Charge effects regulate reversible CO2 reduction catalysisElectronic supplementary information (ESI) available: Synthetic procedures, spectroscopic characterization, and tabulated data. See DOI: 10.1039/c8cc04370a
Modular but geometrically constrained ligands were used to investigate the impact of key ligand design parameters (charge and bite angle) on CO 2 hydrogenation and formic acid dehydrogenation activity. These studies yielded an optimized catalyst that achieved over 118 000 turnovers in CO 2 hydrogena...
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| creator | Geri, Jacob B Ciatti, Joanna L Szymczak, Nathaniel K |
| description | Modular but geometrically constrained ligands were used to investigate the impact of key ligand design parameters (charge and bite angle) on CO
2
hydrogenation and formic acid dehydrogenation activity. These studies yielded an optimized catalyst that achieved over 118 000 turnovers in CO
2
hydrogenation, 247 000 turnovers in HCO
2
H dehydrogenation, was applied in a hydrogen storage device used for 6 cycles of hydrogen storage/release without requiring changes in pH or solvent, and generated H
2
/CO
2
gas at a pressure of 190 atm from formic acid.
Modular but geometrically constrained ligands were used to investigate the impact of key ligand design parameters (charge and bite angle) on CO
2
hydrogenation and formic acid dehydrogenation activity. |
| doi_str_mv | 10.1039/c8cc04370a |
| format | Article |
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2
hydrogenation and formic acid dehydrogenation activity. These studies yielded an optimized catalyst that achieved over 118 000 turnovers in CO
2
hydrogenation, 247 000 turnovers in HCO
2
H dehydrogenation, was applied in a hydrogen storage device used for 6 cycles of hydrogen storage/release without requiring changes in pH or solvent, and generated H
2
/CO
2
gas at a pressure of 190 atm from formic acid.
Modular but geometrically constrained ligands were used to investigate the impact of key ligand design parameters (charge and bite angle) on CO
2
hydrogenation and formic acid dehydrogenation activity.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c8cc04370a</identifier><language>eng</language><creationdate>2018-07</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Geri, Jacob B</creatorcontrib><creatorcontrib>Ciatti, Joanna L</creatorcontrib><creatorcontrib>Szymczak, Nathaniel K</creatorcontrib><title>Charge effects regulate reversible CO2 reduction catalysisElectronic supplementary information (ESI) available: Synthetic procedures, spectroscopic characterization, and tabulated data. See DOI: 10.1039/c8cc04370a</title><description>Modular but geometrically constrained ligands were used to investigate the impact of key ligand design parameters (charge and bite angle) on CO
2
hydrogenation and formic acid dehydrogenation activity. These studies yielded an optimized catalyst that achieved over 118 000 turnovers in CO
2
hydrogenation, 247 000 turnovers in HCO
2
H dehydrogenation, was applied in a hydrogen storage device used for 6 cycles of hydrogen storage/release without requiring changes in pH or solvent, and generated H
2
/CO
2
gas at a pressure of 190 atm from formic acid.
Modular but geometrically constrained ligands were used to investigate the impact of key ligand design parameters (charge and bite angle) on CO
2
hydrogenation and formic acid dehydrogenation activity.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFT01Lw0AQXUTB-nHxLow3haYmJrFprzFiTz3Eg7cw3Uzalc1m2d0U4v_s_3ENggdB5zJveB-8YewqCmdRGC_uecZ5mMTzEI_YJIofkyBNsrfjL5wugnmcpKfszNr30E-UZhN2yHdotgTUNMSdBUPbXqIjD_ZkrNhIgnz94M-65050Cjg6lIMVtpDeYTolONhea0ktKYdmAKGazrQ4qm-LcnUHuEch0WctoRyU25HzJm067lMN2SlYPWZZ3mnPcN8JuSMjPsaUKaCqweFmrFZD7SvMoCSCp_VqCb-fv2AnDUpLl9_7nF0_F6_5S2Asr7QRra9Z_cjj__mbv_hK1038CWKHe3Y</recordid><startdate>20180710</startdate><enddate>20180710</enddate><creator>Geri, Jacob B</creator><creator>Ciatti, Joanna L</creator><creator>Szymczak, Nathaniel K</creator><scope/></search><sort><creationdate>20180710</creationdate><title>Charge effects regulate reversible CO2 reduction catalysisElectronic supplementary information (ESI) available: Synthetic procedures, spectroscopic characterization, and tabulated data. See DOI: 10.1039/c8cc04370a</title><author>Geri, Jacob B ; Ciatti, Joanna L ; Szymczak, Nathaniel K</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c8cc04370a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Geri, Jacob B</creatorcontrib><creatorcontrib>Ciatti, Joanna L</creatorcontrib><creatorcontrib>Szymczak, Nathaniel K</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Geri, Jacob B</au><au>Ciatti, Joanna L</au><au>Szymczak, Nathaniel K</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Charge effects regulate reversible CO2 reduction catalysisElectronic supplementary information (ESI) available: Synthetic procedures, spectroscopic characterization, and tabulated data. See DOI: 10.1039/c8cc04370a</atitle><date>2018-07-10</date><risdate>2018</risdate><volume>54</volume><issue>56</issue><spage>779</spage><epage>7793</epage><pages>779-7793</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Modular but geometrically constrained ligands were used to investigate the impact of key ligand design parameters (charge and bite angle) on CO
2
hydrogenation and formic acid dehydrogenation activity. These studies yielded an optimized catalyst that achieved over 118 000 turnovers in CO
2
hydrogenation, 247 000 turnovers in HCO
2
H dehydrogenation, was applied in a hydrogen storage device used for 6 cycles of hydrogen storage/release without requiring changes in pH or solvent, and generated H
2
/CO
2
gas at a pressure of 190 atm from formic acid.
Modular but geometrically constrained ligands were used to investigate the impact of key ligand design parameters (charge and bite angle) on CO
2
hydrogenation and formic acid dehydrogenation activity.</abstract><doi>10.1039/c8cc04370a</doi><tpages>4</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Charge effects regulate reversible CO2 reduction catalysisElectronic supplementary information (ESI) available: Synthetic procedures, spectroscopic characterization, and tabulated data. See DOI: 10.1039/c8cc04370a |
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