Corannulene: a molecular bowl of carbon with multifaceted properties and diverse applications
Unlike typical polycyclic aromatic hydrocarbons, such as coronene, which are flat and planar, corannulene is a molecular bowl of carbon. It can be imagined as the cap region of fullerene C 60 or an end of a single-walled carbon nanotube. This structural distinction manifests itself in unique propert...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018, Vol.54 (5), p.653-6519 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Nestoros, Eleni Stuparu, Mihaiela C |
| description | Unlike typical polycyclic aromatic hydrocarbons, such as coronene, which are flat and planar, corannulene is a molecular bowl of carbon. It can be imagined as the cap region of fullerene C
60
or an end of a single-walled carbon nanotube. This structural distinction manifests itself in unique properties. For example, corannulene exhibits bowl-flipping dynamics, electron accepting capability, and formation of a ball-in-socket type of interaction with C
60
. These varied properties allow for application of corannulene in a myriad of disciplines ranging from organic electronics and sensing to energy storage and self-assembly. In this feature article, our goal is to discuss the major synthetic developments in corannulene chemistry which allow the scientific community access to this beautiful molecule in a practical fashion, the unique properties of the corannulene nucleus that sets it apart from the planar polynuclear aromatic hydrocarbons, and lastly its applications in the arena of materials chemistry.
The chemistry, properties and applications of corannulene are discussed. |
| doi_str_mv | 10.1039/c8cc02179a |
| format | Article |
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60
or an end of a single-walled carbon nanotube. This structural distinction manifests itself in unique properties. For example, corannulene exhibits bowl-flipping dynamics, electron accepting capability, and formation of a ball-in-socket type of interaction with C
60
. These varied properties allow for application of corannulene in a myriad of disciplines ranging from organic electronics and sensing to energy storage and self-assembly. In this feature article, our goal is to discuss the major synthetic developments in corannulene chemistry which allow the scientific community access to this beautiful molecule in a practical fashion, the unique properties of the corannulene nucleus that sets it apart from the planar polynuclear aromatic hydrocarbons, and lastly its applications in the arena of materials chemistry.
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60
or an end of a single-walled carbon nanotube. This structural distinction manifests itself in unique properties. For example, corannulene exhibits bowl-flipping dynamics, electron accepting capability, and formation of a ball-in-socket type of interaction with C
60
. These varied properties allow for application of corannulene in a myriad of disciplines ranging from organic electronics and sensing to energy storage and self-assembly. In this feature article, our goal is to discuss the major synthetic developments in corannulene chemistry which allow the scientific community access to this beautiful molecule in a practical fashion, the unique properties of the corannulene nucleus that sets it apart from the planar polynuclear aromatic hydrocarbons, and lastly its applications in the arena of materials chemistry.
The chemistry, properties and applications of corannulene are discussed.</description><subject>Buckminsterfullerene</subject><subject>Carbon</subject><subject>Energy storage</subject><subject>Fullerenes</subject><subject>Hydrocarbons</subject><subject>Molecular chains</subject><subject>Nanotubes</subject><subject>Organic chemistry</subject><subject>Polycyclic aromatic hydrocarbons</subject><subject>Properties (attributes)</subject><subject>Self-assembly</subject><subject>Single wall carbon nanotubes</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kc1LHzEQhoNY_OzFu5LSSymsJpvdTeJNFvsBghcFL2XJzk5oJLtZk91K__tGf2qhh85lBt6Hl5l3CDni7JQzoc9AAbCSS222yB4XTVXUlbrbfpprXUhR1btkP6V7lovXaofsllrWDa_KPfKjDdFM0-pxwnNq6Bg8wupNpH149DRYCib2YaKPbvlJx9UvzhrABQc6xzBjXBwmaqaBDu4XxoTUzLN3YBYXpnRI3lnjE75_6Qfk9svlTfutuLr--r29uCpANGIpVC_6SvVgSjUIXQqrlTGy0rIUjOFQWck5GNYzJThKno9tuARoJGgOVqM4IJ82vnmnhxXT0o0uAXpvJgxr6komlGRcKZnRj_-g92GNU94uU3Wj6kbUKlOfNxTEkFJE283RjSb-7jjrnkLvWtW2z6FfZPjkxXLtRxze0NeUM3C8AWKCN_Xv17L-4X96Nw9W_AHUdJG5</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Nestoros, Eleni</creator><creator>Stuparu, Mihaiela C</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8663-6189</orcidid></search><sort><creationdate>2018</creationdate><title>Corannulene: a molecular bowl of carbon with multifaceted properties and diverse applications</title><author>Nestoros, Eleni ; Stuparu, Mihaiela C</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c363t-8b3b48bca28d3923f98aa74972300ed4f711ca0b0831e71c02617cc67c91cf9e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Buckminsterfullerene</topic><topic>Carbon</topic><topic>Energy storage</topic><topic>Fullerenes</topic><topic>Hydrocarbons</topic><topic>Molecular chains</topic><topic>Nanotubes</topic><topic>Organic chemistry</topic><topic>Polycyclic aromatic hydrocarbons</topic><topic>Properties (attributes)</topic><topic>Self-assembly</topic><topic>Single wall carbon nanotubes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nestoros, Eleni</creatorcontrib><creatorcontrib>Stuparu, Mihaiela C</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nestoros, Eleni</au><au>Stuparu, Mihaiela C</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Corannulene: a molecular bowl of carbon with multifaceted properties and diverse applications</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2018</date><risdate>2018</risdate><volume>54</volume><issue>5</issue><spage>653</spage><epage>6519</epage><pages>653-6519</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Unlike typical polycyclic aromatic hydrocarbons, such as coronene, which are flat and planar, corannulene is a molecular bowl of carbon. It can be imagined as the cap region of fullerene C
60
or an end of a single-walled carbon nanotube. This structural distinction manifests itself in unique properties. For example, corannulene exhibits bowl-flipping dynamics, electron accepting capability, and formation of a ball-in-socket type of interaction with C
60
. These varied properties allow for application of corannulene in a myriad of disciplines ranging from organic electronics and sensing to energy storage and self-assembly. In this feature article, our goal is to discuss the major synthetic developments in corannulene chemistry which allow the scientific community access to this beautiful molecule in a practical fashion, the unique properties of the corannulene nucleus that sets it apart from the planar polynuclear aromatic hydrocarbons, and lastly its applications in the arena of materials chemistry.
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2018, Vol.54 (5), p.653-6519 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_rsc_primary_c8cc02179a |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Buckminsterfullerene Carbon Energy storage Fullerenes Hydrocarbons Molecular chains Nanotubes Organic chemistry Polycyclic aromatic hydrocarbons Properties (attributes) Self-assembly Single wall carbon nanotubes |
| title | Corannulene: a molecular bowl of carbon with multifaceted properties and diverse applications |
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