Ni-catalysed regioselective 1,2-diarylation of unactivated olefins by stabilizing Heck intermediates as pyridylsilyl-coordinated transient metallacyclesElectronic supplementary information (ESI) available: Experimental procedures and characterization, and the 1H and 13C NMR spectra of new compounds. See DOI: 10.1039/c7sc04351a

We report a Ni-catalysed diarylation of unactivated olefins in dimethylpyridylvinylsilane by intercepting Heck C(sp 3 )-NiX intermediates, derived from aryl halides, with arylzinc reagents. This approach utilizes a modifiable pyridylsilyl moiety as a coordinating group that plays a dual role of inte...

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Hauptverfasser:	Thapa, Surendra, Dhungana, Roshan K, Magar, Rajani Thapa, Shrestha, Bijay, KC, Shekhar, Giri, Ramesh
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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