization data. See DOI: 10.1039/c8cc06768f
Pd(0)-Catalyzed formal carbene insertion into Si-H bonds has been achieved as an efficient method for C(sp 3 )-Si bond formation. The reaction, which uses readily available N -tosylhydrazones as the diazo precursors, is highly efficient and shows a wide substrate scope. Rh( ii ) and Cu( i ) salts, w...
Gespeichert in:
| Hauptverfasser: | , , , , , , |
|---|---|
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 11422 |
|---|---|
| container_issue | 81 |
| container_start_page | 11419 |
| container_title | |
| container_volume | 54 |
| creator | Liu, Zhenxing Huo, Jingfeng Fu, Tianren Tan, Haocheng Ye, Fei Hossain, Mohammad Lokman Wang, Jianbo |
| description | Pd(0)-Catalyzed formal carbene insertion into Si-H bonds has been achieved as an efficient method for C(sp
3
)-Si bond formation. The reaction, which uses readily available
N
-tosylhydrazones as the diazo precursors, is highly efficient and shows a wide substrate scope. Rh(
ii
) and Cu(
i
) salts, which are the widely used catalysts for carbene insertion reactions, have been proved to be ineffective for the current reaction. A Pd(
ii
) carbene migratory insertion/reductive elimination mechanism is proposed.
Pd(0)-Catalyzed formal carbene insertion into Si-H bonds has been achieved as an efficient method for C(sp
3
)-Si bond formation. |
| doi_str_mv | 10.1039/c8cc06768f |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c8cc06768f</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c8cc06768f</sourcerecordid><originalsourceid>FETCH-rsc_primary_c8cc06768f3</originalsourceid><addsrcrecordid>eNp9UE1Lw0AQXUTBWr14F8ZbAqYmpEnTXttIe1KIB29hspniymYTdrfF9s_6V9ymQg9C5zIzvI95DGP3UTiKwnj6zDPOw3SSZusLNojidBwk4-zj8jAn02ASj5NrdmPMV-gqSrIB-3lDKbEWm8YL_YCjRbnbUw1zz3SxHxQCqlbVsG51g1a0CrYCj5sEjroiRSCUId2DQtkWEAoRLHtdLolb3SrBwWy6TlJDyqLeOeLJ0cuLlQ-4RSGxkjSD_LsjLXqqhJqsA8wToIvBP1Ejtw7dH7W1CzyCgggWr6sZ_H_DLbtaozR099eH7OElf58vA2142bkrLk15osdD9ngOL7v6wDnv8Qs1OH0I</addsrcrecordid><sourcetype>Enrichment Source</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Palladium(0)-catalyzed C(sp3)-Si bond formation via formal carbene insertion into a Si-H bondElectronic supplementary information (ESI) available: Experimental details, and characterization data. See DOI: 10.1039/c8cc06768f</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Liu, Zhenxing ; Huo, Jingfeng ; Fu, Tianren ; Tan, Haocheng ; Ye, Fei ; Hossain, Mohammad Lokman ; Wang, Jianbo</creator><creatorcontrib>Liu, Zhenxing ; Huo, Jingfeng ; Fu, Tianren ; Tan, Haocheng ; Ye, Fei ; Hossain, Mohammad Lokman ; Wang, Jianbo</creatorcontrib><description>Pd(0)-Catalyzed formal carbene insertion into Si-H bonds has been achieved as an efficient method for C(sp
3
)-Si bond formation. The reaction, which uses readily available
N
-tosylhydrazones as the diazo precursors, is highly efficient and shows a wide substrate scope. Rh(
ii
) and Cu(
i
) salts, which are the widely used catalysts for carbene insertion reactions, have been proved to be ineffective for the current reaction. A Pd(
ii
) carbene migratory insertion/reductive elimination mechanism is proposed.
Pd(0)-Catalyzed formal carbene insertion into Si-H bonds has been achieved as an efficient method for C(sp
3
)-Si bond formation.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c8cc06768f</identifier><language>eng</language><creationdate>2018-10</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Liu, Zhenxing</creatorcontrib><creatorcontrib>Huo, Jingfeng</creatorcontrib><creatorcontrib>Fu, Tianren</creatorcontrib><creatorcontrib>Tan, Haocheng</creatorcontrib><creatorcontrib>Ye, Fei</creatorcontrib><creatorcontrib>Hossain, Mohammad Lokman</creatorcontrib><creatorcontrib>Wang, Jianbo</creatorcontrib><title>Palladium(0)-catalyzed C(sp3)-Si bond formation via formal carbene insertion into a Si-H bondElectronic supplementary information (ESI) available: Experimental details, and characterization data. See DOI: 10.1039/c8cc06768f</title><description>Pd(0)-Catalyzed formal carbene insertion into Si-H bonds has been achieved as an efficient method for C(sp
3
)-Si bond formation. The reaction, which uses readily available
N
-tosylhydrazones as the diazo precursors, is highly efficient and shows a wide substrate scope. Rh(
ii
) and Cu(
i
) salts, which are the widely used catalysts for carbene insertion reactions, have been proved to be ineffective for the current reaction. A Pd(
ii
) carbene migratory insertion/reductive elimination mechanism is proposed.
Pd(0)-Catalyzed formal carbene insertion into Si-H bonds has been achieved as an efficient method for C(sp
3
)-Si bond formation.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNp9UE1Lw0AQXUTBWr14F8ZbAqYmpEnTXttIe1KIB29hspniymYTdrfF9s_6V9ymQg9C5zIzvI95DGP3UTiKwnj6zDPOw3SSZusLNojidBwk4-zj8jAn02ASj5NrdmPMV-gqSrIB-3lDKbEWm8YL_YCjRbnbUw1zz3SxHxQCqlbVsG51g1a0CrYCj5sEjroiRSCUId2DQtkWEAoRLHtdLolb3SrBwWy6TlJDyqLeOeLJ0cuLlQ-4RSGxkjSD_LsjLXqqhJqsA8wToIvBP1Ejtw7dH7W1CzyCgggWr6sZ_H_DLbtaozR099eH7OElf58vA2142bkrLk15osdD9ngOL7v6wDnv8Qs1OH0I</recordid><startdate>20181009</startdate><enddate>20181009</enddate><creator>Liu, Zhenxing</creator><creator>Huo, Jingfeng</creator><creator>Fu, Tianren</creator><creator>Tan, Haocheng</creator><creator>Ye, Fei</creator><creator>Hossain, Mohammad Lokman</creator><creator>Wang, Jianbo</creator><scope/></search><sort><creationdate>20181009</creationdate><title>Palladium(0)-catalyzed C(sp3)-Si bond formation via formal carbene insertion into a Si-H bondElectronic supplementary information (ESI) available: Experimental details, and characterization data. See DOI: 10.1039/c8cc06768f</title><author>Liu, Zhenxing ; Huo, Jingfeng ; Fu, Tianren ; Tan, Haocheng ; Ye, Fei ; Hossain, Mohammad Lokman ; Wang, Jianbo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c8cc06768f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Zhenxing</creatorcontrib><creatorcontrib>Huo, Jingfeng</creatorcontrib><creatorcontrib>Fu, Tianren</creatorcontrib><creatorcontrib>Tan, Haocheng</creatorcontrib><creatorcontrib>Ye, Fei</creatorcontrib><creatorcontrib>Hossain, Mohammad Lokman</creatorcontrib><creatorcontrib>Wang, Jianbo</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Zhenxing</au><au>Huo, Jingfeng</au><au>Fu, Tianren</au><au>Tan, Haocheng</au><au>Ye, Fei</au><au>Hossain, Mohammad Lokman</au><au>Wang, Jianbo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Palladium(0)-catalyzed C(sp3)-Si bond formation via formal carbene insertion into a Si-H bondElectronic supplementary information (ESI) available: Experimental details, and characterization data. See DOI: 10.1039/c8cc06768f</atitle><date>2018-10-09</date><risdate>2018</risdate><volume>54</volume><issue>81</issue><spage>11419</spage><epage>11422</epage><pages>11419-11422</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Pd(0)-Catalyzed formal carbene insertion into Si-H bonds has been achieved as an efficient method for C(sp
3
)-Si bond formation. The reaction, which uses readily available
N
-tosylhydrazones as the diazo precursors, is highly efficient and shows a wide substrate scope. Rh(
ii
) and Cu(
i
) salts, which are the widely used catalysts for carbene insertion reactions, have been proved to be ineffective for the current reaction. A Pd(
ii
) carbene migratory insertion/reductive elimination mechanism is proposed.
Pd(0)-Catalyzed formal carbene insertion into Si-H bonds has been achieved as an efficient method for C(sp
3
)-Si bond formation.</abstract><doi>10.1039/c8cc06768f</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_rsc_primary_c8cc06768f |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Palladium(0)-catalyzed C(sp3)-Si bond formation via formal carbene insertion into a Si-H bondElectronic supplementary information (ESI) available: Experimental details, and characterization data. See DOI: 10.1039/c8cc06768f |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-11T00%3A45%3A49IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Palladium(0)-catalyzed%20C(sp3)-Si%20bond%20formation%20via%20formal%20carbene%20insertion%20into%20a%20Si-H%20bondElectronic%20supplementary%20information%20(ESI)%20available:%20Experimental%20details,%20and%20characterization%20data.%20See%20DOI:%2010.1039/c8cc06768f&rft.au=Liu,%20Zhenxing&rft.date=2018-10-09&rft.volume=54&rft.issue=81&rft.spage=11419&rft.epage=11422&rft.pages=11419-11422&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/c8cc06768f&rft_dat=%3Crsc%3Ec8cc06768f%3C/rsc%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |