Metallaaromatic biaryl atropisomers
Synthesis of stable irida-binaphthyl and -phenanthryl complexes, the first examples of metallaaromatic biaryl atropisomers, has been achieved. The combination of experimental and theoretical studies revealed that the nature of these systems is comparable to that of well-known 1,1′-binaphthalene both...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018-09, Vol.54 (78), p.1974-1976 |
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| container_end_page | 1976 |
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| container_issue | 78 |
| container_start_page | 1974 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 54 |
| creator | Talavera, M Peña-Gallego, A Alonso-Gómez, J. L Bolaño, S |
| description | Synthesis of stable irida-binaphthyl and -phenanthryl complexes, the first examples of metallaaromatic biaryl atropisomers, has been achieved. The combination of experimental and theoretical studies revealed that the nature of these systems is comparable to that of well-known 1,1′-binaphthalene both in terms of aromaticity and atropisomerism.
The birth of metallaaromatic biaryl atropisomers: synthesis, structural elucidation, and theoretical analysis of the first examples is reported. |
| doi_str_mv | 10.1039/c8cc06443a |
| format | Article |
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| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2018-09, Vol.54 (78), p.1974-1976 |
| issn | 1359-7345 1364-548X |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Aromaticity Mass spectra NMR Nuclear magnetic resonance |
| title | Metallaaromatic biaryl atropisomers |
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