Pd-nanodot decorated MoS2 nanosheets as a highly efficient photocatalyst for the visible-light-induced Suzuki-Miyaura coupling reactionElectronic supplementary information (ESI) available. See DOI: 10.1039/c7ta08441b
In this work, we demonstrate that the incorporation of MoS 2 nanosheets with Pd nanodots is a promising way for promoting the visible-light-induced Suzuki-Miyaura C-C coupling reaction. The MoS 2 nanosheets decorated with Pd nanodots showed very high photocatalytic activity. The turnover frequency f...
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| creator | Shin, Hyeon Ho Kang, Eunmi Park, Haeli Han, Taejun Lee, Chul-Ho Lim, Dong-Kwon |
| description | In this work, we demonstrate that the incorporation of MoS
2
nanosheets with Pd nanodots is a promising way for promoting the visible-light-induced Suzuki-Miyaura C-C coupling reaction. The MoS
2
nanosheets decorated with Pd nanodots showed very high photocatalytic activity. The turnover frequency for the biphenyl product was >1600 h
−1
even under sunlight illumination at room temperature. Mechanistic studies show that the high catalytic activity originated from the efficient electron-hole pair generation mechanism of MoS
2
under visible-light illumination instead of purely thermal effects.
The incorporation of MoS
2
nanosheets with Pd nanodots is a promising way for promoting the visible-light-induced C-C coupling reaction. |
| doi_str_mv | 10.1039/c7ta08441b |
| format | Article |
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2
nanosheets with Pd nanodots is a promising way for promoting the visible-light-induced Suzuki-Miyaura C-C coupling reaction. The MoS
2
nanosheets decorated with Pd nanodots showed very high photocatalytic activity. The turnover frequency for the biphenyl product was >1600 h
−1
even under sunlight illumination at room temperature. Mechanistic studies show that the high catalytic activity originated from the efficient electron-hole pair generation mechanism of MoS
2
under visible-light illumination instead of purely thermal effects.
The incorporation of MoS
2
nanosheets with Pd nanodots is a promising way for promoting the visible-light-induced C-C coupling reaction.</description><identifier>ISSN: 2050-7488</identifier><identifier>EISSN: 2050-7496</identifier><identifier>DOI: 10.1039/c7ta08441b</identifier><language>eng</language><creationdate>2017-12</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,782,786,27933,27934</link.rule.ids></links><search><creatorcontrib>Shin, Hyeon Ho</creatorcontrib><creatorcontrib>Kang, Eunmi</creatorcontrib><creatorcontrib>Park, Haeli</creatorcontrib><creatorcontrib>Han, Taejun</creatorcontrib><creatorcontrib>Lee, Chul-Ho</creatorcontrib><creatorcontrib>Lim, Dong-Kwon</creatorcontrib><title>Pd-nanodot decorated MoS2 nanosheets as a highly efficient photocatalyst for the visible-light-induced Suzuki-Miyaura coupling reactionElectronic supplementary information (ESI) available. See DOI: 10.1039/c7ta08441b</title><description>In this work, we demonstrate that the incorporation of MoS
2
nanosheets with Pd nanodots is a promising way for promoting the visible-light-induced Suzuki-Miyaura C-C coupling reaction. The MoS
2
nanosheets decorated with Pd nanodots showed very high photocatalytic activity. The turnover frequency for the biphenyl product was >1600 h
−1
even under sunlight illumination at room temperature. Mechanistic studies show that the high catalytic activity originated from the efficient electron-hole pair generation mechanism of MoS
2
under visible-light illumination instead of purely thermal effects.
The incorporation of MoS
2
nanosheets with Pd nanodots is a promising way for promoting the visible-light-induced C-C coupling reaction.</description><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkE9Lw0AQxRdRsNRevAvjTQ-p2z-2iVeN2ENRiPcy3Uya0e1u2N0U4iftx3ELogdBh4F5zDx-D0aI85EcjuQku1HzgDKdTkfrI9Eby1uZzKfZ7Phbp-mpGHj_JmOlUs6yrCf2L2Vi0NjSBihJWYeBSljaYgyHta-JggeMDTVvat0BVRUrJhOgqW2wCgPqzgeorINQE-zY81pToqM9JGzKVkVi0X6075wsucPWISjbNprNBhyhCmxNrkkFZw0r8G3TaNrGBHQdsIngLR48cJUXi2vAHbLGGDGEgggenhd38PsFZ-KkQu1p8DX74uIxf71_SpxXq8bxNsJXP_ZJX1z-dV81ZTX5j_EJidt9Gw</recordid><startdate>20171205</startdate><enddate>20171205</enddate><creator>Shin, Hyeon Ho</creator><creator>Kang, Eunmi</creator><creator>Park, Haeli</creator><creator>Han, Taejun</creator><creator>Lee, Chul-Ho</creator><creator>Lim, Dong-Kwon</creator><scope/></search><sort><creationdate>20171205</creationdate><title>Pd-nanodot decorated MoS2 nanosheets as a highly efficient photocatalyst for the visible-light-induced Suzuki-Miyaura coupling reactionElectronic supplementary information (ESI) available. See DOI: 10.1039/c7ta08441b</title><author>Shin, Hyeon Ho ; Kang, Eunmi ; Park, Haeli ; Han, Taejun ; Lee, Chul-Ho ; Lim, Dong-Kwon</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c7ta08441b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shin, Hyeon Ho</creatorcontrib><creatorcontrib>Kang, Eunmi</creatorcontrib><creatorcontrib>Park, Haeli</creatorcontrib><creatorcontrib>Han, Taejun</creatorcontrib><creatorcontrib>Lee, Chul-Ho</creatorcontrib><creatorcontrib>Lim, Dong-Kwon</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shin, Hyeon Ho</au><au>Kang, Eunmi</au><au>Park, Haeli</au><au>Han, Taejun</au><au>Lee, Chul-Ho</au><au>Lim, Dong-Kwon</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pd-nanodot decorated MoS2 nanosheets as a highly efficient photocatalyst for the visible-light-induced Suzuki-Miyaura coupling reactionElectronic supplementary information (ESI) available. See DOI: 10.1039/c7ta08441b</atitle><date>2017-12-05</date><risdate>2017</risdate><volume>5</volume><issue>47</issue><spage>24965</spage><epage>24971</epage><pages>24965-24971</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><abstract>In this work, we demonstrate that the incorporation of MoS
2
nanosheets with Pd nanodots is a promising way for promoting the visible-light-induced Suzuki-Miyaura C-C coupling reaction. The MoS
2
nanosheets decorated with Pd nanodots showed very high photocatalytic activity. The turnover frequency for the biphenyl product was >1600 h
−1
even under sunlight illumination at room temperature. Mechanistic studies show that the high catalytic activity originated from the efficient electron-hole pair generation mechanism of MoS
2
under visible-light illumination instead of purely thermal effects.
The incorporation of MoS
2
nanosheets with Pd nanodots is a promising way for promoting the visible-light-induced C-C coupling reaction.</abstract><doi>10.1039/c7ta08441b</doi><tpages>7</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008- |
| title | Pd-nanodot decorated MoS2 nanosheets as a highly efficient photocatalyst for the visible-light-induced Suzuki-Miyaura coupling reactionElectronic supplementary information (ESI) available. See DOI: 10.1039/c7ta08441b |
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